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Palladium Supported on Commercial Fumed Silica as Sustainable Catalyst for Suzuki-Miyaura Coupling Reactions

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Abstract

Palladium nanocatalysts supported on commercial fumed silica were synthesized via a convenient liquid method without any external reductant or surfactants. The catalysts were characterized by inductively coupled plasma-mass spectrometry, X-ray powder diffraction and the transmission electron microscope analysis. Then it was applied for Suzuki-Miyaura cross-coupling reactions. It was found that a number of aryl halides were efficiently catalyzed using these catalysts in aqueous-ethanol under relatively mild condition within 0.5h. Further study showed that the catalyst could be recycled up to 10 times without loss of activity.

Palladium nanocatalysts supported on commercial fumed silica were synthesized and applied for Suzuki-Miyaura cross-coupling reactions. A number of aryl halides were efficiently catalyzed using these catalysts in aqueous-ethanol under relatively mild condition within 0.5h. Further study showed that the catalyst could be recycled up to 10 times without loss of activity.

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Acknowledgments

This research was supported by Zhejiang Provincial Natural Science Foundation of China under Grant No. LY18B040003

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Authors and Affiliations

  1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou, 310012, China

    Zhen-Wei Kang, Zhan-Chen Gao, Su-Fang Lv, Fei-Bao Zhang & Jian-Xiong Jiang

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  1. Zhen-Wei Kang
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  2. Zhan-Chen Gao
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  3. Su-Fang Lv
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  4. Fei-Bao Zhang
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  5. Jian-Xiong Jiang
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Corresponding authors

Correspondence to Fei-Bao Zhang or Jian-Xiong Jiang.

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Supplementary Information (SI)

Additional experimental data of Suzuki–Miyaura reactions are given in the Supplementary Information.

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Kang, ZW., Gao, ZC., Lv, SF. et al. Palladium Supported on Commercial Fumed Silica as Sustainable Catalyst for Suzuki-Miyaura Coupling Reactions. Silicon 11, 287–292 (2019). https://doi.org/10.1007/s12633-018-9853-9

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  • DOI: https://doi.org/10.1007/s12633-018-9853-9

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