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Effect of magnesium addition on inclusions in H13 die steel

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Abstract

The effect of magnesium addition on the number, morphology, composition, size, and density of inclusions in H13 die steel was studied. The results show that the total oxygen content in the steel can be significantly decreased to 0.0008wt%. Al2O3 and MnS inclusions are changed into nearly spherical MgO·Al2O3 spinel and spherical MgO·MgS inclusions, respectively. The number of inclusions larger than 1 μm decreases and the number of inclusions smaller than 1 μm increases with increasing magnesium content. V(N,C) precipitates around MgO·Al2O3 and MgO·MgS inclusions during solidification of liquid steel. The densities of MgO·Al2O3 spinel inclusions are lower than that of alumina inclusions. With increasing magnesium content in the Mg-containing inclusions, the density of inclusions decreases, leading to the improvement of inclusion removal efficiency.

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References

  1. G.H. Yan, X.M. Huang, Y.Q. Wang, X.G. Qin, M. Yang, Z.M. Chu, and K. Jin, Effects of heat treatment on mechanical properties of H13 steel, Met. Sci. Heat Treat., 52(2010), No. 7–8, p. 393.

    Google Scholar 

  2. D. Klobčar, J. Tušek, and B. Taljat, Thermal fatigue of materials for die-casting tooling, Mater. Sci. Eng. A, 472(2008), No. 1–2, p. 198.

    Article  Google Scholar 

  3. N. Tripathi and S.C. Du, Chemical characterisation of non-metallic inclusions during casting of hot work die steel, Ironmaking Steelmaking, 33(2006), No. 3, p. 213.

    Article  Google Scholar 

  4. F. Chai, C.F. Yang, and H. Su, Effect of magnesium on inclusion formation in Ti-killed steels and microstructural evolution in welding induced coarse-grained heat affected zone, J. Iron. Steel. Res. Int., 16(2009), No. 1, p. 69.

    Article  Google Scholar 

  5. V.M. Schastlivtsev, T.I. Tabatchikova, I.L. Yakovleva, and S.Y. Klyueva, Effect of structure and nonmetallic inclusions on the intercrystalline fracture of cast steel, Phys. Met. Metallogr., 114(2013), No. 2, p. 180.

    Article  Google Scholar 

  6. J. Yao, X.H. Qu, X.B. He, and L. Zhang, Effect of inclusion size on the high cycle fatigue strength and failure mode of a high V alloyed powder metallurgy tool steel, Int. J. Miner. Metall. Mater., 19(2012), No. 7, p. 608.

    Article  Google Scholar 

  7. W.G. Seo, W.H. Han, J.S. Kim, and J.J. Pak, Deoxidation equilibria among Mg, Al and O in liquid iron in the presence of MgO·Al2O3 spinel, ISIJ Int., 43(2003), No. 2, p. 201.

    Article  Google Scholar 

  8. R. Takata, J. Yang, and M. Kuwabara, Characteristics of inclusions generated during Al-Mg complex deoxidation of molten steel, ISIJ Int., 47(2007), No. 10, p. 1379.

    Article  Google Scholar 

  9. S.J. Luo, Y.H. Su, M.J. Lu, and J.C. Kuo, EBSD analysis of magnesium addition on inclusion formation in SS400 structural steel, Mater. Charact., 82(2013), p. 103.

    Article  Google Scholar 

  10. J.H. Park and H.K. Todoroki, Control of MgO·Al2O3 spinel inclusions in stainless steels, ISIJ Int., 50(2010) No. 10, p. 1333.

    Article  Google Scholar 

  11. J. Yang, K.J. Okumura, M. Kuwabara, and M. Sano, Behavior of magnesium in the desulfurization process of molten iron with magnesium vapor produced in-situ by aluminothermic reduction of magnesium oxide, ISIJ Int., 42(2002), No. 7, p. 685.

    Article  Google Scholar 

  12. C.B. Shi, X.C. Chen, H.J. Guo, Z.J. Zhu, and X.L. Sun, Control of MgO·Al2O3 spinel inclusions during protective gas electroslag remelting of die steel, Metall. Mater. Trans. B, 44(2013), No. 2, p. 378.

    Article  Google Scholar 

  13. H. Ohta and H. Suito, Thermodynamics of aluminum and manganese deoxidation equilibria in Fe-Ni and Fe-Cr alloys, ISIJ Int., 43(2003), No. 9, p. 1301.

    Article  Google Scholar 

  14. H. Ohta and H. Suito, Calcium and magnesium deoxidation in Fe-Ni and Fe-Cr alloys equilibrated with CaO-Al2O3 and CaO-Al2O3-MgO slags, ISIJ Int., 43(2003), No. 9, p. 1293.

    Article  Google Scholar 

  15. K. Fujii, T. Nagasaka, and M. Hino, Activities of the constituents in spinel solid solution and free energies of formation of MgO, MgO·Al2O3, ISIJ Int., 40(2000), No. 11, p. 1059.

    Article  Google Scholar 

  16. H. Todoroki and K. Mizuno, Effect of silica in slag on inclusion compositions in 304 stainless steel deoxidized with aluminum, ISIJ Int., 44 (2004), No. 8, p. 1350.

    Article  Google Scholar 

  17. A. Hayashi, T. Uenishi, H. Kandori, T. Miki, and M. Hino, Aluminum deoxidation equilibrium of molten Fe-Ni alloy coexisting with alumina or hercynite, ISIJ Int., 48(2008), No. 11, p. 1533.

    Article  Google Scholar 

  18. D. Domanski, G. Urretavizcaya, F.J. Castro, and F.C. Gennari, Mechanochemical synthesis of magnesium aluminate spinel powder at room temperature, J. Am. Ceram. Soc., 87(2004), No. 11, p. 2020.

    Article  Google Scholar 

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Correspondence to Zheng Wu.

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Wu, Z., Li, J., Shi, Cb. et al. Effect of magnesium addition on inclusions in H13 die steel. Int J Miner Metall Mater 21, 1062–1067 (2014). https://doi.org/10.1007/s12613-014-1010-x

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  • DOI: https://doi.org/10.1007/s12613-014-1010-x

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