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Recent increase in surface fCO2 in the western subtropical North Pacific

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Abstract

We observed unusually high levels (> 440 μatm) of carbon dioxide fugacity (fCO2) in surface seawater in the western subtropical North Pacific, the area where Subtropical Mode Water is formed, during summer 2015. The NOAA Kuroshio Extension Observatory moored buoy located in this region also measured high CO2 values, up to 500 μatm during this period. These high sea surface fCO2 (fCO2SW) values are explained by much higher normalized total dissolved inorganic carbon and slightly higher normalized total alkalinity concentrations in this region compared to the equatorial Pacific. Moreover, these values are much higher than the climatological CO2 values, even considering increasing atmospheric CO2, indicating a recent large increase in sea surface CO2 concentrations. A large seasonal change in sea surface temperature contributed to higher surface fCO2SW in the summer of 2015.

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References

  • Atlas R, Hoffman RN, Ardizzone J, Leidner SM, Jusem JC, Smith DK, Gombos D (2011) A cross-calibrated, multiplatform ocean surface wind velocity product for meteorological and oceanographic applications. B Am Meteorol Soc 92(2): 157–174. doi:10.1175/2010bams2946.1

    Article  Google Scholar 

  • Ayers JM, Lozier MS (2010) Physical controls on the seasonal migration of the North Pacific transition zone chlorophyll front. J Geophys Res 115(C5):C05001. doi:10.1029/2009JC005596

    Article  Google Scholar 

  • Behrenfeld MJ, Falkowski PG (1997) Photosynthetic rates derived from satellite-based chlorophyll concentration. Limnol Oceanogr 42(1): 1–20

    Article  Google Scholar 

  • Bingham FM (1992) Formation and spreading of Subtropical Mode Water in the North Pacific. J Geophys Res 97:177–189

    Article  Google Scholar 

  • Conway TJ, Tans PP, Waterman LS, Thoning KW (1994) Evidence for interannual variability of the carbon cycle from the National Oceanic and Atmospheric Administration/Climate Monitoring and Diagnostics Laboratory Global Air Sampling Network. J Geophys Res 99(D11):22831–22855. doi:10.1029/94jd01951

    Article  Google Scholar 

  • Gnanadesikan A, Pradal MA, Abernathey R (2015) Isopycnal mixing by mesoscale eddies significantly impacts oceanic anthropogenic carbon uptake. Geophys Res Lett 42(11): 4249–4255. doi:10.1002/2015gl064100

    Article  Google Scholar 

  • Hanawa K (1987) Interannual variations in the winter-time outcrop area of Subtropical Mode Water in the western North Pacific Ocean. Atmos Ocean 25:358–374

    Article  Google Scholar 

  • Ishii M, Inoue HY, Matsueda H, Saito S, Fushimi K, Nemoto K, Yano T, Nagai H, Midorikawa T (2001) Seasonal variation in total inorganic carbon and its controlling processes in surface waters of the western North Pacific subtropical gyre. Mar Chem 75:17–32

    Article  Google Scholar 

  • Ishii M, Feely RA, Rodgers KB, Park GH, Wanninkhof R, Sasano D, Sugimoto H, Cosca CE, Nakaoka S, Telszewski M, Nojiri Y, Fletcher SEM, Niwa Y, Patra PK, Valsala V, Nakano H, Lima I, Doney SC, Buitenhuis ET, Aumont O, Dunne JP, Lenton A, Takahashi T (2014) Air-sea CO2 flux in the Pacific Ocean for the period 1990–2009. Biogeosciences 11(3): 709–734. doi:10.5194/bg-11-709-2014

    Article  Google Scholar 

  • Le Quéré C, Raupach MR, Canadell JG, Marland G, Bopp L, Ciais P, Conway TJ, Doney SC, Feely RA, Foster P, Friedlingstein P, Gurney K, Houghton RA, House JI, Huntingford C, Levy PE, Lomas MR, Majkut J, Metzl N, Ometto JP, Peters GP, Prentice IC, Randerson JT, Running SW, Sarmiento JL, Schuster U, Sitch S, Takahashi T, Viovy N, van der Werf GR, Woodward FI (2009) Trends in the sources and sinks of carbon dioxide. Nat Geosci 2(12): 831–836. doi:10.1038/ngeo689

    Article  Google Scholar 

  • Le Quéré C, Andrew RM, Canadell JG, Sitch S, Korsbakken JI, Peters GP, Manning AC, Boden TA, Tans PP, Houghton RA, Keeling RF, Alin S, Andrews OD, Anthoni P, Barbero L, Bopp L, Chevallier F, Chini LP, Ciais P, Currie K, Delire C, Doney SC, Friedlingstein P, Gkritzalis T, Harris I, Hauck J, Haverd V, Hoppema M, Klein Goldewijk K, Jain AK, Kato E, Körtzinger A, Landschützer P, Lefèvre N, Lenton A, Lienert S, Lombardozzi D, Melton JR, Metzl N, Millero F, Monteiro PMS, Munro DR, Nabel JEMS, Nakaoka S, O'Brien K, Olsen A, Omar AM, Ono T, Pierrot D, Poulter B, Rödenbeck C, Salisbury J, Schuster U, Schwinger J, Séférian R, Skjelvan I, Stocker BD, Sutton AJ, Takahashi T, Tian H, Tilbrook B, van der Laan-Luijkx IT, van der Werf GR, Viovy N, Walker AP, Wiltshire AJ, Zaehle S (2016) Global Carbon Budget 2016. Earth Syst Sci Data 8(2): 605–649. doi:10.5194/essd-8-605-2016

    Article  Google Scholar 

  • Metzl N, Corbière A, Reverdin G, Lenton A, Takahashi T, Olsen A, Johannessen T, Pierrot D, Wanninkhof R, Olafsdottir SR, Olafsson J, Ramonet M (2010) Recent acceleration of the sea surface fCO2 growth rate in the North Atlantic subpolar gyre (1993-2008) revealed by winter observations. Global Biogeochem Cy 24:GB4004. doi:10.1029/2009gb003658

    Article  Google Scholar 

  • McKinley GA, Takahashi T, Buitenhuis E, Chai F, Christian JR, Doney SC, Jiang MS, Lindsay K, Moore JK, Le Quéré C, Lima I, Murtugudde R, Shi L, Wetzel P (2006) North Pacific carbon cycle response to climate variability on seasonal to decadal timescales. J Geophys Res-Oceans 111:C07S06. doi:10.1029/2005jc003173

    Article  Google Scholar 

  • Midorikawa T, Ishii M, Kosugi N, Sasano D, Nakano T, Saito S, Sakamoto N, Nakano H, Inoue HY (2012) Recent deceleration of oceanic pCO2 increase in the western North Pacific in winter. Geophys Res Lett 39(12):L12601. doi:10.1029/2012GL051665

    Article  Google Scholar 

  • Newman M, Alexander MA, Ault TR, Cobb KM, Deser C, Di Lorenzo E, Mantua NJ, Miller AJ, Minobe S, Nakamura H, Schneider N, Vimont DJ, Phillips AS, Scott JD, Smith CA (2016) The pacific decadal oscillation, revisited. J Climate 29(12): 4399–4427. doi:10.1175/jcli-d-15-0508.1

    Article  Google Scholar 

  • Park GH, Wanninkhof R, Doney SC, Takahashi T, Lee K, Feely RA, Sabine CL, Triñanes J, Lima ID (2010) Variability of global net sea-air CO2 fluxes over the last three decades using empirical relationships. Tellus B 62(5): 352–368. doi:10.1111/j.1600-0889.2010.00498.x

    Article  Google Scholar 

  • Park GH, Wanninkhof R (2012) A large increase of the CO2 sink in the western tropical North Atlantic from 2002 to 2009. J Geophys Res-Oceans 117:C08029. doi:10.1029/2011jc007803

    Google Scholar 

  • Pierrot D, Lewis E, Wallace DWR (2006) MS Excel program developed for CO2 system calculations. Rep ORNL/CDIAC–105. Carbon Dioxide Inf Anal Cent, Oak Ridge Natl Lab, US Dept Energy, Oak Ridge. doi:10.3334/CDIAC/otg.CO2SYS_XLS_CDIAC105a

  • Pierrot D, Neill C, Sullivan K, Castle R, Wanninkhof R, Luger H, Johannessen T, Olsen A, Feely RA, Cosca CE (2009) Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep-Sea Res Pt II 56:512–522. doi:10.1016/j.dsr2.2008.12.005

    Article  Google Scholar 

  • Schuster U, Watson AJ, Bates NR, Corbière A, Gonzalez-Davila M, Metzl N, Pierrot D, Santana-Casiano M (2009) Trends in North Atlantic sea-surface fCO2 from 1990 to 2006. Deep-Sea Res Pt II 56(8–10):620–629. doi:10.1016/j.dsr2.2008.12.011

    Article  Google Scholar 

  • Suga T, Hanawa K, Toba Y (1989) Subtropical Mode Water in the 137°E section. J Phys Oceanogr 19:1605–1618

    Article  Google Scholar 

  • Suga T, Yoshikazu A, Saito H, Hanawa K (2008) Ventilation of the North Pacific subtropical pyconcline and mode water formation. Prog Oceanogr 77:285–297

    Article  Google Scholar 

  • Takahashi T, Olafsson J, Goddard JG, Chipman DW, Sutherland SC (1993) Seasonal variation of CO2 and nutrients in the high-latitude surface oceans: a comparative study. Global Biogeochem Cy 7(4): 843–878. doi:10.1029/93gb02263

    Article  Google Scholar 

  • Takahashi T, Sutherland SC, Wanninkhof R, Sweeney C, Feely RA, Chipman DW, Hales B, Friederich G, Chavez F, Sabine C, Watson A, Bakker DCE, Schuster U, Metzl N, Yoshikawa-Inoue H, Ishii M, Midorikawa T, Nojiri Y, Körtzinger A, Steinhoff T, Hoppema M, Olafsson J, Arnarson TS, Tilbrook B, Johannessen T, Olsen A, Bellerby R, Wong CS, Delille B, Bates NR, de Baar HJW (2009a) Climatological mean and decadal change in surface ocean pCO2, and net sea-air CO2 flux over the global oceans. Deep-Sea Res Pt II 56(8–10):554–577. doi:10.1016/j.dsr2.2008.12.009

    Article  Google Scholar 

  • Takahashi T, Sutherland SC, Kozyr A (2009b) Global ocean surface water partial pressure of CO2 database: measurements performed during 1968–2008 (version 2008). Rep ORNL/CDIAC–152, Carbon Dioxide Inf Anal Cent, Oak Ridge Natl Lab, US Dept of Energy, Oak Ridge. doi:10.3334/CDIAC/otg.ndp088r

    Google Scholar 

  • Valsala V, Maksyutov S, Telszewski M, Nakaoka S, Nojiri Y, Ikeda M, Murtugudde R (2012) Climate impacts on the structures of the North Pacific air-sea CO2 flux variability. Biogeosciences 9(1): 477–492. doi:10.5194/bg-9-477-2012

    Article  Google Scholar 

  • Wakita M, Honda MC, Matsumoto K, Fujiki T, Kawakami H, Yasunaka S, Sasai Y, Sukigara C, Uchimiya M, Kitamura M, Kobari T, Mino Y, Nagano A, Watanabe S, Saino T (2016) Biological organic carbon export estimated from the annual carbon budget observed in the surface waters of the western subarctic and subtropical North Pacific Ocean from 2004 to 2013. J Oceanogr 72(5): 665–685. doi:10.1007/s10872-016-0379-8

    Article  Google Scholar 

  • Wanninkhof R (2014) Relationship between wind speed and gas exchange over the ocean revisited. Limnol Oceanogr-Meth 12:351–362

    Article  Google Scholar 

  • Weiss RF (1974) Carbon dioxide in water and seawater: the solubility of a non-ideal gas. Mar Chem 2(3): 203–215

    Article  Google Scholar 

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Correspondence to Geun-Ha Park.

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Kim, D., Choi, Y., Kim, TW. et al. Recent increase in surface fCO2 in the western subtropical North Pacific. Ocean Sci. J. 52, 329–335 (2017). https://doi.org/10.1007/s12601-017-0030-7

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  • DOI: https://doi.org/10.1007/s12601-017-0030-7

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