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Zr–Ti–Al–Fe–Cu bulk metallic glasses for biomedical device application

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Abstract

A series of Zr63.5−xTixAl9Fe4.5Cu23 (x = 0, 1.5, 3.0, 4.5, 6.0; at%) bulk metallic glasses (BMGs) were designed and produced by means of copper mold suction casting. The effect of Ti addition on the glass-forming ability (GFA) and mechanical properties of Zr63.5−xTixAl9Fe4.5Cu23 alloys was first investigated. The glass-forming ability and room-temperature plasticity of BMGs increase first and then reduced with Ti content increasing. At x = 3.0, the Zr60.5Ti3Al9Fe4.5Cu23 BMG showed a critical glass formation diameter of 10 mm and excellent room-temperature compressive plasticity (ɛP = 4.7%) by using the samples with dimensions of Φ3 mm × 6 mm. Meanwhile, the BMG also showed better biocompatibility and biocorrosion resistance compared with Ti6Al4V alloy. Under the imitated human body condition, the corrosion current density (Icorr) of BMG was 6.61 × 10–10 A·cm−2, which is two orders of magnitude lower than that of conventional Ti6Al4V alloy. Moreover, the CCD-986sk cell viabilities are, respectively, 65.4% and 46.6% on the BMG and Ti6Al4V alloy, indicating better biocompatibility of BMG. The Zr60.5Ti3Al9Fe4.5Cu23 BMG with larger GFA, excellent mechanical properties, biocompatibility and biocorrosion resistance is considered as a potential material in biomedical device fields.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 51901116 and 51671045), the Science Challenge Project (No. TZ2016004), the Fundamental Research Funds for the Central Universities (Nos. DUT16ZD209 and DUT18GF112) and the National Magnetic-Confinement Fusion Science Program (Nos. 2013GB107003 and 2015GB105003).

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Authors and Affiliations

  1. College of Mechanical and Electronic Engineering, Shandong University of Science and Technology, Qingdao, 266590, China

    Kai-Ming Han & Hui Jiang

  2. Key Laboratory of Materials Modification (Ministry of Education), Dalian University of Technology, Dalian, 116024, China

    Ying-Min Wang & Jian-Bing Qiang

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  1. Kai-Ming Han
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  2. Hui Jiang
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Correspondence to Hui Jiang or Ying-Min Wang.

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Han, KM., Jiang, H., Wang, YM. et al. Zr–Ti–Al–Fe–Cu bulk metallic glasses for biomedical device application. Rare Met. 40, 1239–1246 (2021). https://doi.org/10.1007/s12598-020-01644-6

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  • DOI: https://doi.org/10.1007/s12598-020-01644-6

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