Skip to main content
Log in

Microstructural evolution and properties of a Cu–Cr–Ag alloy during continuous manufacturing process

  • Published:
Rare Metals Aims and scope Submit manuscript

Abstract

Microstructure evolution and properties of a Cu–Cr–Ag alloy during the continuous manufacturing process were investigated in detail by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) in the study. The Cu–Cr–Ag alloy rod with uniform compositions is fabricated by upward continuous casting technology. Few of the Cr phases are observed in the as-cast alloy. During the continuous extrusion process, the severe shear deformation and the dynamic aging occur. The average grain size of as-extruded alloy is much smaller than that of as-cast alloy. Both fcc and bcc Cr precipitates appear in the matrix. The interaction mode between dislocations and precipitates can be identified as Orowan bypass mode according to the TEM observations. The overall difference in the yield strength between as-cast and as-extruded Cu–Cr–Ag alloy is attributed to solid solution strengthening, grain refinement strengthening, precipitation hardening and working hardening.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Hatakeyama M, Toyama T, Yang J, Nagai Y, Hasegawa M, Ohkubo T, Eldrup M, Singh BN. Nanostructural evolution of Cr-rich precipitates in a Cu–Cr–Zr alloy during heat treatment studied by 3 dimensional atom probe. Mater Trans. 2008;49(3):518.

    Article  CAS  Google Scholar 

  2. Cheng JY, Shen B, Yu FX. Precipitation in a Cu–Cr–Zr–Mg alloy during aging. Mater Character. 2013;81:68.

    Article  CAS  Google Scholar 

  3. Li MM, Zhang XP, Chen HM, Wang H, Yang B. Microstructure evolution and mechanical properties of Cu–Cr–In alloy during thermo-mechanical treatment. Chin J Rare Met. 2017;41(12):1311.

    Google Scholar 

  4. Liu Q, Zhang X, Ge Y, Wang J, Cui JZ. Effect of processing and heat treatment on behavior of Cu–Cr–Zr alloys to railway contact wire. Metall Mater Trans A. 2006;37:3233.

    Article  Google Scholar 

  5. Pang Y, Xia CD, Wang MP, Li Z, Xiao Z, Wei HG, Sheng XF, Jia YL, Chen C. Effects of Zr and (Ni, Si) additions on properties and microstructure of Cu–Cr alloy. J Alloys Compd. 2014;582:786.

    Article  CAS  Google Scholar 

  6. Xia CD, Zhang W, Kang ZY, Jia YL, Wu YF, Zhang R, Xu GY, Wang MP. High strength and high electrical conductivity Cu–Cr system alloys manufactured by hot rolling–quenching process and thermomechanical treatments. Mater Sci Eng A. 2012;538:2951.

    Article  Google Scholar 

  7. Wang ZQ, Zhong YB, Cao GH, Wang C, Wang J, Ren WL, Lei ZS, Ren ZR. Influence of dc electric current on the hardness of thermally aged Cu–Cr–Zr alloy. J Alloys Compd. 2009;479(1–2):303.

    Article  CAS  Google Scholar 

  8. Huang FX, Ma JS, Ning HL, Geng ZT, Lu C, Guo SM, Yu XT, Wang T, Li H, Lou HF. Analysis of phases in a Cu–Cr–Zr alloy. Scr Mater. 2003;48(1):97.

    Article  CAS  Google Scholar 

  9. Cheng JY, Yu FX, Shen B. Solute clusters and chemistry in a Cu–Cr–Zr–Mg alloy during the early stage of aging. Mater Lett. 2014;115:201.

    Article  CAS  Google Scholar 

  10. Zhang Y, Volinsky A, Tran HT, Chai Z, Liu P, Tian BH, Liu Y. Aging behavior and precipitates analysis of the Cu–Cr–Zr–Ce alloy. Mater Sci Eng A. 2016;650:248.

    Article  CAS  Google Scholar 

  11. Li HQ, Xie SH, Mi XJ, Wu PY. Phase and microstructure analysis of Cu–Cr–Zr alloys. J Mater Sci Technol. 2007;23(6):795.

    Article  CAS  Google Scholar 

  12. Chbihi A, Sauvage X, Blavette D. Atomic scale investigation of Cr precipitation in copper. Acta Mater. 2012;60(11):4575.

    Article  CAS  Google Scholar 

  13. Correia JB, Davies HA, Sellars CM. Strengthening in rapidly solidified age hardened Cu–Cr and Cu–Cr–Zr alloys. Acta Mater. 1997;45(1):177.

    Article  CAS  Google Scholar 

  14. Hatakeyama M, Toyama T, Yang J. 3D-AP and positron annihilation study of precipitation behavior in Cu–Cr–Zr alloy. J Nucl Mater. 2009;386–388:852.

    Article  Google Scholar 

  15. Jin Y, Adachi K, Takeuchi T, Suzuki HG. Ageing characteristics of Cu–Cr in situ composite. J Mater Sci. 1998;33(5):1333.

    Article  CAS  Google Scholar 

  16. Peng LJ, Xie HF, Huang GJ, Xu GL, Yin XQ, Feng X, Mi XJ, Yang Z. The phase transformation and strengthening of a Cu-0.71 wt% Cr alloy. J Alloys Compd. 2017;708:1096.

    Article  CAS  Google Scholar 

  17. Batra IS, Dey GK, Kulkarni UD, Banerjee S. Precipitation in a Cu–Cr–Zr alloy. Mater Sci Eng A. 2002;356(1–2):32.

    Google Scholar 

  18. Zhao ZQ, Xiao Z, Li Z, Ma MZ, Dai JJ. Effect of magnesium on microstructure and properties of Cu–Cr alloy. J Alloys Compd. 2018;752:191.

    Article  CAS  Google Scholar 

  19. Chihiro W, Ryoichi M, Kazue T. Mechanical properties of Cu–Cr system alloys with and without Zr and Ag. J Mater Sci. 2008;43(3):813.

    Article  Google Scholar 

  20. Li HQ, Xie SS, Mi XJ, Liu Y, Wu PY, Chen L. Influence of cerium and yttrium on Cu–Cr–Zr alloys. J Rare Earth. 2006;24(1):367.

    Article  Google Scholar 

  21. Liu Q, Cui ZJ, Xu GM, Liu XT. Experimental study of Cu–Ag alloy contact wire manufactured through upward-casting process. J Northeast Univ. 2004;25(9):844.

    CAS  Google Scholar 

  22. Zhang ZG. Study on high conductivity and high strength copper–silver alloy wire and new continuously manufacturing techniques. Zhengzhou: Zhengzhou University; 2013. 19.

    Google Scholar 

  23. Yuan Y, Li Z, Xiao Z, Zhao ZQ, Yang ZQ. Microstructure evolution and properties of Cu–Cr alloy during continuous extrusion process. J Alloys Compd. 2017;703:454.

    Article  CAS  Google Scholar 

  24. Sun J, Liu P, Liu XK, Chen XH, He DH, Ma FC, Li W. Microstructure evolution and properties of Cu–Ni–Si alloy during continuous extrusion process. Chin J Nonferr Met. 2014;24(4):944.

    CAS  Google Scholar 

  25. Thomas BM, Derguti F, Jackson M. Continuous extrusion of a commercially pure titanium powder via the conform process. Mater Sci Technol. 2017;33(7):899.

    Article  CAS  Google Scholar 

  26. Yuan Y, Li Z, Xiao Z, Zhao ZQ. Investigations on voids formation in Cu–Mg alloy during continuous extrusion. JOM. 2017;69(9):1696.

    Article  CAS  Google Scholar 

  27. Liu Y, Li Z, Jiang YX, Zhang Y, Zhou ZY. The microstructure evolution and properties of a Cu–Cr–Ag alloy during thermal-mechanical treatment. J Mater Res. 2017;32(7):1324.

    Article  CAS  Google Scholar 

  28. Freudenberger J, Lyubimova J, Gaganov A. Non-destructive pulsed field CuAg-solenoids. Mater Sci Eng A. 2010;527(7–8):2004.

    Article  Google Scholar 

  29. Lei Q, Li Z, Zhu A, Qiu WT, Liang SQ. The transformation behavior of Cu–8.0Ni–1.8Si–0.6Sn–0.15Mg alloy during isothermal heat treatment. Mater Charact. 2011;62(9):904.

    Article  CAS  Google Scholar 

  30. Mabuchhi M, Higashi K. Strengthening mechanisms of Mg–Si alloys. Acta Mater. 1996;44(11):4611.

    Article  Google Scholar 

  31. Hansen N. Hall–Petch relation and boundary strengthening. Scr Mater. 2004;51(8):801.

    Article  CAS  Google Scholar 

  32. Han K, Vasquez AA, Xin Y, Kalu PN. Microstructure and tensile properties of nanostructured Cu–25wt% Ag. Acta Mater. 2003;51(3):767.

    Article  CAS  Google Scholar 

  33. Wang SC, Zhu Z, Starink MJ. Estimation of dislocation densities in cold rolled Al–Mg–Cu–Mn alloys by combination of yield strength data, EBSD and strength models. J Microsc. 2005;217(2):1.

    Google Scholar 

  34. Shintani T, Murata Y. Evaluation of the dislocation density and dislocation character in cold rolled Type 304 steel determined by profile analysis of X-ray diffraction. Acta Mater. 2011;59(11):4314.

    Article  CAS  Google Scholar 

  35. Wen H, Topping TD, Isheim D, Seidman DN, Lavernia EJ. Strengthening mechanisms in a high-strength bulk nanostructured Cu–Zn–Al alloy processed via cryomilling and spark plasma sintering. Acta Mater. 2013;61(8):2769.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This study was financially supported by the National Key R&D Program of China (No. 2016YFB0301400) and the National Natural Science Foundation of China (No. 51601017).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xu-Jun Mi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xu, GL., Peng, LJ., Huang, GJ. et al. Microstructural evolution and properties of a Cu–Cr–Ag alloy during continuous manufacturing process. Rare Met. 40, 2213–2220 (2021). https://doi.org/10.1007/s12598-019-01238-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12598-019-01238-x

Keywords

Navigation