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Study of morphological characteristics and elemental composition of respirable particulate matter in an opencast coal mineusing FESEM-EDX

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Abstract

Atmospheric aerosol consists of both natural and anthropogenic origin. Studies have shown that continuous exposure to these particles is associated with a high percentage of death from respiratory and cardiovascular disease. In the present study, the PM10 samples were collected from eight sampling stations around a highly mechanised opencast coal mine in Talcher, India. Identification of the probable sources of PM10 was carried out through morphological analysis using FESEM, and elemental analysis was performed by using EDX analysis. Based on the FESEM-EDX analysis, the seasonal behaviour of PM10 was studied. The FESEM study revealed that the monitoring stations, which were mostly affected by mining activities were found dominated by the big-sized and irregular-shaped particles. On the other hand, monitoring stations mostly affected by transportation activities were affected by small-sized and regular-shaped particles. The EDX analyses showed that elements like C, O, Si, Al, Hg and Fe were the major elemental constituents of PM10 in the study area.

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References

  • Attfield M, Castranova V, Hale JM, Suarthana E, Thomas KC, Wang ML (2011) Coal mine dust exposures and associated health outcomes. Report of DHHS (NIOSH) Publication No. 2011-172. Available on https://stacks.cdc.gov/view/cdc/5947. Last assessed on 15/12/2018.

  • Basha AM, Yasovardhan N, Satyanarayana SV, Reddy GVS, Kumar AV (2014) Baseline survey of trace metals in ambient PM10 at Tummalapalle uranium mining site. Atmos Pollut Res 5:591–600

    Article  Google Scholar 

  • Brook RD, Franklin B, Cascio W, Hong Y, Howard G, Lipsett M, Luepker R, Mittleman M, Samet J, Smith SC Jr, Tager I (2004) Air pollution and cardiovascular disease: a statement for healthcare professionals from the Expert Panel on Population and Prevention Science of the American Heart Association. Circulation 109(21):2655–2671

    Article  Google Scholar 

  • Bureau of Indian Standards (2000) Methods for measurement of air pollution: guidelines for planning the sampling of atmosphere (second revision). IS 5182 (Part 14): Methods for Measurement of Air Pollution

  • Campos-Ramos A, Aragon-Pina A, Galindo-Estrada I, Querol X, Alastuey A (2009) Characterization of atmospheric aerosols by SEM in a rural area in the western part of Mexico and its relation with different pollution sources. Atmos Environ 43:6159–6167

    Article  Google Scholar 

  • Chakraborty A, Gupta T (2009) Chemical characterization of submicron aerosol in Kanpur Region: a source apportionment study. Int J Civ Environ Eng 1(2):87–90

    Google Scholar 

  • Chen YC, Hsu CY, Lin SL, Chang-Chien GP, Chen MJ, Fang GC, Chiang HC (2015) Characteristics of concentrations and metal compositions for PM2. 5 and PM2. 5–10 in Yunlin County, Taiwan during air quality deterioration. Aerosol Air Qual Res 15:2571–2583

    Article  Google Scholar 

  • Cheng CS, Campbell M, Li Q, Li G, Auld H, Day N, Comer N (2008) Differential and combined impacts of extreme temperatures and air pollution on human mortality in south–central Canada. Part II: future estimates. Air Qual Atmos Health 1(4):223–235

    Article  Google Scholar 

  • Conner TL, Williams RW (2004) Identification of possible sources of particulate matter in the personal cloud using SEM/EDX. Atmos Environ 38:5305–5310

    Article  Google Scholar 

  • Donaldson K, Mills N, MacNee W, Robinson S, Newby D (2005) Role of inflammation in cardiopulmonary health effects of PM. Toxicol Appl Pharmacol 207(2):483–488

    Article  Google Scholar 

  • Geng H, Ryu J, Maskey S, Jung HJ, Ro CU (2011) Characterization of individual aerosol particles collected during a haze episode in Incheon, Korea using the quantitative ED-EPMA technique. Atmos Chem Phys 11:1327–1337

    Article  Google Scholar 

  • Hafner HR, Wheeler NJ, Roberts PT (2004) Analysis of air toxics monitoring data. Work plan prepared for Lake Michigan Air Directors Consortium, Des Plaines, IL, by Sonoma Technology. Inc., Petaluma, CA, STI-903555-2442-WP2, January. Part 14: Guidelines for Planning the Sampling of Atmosphere (Second Revision)

  • Iordanidis A, Buckman J, Triantafyllou AG, Asvesta A (2008) ESEM–EDX characterisation of airborne particles from an industrialised area of northern Greece. Environ Geochem Health 30(5):391–405

    Article  Google Scholar 

  • Johann-Essex V, Keles C, Sarver E (2017) A computer-controlled SEM-EDX routine for characterizing respirable coal mine dust. Minerals 7(1):15

    Article  Google Scholar 

  • Khillare PS, Balachandran S, Meena BR (2004) Spatial and temporal variation of heavy metals in atmospheric aerosol of Delhi. Environ Monit Assess 90(1-3):1–21

    Article  Google Scholar 

  • Kulshrestha A, Satsangi PG, Masih J, Taneja A (2009) Metal concentration of PM2.5 and PM10 particles and seasonal variations in urban and rural environment of Agra, India. Sci Total Environ 407(24):6196–6204

    Article  Google Scholar 

  • Laney A, Wolfe A, Petsonk E, Halldin C (2012) Pneumoconiosis and advanced occupational lung disease among surface coal miners—16 states, 2012–2011; Report No. 61(23). MMWR, Atlanta, pp 431–434

    Google Scholar 

  • Laskin A, Cowin JP, Iedema MJ (2006) Analysis of individual environmental particles using modern methods of electron microscopy and X-ray microanalysis. J Electron Spectrosc Relat Phenom 150(2-3):260–274

    Article  Google Scholar 

  • Li W, Shao L, Wang Z, Shen R, Yang S, Tang U (2010) Size, composition, and mixing state of individual aerosol particles in a South China coastal city. J Environ Sci 22(4):561–569

    Article  Google Scholar 

  • Mathis U, Kaegi R, Mohr M, & Zenobi, R (2004). TEManalysis of volatile nanoparticles from particle trapequipped diesel and direct-injection spark-ignitionvehicles. Atmos. Environ. 38:4347–4355

  • Niemi JV, Saarikoski S, Tervahattu H, Mäkelä T, Hillamo R, Vehkamäki H, Kulmala M (2006) Changes in background aerosol composition in Finland during polluted and clean periods studied by TEM/EDX individual particle analysis. Atmos Chem Phys 6(12):5049–5066

    Article  Google Scholar 

  • Ostro BD, Hurley S, Lipsett MJ (1999) Air pollution and daily mortality in the Coachella Valley, California: a study of PM10 dominated by coarse particles. Environ Res 81(3):231–238

    Article  Google Scholar 

  • Pachauri T, Singla V, Satsangi A, Lakhani A, Kumari KM (2013) SEM-EDX characterization of individual coarse particles in Agra, India. Aerosol Air Qual Res 13(2):523–536

    Article  Google Scholar 

  • Pandey B, Agrawal M, Singh S (2014) Assessment of air pollution around coal mining area: emphasizing on spatial distributions, seasonal variations and heavy metals, using cluster and principal component analysis. Atmos Pollut Res 5:79–86

    Article  Google Scholar 

  • Pipal AS, Jan R, Satsangi PG, Tiwari S, Taneja A (2014) Study of surface morphology, elemental composition and origin of atmospheric aerosols (PM2.5 and PM10) over Agra, India. Aerosol Air Qual Res 14(6):1685–1700

    Article  Google Scholar 

  • Querol X, Viana M, Alastuey A, Amato F, Moreno T, Castillo S, Pey J, de la Rosa J, de la Campa AS, Artinano B, Salvador P, Dos Santos SG, Fernandez-Patier R, Moreno-Grau S, Negral L, Minguillon MC, Monfort E, Gil JI, Inza A, Ortega LA, Santamaria JM, Zabalza J (2007) Source origin of trace elements in PM from regional background, urban and industrial sites of Spain. Atmos Environ 41:7219–7231

    Article  Google Scholar 

  • Ragosta M, Caggiano R, D'Emilio M, Macchiato M (2002) Source origin and parameters influencing levels of heavy metals in TSP, in an industrial background area of Southern Italy. Atmos Environ 36:3071–3087

    Article  Google Scholar 

  • Reid JS, Koppmann R, Eck TF, Eleuterio DP (2005) A review of biomass burning emissions part II: intensive physical properties of biomass burning particles. Atmos Chem Phys 5(3):799–825

    Article  Google Scholar 

  • Roy D, Singh G, Gosai N (2015) Identification of possible sources of atmospheric PM10 using particle size, SEM-EDS and XRD analysis, Jharia Coalfield Dhanbad, India. Environ Monit Assess 187(11):680

    Article  Google Scholar 

  • Satsangi PG, Yadav S (2014) Characterization of PM 2.5 by X-ray diffraction and scanning electron microscopy–energy dispersive spectrometer: its relation with different pollution sources. Int J Environ Sci Technol 11(1):217–232

    Article  Google Scholar 

  • Seinfeld JH (1986) Atmospheric Chemistry and Physics of Air Pollution, vol 986. Wiley, New York

    Google Scholar 

  • Sellaro R, Sarver E, Baxter D (2015) A standard characterization methodology for respirable coal mine dust using SEM-EDX. Resources 4(4):939–957

    Article  Google Scholar 

  • Shah MH, Shaheen N, Nazir R (2012) Assessment of the trace elements level in urban atmospheric particulate matter and source apportionment in Islamabad. Pakistan. Atmos Pollut Res 3:39–45

    Article  Google Scholar 

  • Srivastava A, Jain VK (2007) Size distribution and source identification of total suspended particulate matter and associated heavy metals in the urban atmosphere of Delhi. Chemosphere 68:579–589

    Article  Google Scholar 

  • Srivastava A, Jain VK, Srivastava A (2009) SEM-EDX analysis of various sizes aerosols in Delhi India. Environ Monit Assess 150:405–416

    Article  Google Scholar 

  • Sternbeck J, Sjödin Å, Andréasson K (2002) Metal emissions from road traffic and the influence of resuspension—results from two tunnel studies. Atmos Environ 36(30):4735–4744

    Article  Google Scholar 

  • Suvarapu LN, Baek S (2017) Determination of heavy metals in the ambient atmosphere: A review. Toxicol Ind Health 33(1):79–96

    Article  Google Scholar 

  • Suzuki K (2006) Characterisation of airborne particulates and associated trace metals deposited on tree bark by ICP-OES, ICP-MS, SEM-EDX and laser ablation ICP-MS. Atmos Environ 40(14):2626–2634

    Article  Google Scholar 

  • Thorpe A, Harrison RM (2008) Sources and properties of non-exhaust particulate matter from road traffic: a review. Sci Total Environ 400(1):270–282

    Article  Google Scholar 

  • Wang J, Cubison MJ, Aiken AC, Jimenez JL, Collins DR (2010) The importance of aerosol mixing state and size-resolved composition on CCN concentration and the variation of the importance with atmospheric aging of aerosols. Atmos Chem Phys 10(15):7267–7283

    Article  Google Scholar 

  • Weingartner E, Burtscher H, Baltensperger U (1997) Hygroscopic properties of carbon and diesel soot particles. Atmos Environ 31(15):2311–2327

    Article  Google Scholar 

  • White WM (2013) Trace Elements in Igneous Processes. In: White WM (ed) Geochemistry. Wiley Blackwell, Chichester, pp 258–312

    Google Scholar 

  • World Health Organization (WHO) (2013) Expert Committee on Biological Standardization (1971). Twenty-third report. Available on http//www.whqlibdoc.who.int. Last assessed on 23/11/2018

  • Zanobetti A, Schwartz J, Dockery DW (2000) Airborne particles are a risk factor for hospital admissions for heart and lung disease. Environ Health Perspect 108(11):1071–1077

    Article  Google Scholar 

  • Zhang Y, Wang X, Chen H, Yang X, Chen J, Allen JO (2009) Source apportionment of lead-containing aerosol particles in Shanghai using single particle mass spectrometry. Chemosphere 74(4):501–507

    Article  Google Scholar 

  • Zhang Q, Shen Z, Cao J, Ho K, Zhang R, Bie Z, Chang H, Liu S (2014) Chemical profiles of urban fugitive dust over Xi'an in the south margin of the Loess Plateau, China. Atmos Pollut Res 5(3):421–430

    Article  Google Scholar 

Download references

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Correspondence to Debi Prasad Tripathy.

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Editorial handling: Domenico M. Doronzo

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Tripathy, D.P., Dash, T.R. Study of morphological characteristics and elemental composition of respirable particulate matter in an opencast coal mineusing FESEM-EDX. Arab J Geosci 12, 514 (2019). https://doi.org/10.1007/s12517-019-4624-5

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