Skip to main content
Log in

On the petrogenesis and evolution of U-rich granite: insights from mineral chemistry studies of Gattar granite, North Eastern Desert, Egypt

  • Original Paper
  • Published:
Arabian Journal of Geosciences Aims and scope Submit manuscript

An Erratum to this article was published on 02 August 2014

Abstract

In Egypt, the younger granites are essentially undeformed and emplaced at shallow levels with typical A-type chemical characteristics. Petrogenesis of A-type granites in Egypt may be more intricate, especially where magmatic fluids and hydrothermal solutions are concerned. Moreover, these post-orogenic granites are attracting increased economic interest because some plutons like Gattar granite are associated with high concentrations of ore metals such U and Mo, and most of such U-rich granites have common features of localization of the U-mineralization within the alteration zones along sheared and fractured parts of the granites and intimate fluorite association. Our study demonstrated that the feldspars formed in a temperature below 700 °C and at a shallow depth, the temperature of transformation of zircon is high between 400 and 700 °C and shifted to less than 600 °C by an increasing F content in final differentiation products. Muscovite of Gattar granite is late to post-magmatic and formed in a temperature between 300 and 400 °C by hydrolysis of K-feldspars, and chlorite originated in nearly 300 °C on the average estimation. The chemical compositions of apatite reported that the apatite classified as fluoro-apatite with average F contents 3.56 % reflecting either primary magma conditions or subsequent metamorphism in the presence of relatively high F fluids. Pitchblende appeared in average 230 °C, and secondary uranium minerals emerged in average 150 °C. It is markedly noticeable that there is temperature gradation from very high temperature alteration near to solidification of granitic magma to very low alteration that represents prevalence of secondary uranium deposits. Our findings articulated the role of H2O- and F-bearing fluids in alteration of essential and accessory minerals and transformation of uranium element from solution and fluids into the crystal lattice of zircon as U+4 in an early stage event. Perhaps, the cause of this gradation is the evolution of U-rich granitic magma into residual fluids through magmatic differentiation and, afterwards, hydrothermal solutions through fluid-rock interaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16

Similar content being viewed by others

References

  • Abd El-Naby HH (2009) Role of argillic alteration in uranophane precipitation along shear zones of the Gattar granites, Eastern Desert, Egypt. Earth Sci 20(2):45–69

    Google Scholar 

  • Abdel Warith A, Michalik M, Ali BH (2010) Fluorine enriched granites: chemical characterization and relation to uranium mineralization. J Appl Sci 6(4):299–323

    Google Scholar 

  • Akaad MK, Noweir AM (1980) Geology and lithostratigraphy of the Arabian Desert orogenic belt of Egypt between latitudes 25 3 50 and 26 3 00N. Inst Appl Geol Jeddah Bull 3:127–135

    Google Scholar 

  • Burns PC (1999) The crystal chemistry of uranium. In: Burns PC, Finch RJ (eds) Uranium: mineralogy, geochemistry and the environment. Rev. Mineral., vol 38. Mineralogical Society of America, pp 23–90

  • Cathelineau M (1988) Cation site occupancy in chlorites and illites as a function of temperature. Clays Miner 23:471–485

    Article  Google Scholar 

  • Cathelineau M, Nieva D (1985) A chlorite solid solution geothermometer: the Los Azufres (Mexico) geothermal system. Contrib Miner Petrol 91:235–244

    Article  Google Scholar 

  • Corfu F, Hanchar JM, Hoskin PWO, Kinny P (2003) Atlas of zircon textures. In: Hanchar JM, Hoskin PWO (eds) Zircon, 53. Reviews in mineralogy and geochemistry. Mineral Soc Am, Washington, DC, pp 469–500

    Google Scholar 

  • Cuney M (2009) The extreme diversity of uranium deposits. Miner Deposita 44:3–9

    Article  Google Scholar 

  • Cuney M (2010) Evolution of fractionation processes through time; driving the secular variation of uranium deposit types. Econ Geol 105:553–569

    Article  Google Scholar 

  • Cuney M, Kyser TK (2009) Recent and not-so recent developments in uranium deposits and implications for exploration. Mineral Assoc Can-Short Course Series 39:257

    Google Scholar 

  • Dill HG, Weber B (2010) Accessory minerals of fluorite and their implication concerning the environment of formation (Nabburg-Wölsendorf fluorite district, SE Germany), with special reference to fetid fluorite (“Stinkspat”). Ore Geol Rev 37:65–86

    Article  Google Scholar 

  • El Kaliouby BA, El Sayed MH, Dawood YH (2003) Geochemistry and uranium mineralization of the younger granite-Hammamat sediments contact zone, Gattar area, north Eastern Desert, Egypt. MERC Ain Shams Univ, Earth Sci Ser 17:1–23

    Google Scholar 

  • El Kammar AM, Salman AE, Shalaby MH, Mahdy AI (2001) Geochemical and genetical constraints on rare metals mineralization at the central Eastern Desert of Egypt. Geochem J 35:117–135

    Article  Google Scholar 

  • El Mansi MM (2000) Coloration of fluorite and its relation to radioactivity. Egypt Mineral 12:93–106

    Google Scholar 

  • El Rakaiby ML, Shalaby MH (1992) Geology of Gebel Qattar batholith, Central Eastern Desert. Egypt Int J Remote Sens 13(l2):2337–2347

    Article  Google Scholar 

  • El-Feky MG (2011) Mineralogical, REE-geochemical and fluid inclusion studies on some uranium occurrences, Gabal Gattar, Northeastern Desert, Egypt. Chin J Geochem 30:430–443

    Article  Google Scholar 

  • El-Gaby S (1975) Petrochemistry and geochemistry of some granites from Egypt. Neues Jahrbuch für Mineral 124:147–189

    Google Scholar 

  • Elkins LT, Grove TL (1990) Ternary feldspar experiments and thermodynamic models. Am Mineral 75:544–559

    Google Scholar 

  • Ewing RC, Weber WG, Lutze W (1996) Crystalline ceramics: waste form for the disposal of weapons plutonium, ibid:65-83

  • Eyal M, Litvinovsky B, Jahn B, Zanvilevich A, Katzir Y (2010) Origin and evolution of post-collisional magmatism: coeval Neoproterozoic calc-alkaline and alkaline suites of the Sinai Peninsula. Chem Geol 269:153–179

    Article  Google Scholar 

  • Fayek M, Janeczek J, Ewing RC (1997) Mineral chemistry and oxygen isotopic analyses of uraninite, pitchblende and uranium alteration minerals from the Cigar Lake Deposit, Saskatchewan, Canada. Appl Geochem 12:549–565

  • Finch R, Ewing RC (1992) The corrosion of uraninite under oxidizing conditions. J Nucl Mater 190:133–156

  • Finch R, Murakami T (1999) Systematics and paragenesis of uranium minerals. In: Burns PC, Finch R (eds) Uranium: mineralogy, geochemistry and the environment. Rev. Mineral., vol 38. Mineralogical Society of America, pp 91–180

  • Frost BR, Frost DC, Hulseboschi TP, Swapp SM (2000) Origin of the charnockites of the Louis Lake batholith, Wind River Range, Wyoming. J Petrol 41(12):1759–1776

    Article  Google Scholar 

  • Fuhrman ML, Lindsley DL (1988) Ternary feldspar modeling and thermometry. Am Mineral 73:201–215

    Google Scholar 

  • Greenberg JK (1981) Characteristics and origin of Egyptian younger granites. Geol Soc Am Bull 92:790–840

    Google Scholar 

  • Greiling RO, Abdeen MM, Dardir AA, El Akhal H, El-Ramly MF, Kamal El Din GM, Osman AF, Rashwan AA, Rice AH, Sadek MF (1994) A structural synthesis of the Proterozoic Arabian-Nubian Shield in Egypt. Geol Rundsch 83:484–501

    Article  Google Scholar 

  • Harris N (1985) Alkaline complexes from the Arabian Shield. J Afr Earth Sci 3:83–88

    Google Scholar 

  • Heinrich GW (1958) Mineralogy of radioactive raw materials. McGraw Hill Book Co., New York, 654p

    Google Scholar 

  • Helmy HM (1999) Mineralogy, fluid inclusions and geochemistry of the molybdenum-uranium-fluorite mineralizations, Gebel Gattar area, Eastern Desert, Egypt. Inter. Conf. on Geochemistry, Alexandria University, 15-16 Sept., 171-198

  • Hutchinson RW, Blackwell DJ (1984) Time, crustal evolution and generation of uranium deposits. In: De Vivo B, Ippolito F, Capaldi G, Simpson PR (eds.) Uranium geochemistry, mineralogy, geology, exploration and resources. The Institute of Mining and Metallurgy, p.20

  • Janeczek J, Ewing RC (1992) Structural formula of uraninite. J Nucl Mater 190:128–132

    Article  Google Scholar 

  • Johan Z, Johan V (2005) Accessory minerals of the Cinovec (Zinnwald) granite cupola, Czech Republic: indicators of petrogenetic evolution. Mineral Petrol 83:113–150

    Article  Google Scholar 

  • Johnson PR (1998) Tectonic map of Saudi Arabia and adjacent areas. Saudi Arabian Deputy Ministry for Mineral Resource, Technical Report USGS-TR-98-3, scale 1:40,000,000

  • Johnson PR, Woldehaimanot B (2003) Development of the Arabian-Nubian Shield: perspectives on accretion and deformation in the northern East African Orogen and the assembly of Gondwana. In: Yoshida M, Dasgupta S, Windley B (eds) Proterozoic East Gondwana: supercontinent assembly and breakup. Geol. Soc. Lond., Special Publications 206, 289–325

  • Kebede T, Koeberl C, Koller F (2001) Magmatic evolution of the Suqii-Wagga garnet-bearing two mica granite, Wallagga area, Western Ethiopia. J. African earth sciences, 32, No.2, 193-221

  • Kroner A (1985) Ophiolites and the evolution of tectonic boundaries in the late Proterozoic Arabian-Nubian Shield of northeastern Africa and Arabia. Precambr Res 27:277–300

    Article  Google Scholar 

  • Kuster D (2009) Granitoid-hosted Ta mineralization in the Arabian-Nubian Shield: ore deposit types, tectono-metallogenetic setting and petrogenetic framework. Ore Geol Rev 35:68–86

    Article  Google Scholar 

  • Kuster D, Harms U (1998) Post-collisional potassic granitoids from the southern and northwestern parts of the late Neoproterozoic East African Orogen: a review. Lithos 45:177–195

    Article  Google Scholar 

  • Mahdy NM (2011) Mineralogical studies and mineral chemistry of some radioactive mineralizations in Gabal Gattar area, Northern Eastern Desert, Egypt. MSC, Ain Shams University

  • Mahdy NM, Shalaby MH, Helmy HM, Farag AO, El-Sawy S, and Abu Zied EO (2013) Trace and REE element geochemistry of fluorite and its relation to uranium mineralizations, Gabal Gattar Area, Northern Eastern Desert, Egypt. Arabian Journal of Geoscience (online access)

  • Miller CF, Stoddard EF, Bradfish LJ, Dollase WA (1981) Composition of plutonic muscovite: genetic implications. Can Mineral 19:25–34

    Google Scholar 

  • Min M-Z, Katsumura Y (1997) A possible mechanism of wall-rock hematitization in uranium deposits: radiation-induced oxidation of ferrous ion. Geochem J 31:183–188

    Article  Google Scholar 

  • Miyashiro A (1973) Metamorphism and metamorphic belts, G. Allen and Unwin, London, 429p

    Book  Google Scholar 

  • Mohamed FH, El-Sayed MM (2005) Post-orogenic and anorogenic A-type-fluorite bearing granitoids, Eastern Desert, Egypt: petrogenetic and geotectonic implications. Chemie Der Erde 68:431–450

    Article  Google Scholar 

  • Monier G, Robert JL (1986) Muscovite Solid solutions in the system K2O-MgO-FeO-Al2O3-SiO2-H2O: an experimental study at 2 kbar PH2O and comparison with natural Li-free whit micas. Mineral Mag 50:257–266

    Article  Google Scholar 

  • Moussa AMM, Stern RJ, Manton WI, Ali KA (2008) SHRIMP zircon dating and Sm/Nd isotopic investigations of Neoproterozoic granitoids, Eastern Desert, Egypt. Precambrian Res 160:341–356

    Article  Google Scholar 

  • Nash JT, Granger HC, Adams SS (1981) Geology and concepts of genesis important types of uranium deposits. Econ. Geol., 75th Anniversary Volume, 63-117

  • Neiva AMR (1982) In: Evans AM (ed) Metallization associated with acid magmatism. Wiley, New York, pp 243–259

    Google Scholar 

  • Philips ER, Ransom DM, Vernon RH (1972) Myrmekite and muscovite development by retrograde metamorphism at Broken Hill, New South Wales. Mineral Mag 38:570–578

    Article  Google Scholar 

  • Potter EG, Mitchel RH (2005) Mineralogy of the deadhorse creek volcaniclastic breccia complex, northwestern Ontario. Canada Contrib Mineral Petrol 150:212–229

    Article  Google Scholar 

  • Ramdohr P (1980) The ore minerals and their intergrowth. 2nd Edition, Vol.2, 1075p, International series in earth science, Academic Press, New York

  • Speer JA (1984) Micas in igneous rocks. In: Bailey SW (ed) Micas. Rev. Mineral, 13, 299–356

  • Speer JA (1984) Micas in igneous rocks. In: Bailey, S.W. (ed). Reviews in mineralogy, volume 13, Micas. Mineralogical Society of America, 229-356

  • Stern RJ, Hedge CE (1985) Geochronologic and isotopic constraints on late Precambrian crustal evolution in the Eastern Desert of Egypt. Am J Sci 285:97–127

    Article  Google Scholar 

  • Stern RJ, Johnson PR (2010) Continental lithosphere of the Arabian Plate: a geologic, petrologic, and geophysical synthesis. Earth Sci Rev 101:29–67

    Article  Google Scholar 

  • Streckeisen A (1976) To each Plutonic rock its proper name. Earth Sci Rev 12:1–33

    Article  Google Scholar 

  • Sylvester PJ (1998) Post-collisional strongly peraluminous granites. Lithos 45:29–44

    Article  Google Scholar 

  • Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell, Melbourne

    Google Scholar 

  • Thomas R (1992) Abschättzung des Wassergehaltes granitischer Schmelzen aus Einschlußdaten. Zentralb Geol Paläont Teil., I, 909 - 916

  • Thomas R, Förster H-J, Tischendorf G (1991) PTX-signatures of Hercynian ore-producing granites, Erzgebirge, Germany. In: Pagel M, Leroy JL (eds) Source, transport and deposition of metals. Balkema, Rotterdam, pp 231–234

    Google Scholar 

  • Tiangang L, Zhizhang H (1986) Vein uranium deposits in granites of Xiazhuang ore field, China. Vein type uranium deposits, IAEA, Vienna, IAEA—TECDOC—361

  • Windley BF (1995) The evolving continents, 3rd edn. John Wiley & Sons Ltd., Chichester

    Google Scholar 

  • Zen E (1988) Phase relations of peraluminous rocks and their petrogenetic implications. Annu Rev Earth Planet Sci 16:21–51

  • Zhao Z-F, Zheng Y-F, Wei C-S, Gong B (2004) Temporal relationship between granite cooling and hydrothermal uranium mineralization at Dalongshan in China: a combined radiometric and oxygen isotopic study. Ore Geol Rev 25:221–236

    Article  Google Scholar 

Download references

Acknowledgments

The authors thank the staff of scan electron microscope, Nuclear Materials Authority, Egypt, for their scientific cooperation to finish of this manuscript. The thank also goes to the anonymous reviewers for their comments in improving the manuscript.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Nasser Mourad Mahdy.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shalaby, M.H., Abu Zeid, E.K. & Mahdy, N.M. On the petrogenesis and evolution of U-rich granite: insights from mineral chemistry studies of Gattar granite, North Eastern Desert, Egypt. Arab J Geosci 8, 3565–3585 (2015). https://doi.org/10.1007/s12517-014-1466-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12517-014-1466-z

Keywords

Navigation