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A novel 3D printed technology to construct a monolithic ultrathin nanosheets Co3O4/SiO2 catalyst for benzene catalytic combustion

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Abstract

In this study, a novel three-dimensional (3D)-OMm-Co3O4/SiO2-0.5AP (OMm = ordered macro–meso porous, AP = aluminum phosphate) monolithic catalyst was for the first time constructed successfully with the hierarchical Co-phyllosilicate ultrathin nanosheets growth on the surface of 3D printed ordered macropore–mesoporous SiO2 support. On the one hand, we discovered that the construction of ordered macropore–mesoporous structures is beneficial to the diffusion and adsorption of reactants, intermediates, and products. On the other hand, the formation of hierarchical Co-phyllosilicate ultrathin nanosheets could provide more active Co&+ species, abundant acid sites, and active oxygen. The above factors are in favor of improving the catalytic performance of benzene oxidation, and then a 3D-OMm-Co3O4/SiO2-0.5AP catalyst exhibited the superior catalytic activity. To explore the effect of catalysts structure and morphology, various Co-based catalysts were also constructed. Simultaneously, the 3D-OMm-Co3O4/SiO2-0.5AP catalyst has excellent catalytic performance, water resistance, and thermal stability in the catalytic combustion of benzene due to the strong interactions between Co&+ species and SiO2 in the phyllosilicate. Therefore, this study proposes a new catalyst synthesis method through 3D printing, and presents considerable prospects for the removal of VOCs from industrial applications.

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Acknowledgements

This work is supported by the LICP Cooperation Foundation for Young Scholars (No. HZJJ21-02), the National Natural Science Foundation of China (Nos. 52070182 and 51908535), the DNL Cooperation Found, Chinese Academy of Sciences (No. DNL202004), Province Natural Science Foundation of GanSu (Nos. 20JR10RA053 and 20JR10RA046), and Major Program of the Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences (No. ZYFZFX-10).

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  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China

    Yuntai Xi, Fang Dong & Zhicheng Tang

  2. School of Petroleum and Chemical, Lanzhou University of Technology, Lanzhou, 730050, China

    Yuntai Xi, Shixing Wu & Jiyi Zhang

  3. Dalian National Laboratory for Clean Energy, Dalian, 116023, China

    Fang Dong

  4. Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi, 832003, China

    Xin Xu

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  1. Yuntai Xi
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Correspondence to Fang Dong, Zhicheng Tang or Jiyi Zhang.

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A novel 3D printed technology to construct a monolithic ultrathin nanosheets Co3O4/SiO2 catalyst for benzene catalytic combustion

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Xi, Y., Dong, F., Xu, X. et al. A novel 3D printed technology to construct a monolithic ultrathin nanosheets Co3O4/SiO2 catalyst for benzene catalytic combustion. Nano Res. 16, 12173–12185 (2023). https://doi.org/10.1007/s12274-023-5631-0

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  • DOI: https://doi.org/10.1007/s12274-023-5631-0

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