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Bottom-up synthesis of 2D heterostructures enables effective polysulfides inhibition and conversion

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Abstract

Due to the high theoretical capacity and energy density, lithium-sulfur (Li−S) batteries have good commercial prospects. However, shuttle effect of soluble lithium polysulfides (LiPSs) formed by sulfur reduction has severely limited the further development of Li−S batteries. In this work, the two-dimensional (2D) MXene-metal-organic framework (MOF) (Ti3C2Tx-CoBDC (BDC: 1,4-benzenedicarboxylate)) heterostructures were employed to modify the separator to inhibit the shuttle effect and facilitate the conversion of the soluble polysulfides. Firstly, a bottom-up synthesis strategy was adopted to synthesize the 2D MXene-MOF heterogeneous layered structure. With high specific surface area, in which the catalytic metal atoms not only restrain the shuttle effect of polysulfides but also exhibit excellent redox electrocatalytic performance. The cell with Ti3C2Tx-CoBDC@PP (PP: polypropylene) separator has a high initial capacity of 1255 mAh·g−1 at 0.5 C. When the current density is 2 C, the battery has a capacity retention rate of 94.4% after 600 cycles, with the fading rate of only 0.01% per cycle. Besides, with a sulfur loading of 7.5 mg·cm−2, the battery shows the discharge capacity of 1096 mAh·g−1 at 0.2 C and exhibits excellent cycling stability. This work offers novel insights into the application of MOF and MXene heterostructures in Li−S batteries.

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Acknowledgements

This work was supported by Hainan Provincial Joint Project of Sanya Yazhou Bay Science and Technology City (No. 520LH056) and the National Key Research and Development Program of China (No. 2022YFB3803502).

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  1. Ge Zhang and Cheng Zhou contributed equally to this work.

Authors and Affiliations

  1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China

    Ge Zhang, Cheng Zhou, Juncai Long, Yan Li, Lei Lv, Kaijian Yan, Xinhui Chen & Liqiang Mai

  2. International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China

    Chenxu Dong & Xu Xu

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  1. Ge Zhang
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  2. Cheng Zhou
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Correspondence to Xu Xu or Liqiang Mai.

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Zhang, G., Zhou, C., Long, J. et al. Bottom-up synthesis of 2D heterostructures enables effective polysulfides inhibition and conversion. Nano Res. 16, 8488–8496 (2023). https://doi.org/10.1007/s12274-023-5535-z

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