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Investigation of Eco-friendly Dyeing of Para-aramid Using Supercritical CO2

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Abstract

In order to solve the problems of dyeing difficulty and serious pollution of traditional water-based dyeing of para-aramid, supercritical CO2 fluid was employed as a dyeing solvent to dye para-aramid yarn (temperatures 80–120 °C, pressures 16–24 MPa, dyeing time 15–90 min, and dye concentration 1 %–7 % o.m.f.). The K/S values reached 2.07 and 1.91 at 120 °C, 24 MPa, 60 min, 5 % o.m.f., and a CO2 flow of 20 g/min with C. I. Disperse Red 54 and C. I. Disperse Blue 79, respectively. The results proved that para-aramid yarn could be dyed in supercritical CO2 fluid. Moreover, the thermal and mechanical properties of dyed para-aramid yarns in supercritical CO2 showed a slightly increasing trend. The washing, rubbing, and the light color fastness of the dyed samples were rated above 4–5, and the color fastness durability of the dyed para-aramid was also presented good.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21908015), Basic Scientific Research Project of Higher Education Department of Liaoning Province (J202152), Dalian Youth Science and Technology Star Fund (2020RQ019), Guidance Program of Liaoning Natural Science Foundation (2019-ZD-0285), and the Seventh Batch “Hundred People Plan” of Talent Introduction in Fujian Province.

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Authors and Affiliations

  1. Liaoning Provincial Key Laboratory of Supercritical CO2 Dyeing, Dalian Polytechnic University, Dalian, 116034, China

    Yue Zhang, Huanda Zheng & Laijiu Zheng

  2. College of Clothing and Textile, Eastern Liaoning University, Dandong, 118003, China

    Yue Zhang

  3. Shishi CTES Research Institute of Apparel and Accessories Industry, Shishi, 362700, China

    Tao Cai & Fuer Zheng

Authors
  1. Yue Zhang
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  2. Huanda Zheng
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  3. Laijiu Zheng
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  4. Tao Cai
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  5. Fuer Zheng
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Corresponding authors

Correspondence to Huanda Zheng or Laijiu Zheng.

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The authors declared that they have no conflicts of interest to this work. We declare that we do not have any commercial or associative interest that represents a conflict of interest in connection with the work submitted.

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Zhang, Y., Zheng, H., Zheng, L. et al. Investigation of Eco-friendly Dyeing of Para-aramid Using Supercritical CO2. Fibers Polym 23, 2196–2205 (2022). https://doi.org/10.1007/s12221-022-4716-9

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  • DOI: https://doi.org/10.1007/s12221-022-4716-9

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