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The Superhydrophobic State Stability of Coatings Based on Copolymers of Glycidyl Methacrylate and Alkyl Methacrylates on Cotton Fabric Surface

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Abstract

We suggest a simple and reproducible strategy for fabricating durable superhydrophobic coatings on the basis of series of functional random copolymers of alkyl methacrylates and glycidyl methacrylate on cotton fabric surface. The procedure consists of the fabric treatment by solutions of copolymers in methylethylketone and following heating at 140 °C. The initial contact angles of obtained coatings on fabric surface achieve 165°. The dependence of superhydrophobic properties of coatings based on copolymers of glycidyl methacrylate and alkyl (meth)acrylates (with alkyl radicals С4–С18 in side chains) attached to the cotton fabric surface was studied. The comparative analysis of superhydrophobic state stability of polymer coatings during long-term contacts with aggressive media is presented. We evaluated the contact angles stability as a function of prolonged contact of polymer coatings with water under saturated vapor conditions, organic solvents, and synthetic detergents. Polymeric coatings based on a copolymer of lauryl methacrylate (С12) and glycidyl methacrylate provide better stability of superhydrophobic properties compared with other copolymers of alkyl methacrylates.

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Acknowledgments

The research was conducted with the financial support from the Russian Science Foundation, project 16-13-10337.

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Authors and Affiliations

  1. Department of Chemical Engineering, Volgograd State Technical University, Volgograd, 400005, Russia

    Evgeny Bryuzgin, Viktor Klimov, Alexander Navrotskiy & Ivan Novakov

  2. Joint Russian-Vietnamese Tropical Research and Technological Center (South Branch), Ho Chi Minh, 72509, Vietnam

    Manh Duc Le

Authors
  1. Evgeny Bryuzgin
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  2. Viktor Klimov
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  3. Manh Duc Le
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  4. Alexander Navrotskiy
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  5. Ivan Novakov
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Correspondence to Evgeny Bryuzgin.

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Bryuzgin, E., Klimov, V., Le, M.D. et al. The Superhydrophobic State Stability of Coatings Based on Copolymers of Glycidyl Methacrylate and Alkyl Methacrylates on Cotton Fabric Surface. Fibers Polym 21, 1032–1038 (2020). https://doi.org/10.1007/s12221-020-9741-y

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  • DOI: https://doi.org/10.1007/s12221-020-9741-y

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