Skip to main content
Log in

Mechanical, thermal and degradation characteristics of jute fabric-reinforced polypropylene composites: Effect of potassium dichromate as oxidizing agent

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

In this study, potassium dichromate (K2Cr2O7) was used to investigate the oxidizing effect on the properties of the compression molded jute fabrics-reinforced polypropylene (PP) composites. Jute fabrics were treated with K2Cr2O7 in oxalic acid and sulphuric acid media. Solutions of oxalic acid and sulphuric acid were prepared in water as 1.0–10.0 % w/v and 0.1–2.0 % v/v respectively, where percentage of K2Cr2O7 was maintained at 0.02 % w/v. Among the treatments, 5.0 % oxalic acid treated jute-PP composite showed better mechanical performance over the other combinations and also than that of the untreated sample. The treatment of jute fabrics improved the thermal stability of the composites by shifting the thermal degradation temperatures of the composites to higher temperature regions compared to PP or jute fabrics. Treated jute composites were found less degradable in soil, water and simulated weathering conditions as well as less water sensible compared to the untreated composite sample.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. Puglia, J. Biagiotti, and L. M. Kenny, J. Nat. Fiber., 1, 23 (2005).

    Article  Google Scholar 

  2. S. O. Han, B. Defoort, L. T. Drzal, and P. A. Askeland, Proc. of 33rd ISTC Conference, 33, 1466 (2001).

    CAS  Google Scholar 

  3. S. V. Joshi, L. T. Drzal, A. K. Mohanty, and S. Arora, Compos. Part A-Appl. S., 35, 371 (2004).

    Article  Google Scholar 

  4. A. K. Mohanty, M. Misra, and L. T. Drzal, J. Polym. Environ., 10, 19 (2002).

    Article  CAS  Google Scholar 

  5. S. J. Eichhorn, C. A. Baillie, N. Zafeiropoulos, L. Y. Mwaikambo, M. P. Ansell, A. Dufresne, K. M. Entwistle, P. J. Herrera-Franco, G. C. Escamilla, L. Groom, M. Hughes, C. Hill, T. G. Rials, and W. P. Mild, J. Mat. Sci., 36, 2107 (2001).

    Article  CAS  Google Scholar 

  6. M. A. Khan and J. A. Khan, “Proc. of 8th Global WPC and Natural Fiber Composites Congress and Exhibition”, Stuttgart, Germany, 22–23 June, 2010.

    Google Scholar 

  7. R. A. Gross and B. Karla, Science, 297, 1803 (2002).

    Article  Google Scholar 

  8. G. Bogoeva-Gaceva, M. Avella, M. Malinconico, A. Buzarovska, A. Grozdanov, G. Gentile, and M. E. Errico, Polym. Compos., 28, 98 (2007).

    Article  CAS  Google Scholar 

  9. D. N. Saheb and J. P. Jog, Adv. Polym. Technol., 18, 351 (1999).

    Article  CAS  Google Scholar 

  10. A. K. Bledzki and J. Gassan, Prog. Polym. Sci., 24, 221 (1999).

    Article  CAS  Google Scholar 

  11. J. A. Khan, M. A. Khan, and R. Islam, Polym. Compos., 34, 671 (2013).

    Article  CAS  Google Scholar 

  12. S. Sultana, M. M. Huque, and M. M. Helali, Polym. Plast. Technol. Eng., 46, 385 (2007).

    Article  CAS  Google Scholar 

  13. M. R. Rahman, M. M. Huque, M. N. Islam, and M. Hasan, Compos. Part A-Appl. S., 39, 1739 (2008).

    Article  Google Scholar 

  14. S. S. Tripathy, G. Levita, and L. D. Landro, Polym. Compos., 22, 815 (2001).

    Article  CAS  Google Scholar 

  15. H. U. Zaman, M. A. Khan, R. A. Khan, M. A. Rahman, L. R. Das, and M. Al-Mamun, Fiber. Polym., 11, 455 (2010).

    Article  CAS  Google Scholar 

  16. S. Moharana, S. B. Mishra, and S. S. Tripathy, J. Appl. Polym. Sci., 40, 345 (1990).

    Article  CAS  Google Scholar 

  17. H. U. Zaman, A. K. Mubarak, and A. K. Ruhul, Polymer Plast. Tech. Eng., 50, 651 (2011).

    Article  CAS  Google Scholar 

  18. T. P. Nevell, “Methods in Carbohydrate Chemistry”, Vol. III, pp.164–184, Academic Press, NewYork, 1963.

    Google Scholar 

  19. L. F. McBurney, “Cellulose and Cellulose Derivatives”, Interscience Publishers Inc., 1954.

    Google Scholar 

  20. J. A. Khan, M. A. Khan, and R. Islam, Fiber. Polym., 13, 1300 (2012).

    Article  CAS  Google Scholar 

  21. J. T. Marsh and F. C. Wood, “An Introduction to the Chemistry of Cellulose”, 2nd ed., Chapman & Hall Ltd., 1942.

    Google Scholar 

  22. T. T. L. Doan, H. Brodowsky, and E. Mäder, Compos. Sci. Technol., 67, 2707 (2007).

    Article  CAS  Google Scholar 

  23. P. V. Joseph, K. Joseph, S. Thomas, C. K. S. Pillai, V. S. Prasad, G. Groeninckx, and S. Mariana, Compos. Part AAppl. S., 34, 253 (2003).

    Article  Google Scholar 

  24. S. Mohanty and S. K. Nayak, J. Appl. Polym. Sci., 102, 3306 (2006).

    Article  CAS  Google Scholar 

  25. J. R. Daniel, “Encyclopedia of Polymer Science and Engineering”, 2nd ed., Vol. 3, pp.109–112, John Wiley, New York, 1985.

    Google Scholar 

  26. S. K. Bhaduri, A. Mathew, M. D. Day, and S. N. Pandey, Cellulose Chem. Technol., 28, 391 (1994).

    CAS  Google Scholar 

  27. S. H. Aziz and M. P. Ansell, Compos. Sci. Technol., 64, 1231 (2004).

    Article  CAS  Google Scholar 

  28. A. Espert, F. Vilaplana, and S. Karlsson, Compos. Part AAppl. S., 35, 1267 (2002).

    Article  Google Scholar 

  29. A. C. Karmaker, J. Mater. Sci. Lett., 16, 462 (1997).

    Article  CAS  Google Scholar 

  30. M. M. Hassan, M. R. Islam, and M. A. Khan, J. Adhes. Sci. Technol., 17, 737 (2003).

    Article  CAS  Google Scholar 

  31. C. Heitner, “Photochemistry of Lignocellulosic Materials”, ACS Symposium Series, Vol. 531, p.3, Am. Chem. Soc., 1993.

    Book  Google Scholar 

  32. D. N. S. Hon, “Wood and Cellulostic Chemistry”, 2nd ed., p.512, New York, Marcel Dekker, 2000.

    Google Scholar 

  33. P. V. Joseph, R. S. Marcelo, L. H. C. Mattoso, K. Joseph, and S. Thomas, Compos. Sci. Technol., 62, 1357 (2002).

    Article  CAS  Google Scholar 

  34. D. Blai, D. J. Carlsson, and D. M. Wiles, J. Polym. Sci., Part A, 1, 1077 (1972).

    Article  Google Scholar 

  35. M. D. H. Beg and K. L. Pickering, Polym. Degrad. Stab., 93, 1939 (2008).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jahangir A. Khan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khan, J.A., Khan, M.A. & Islam, R. Mechanical, thermal and degradation characteristics of jute fabric-reinforced polypropylene composites: Effect of potassium dichromate as oxidizing agent. Fibers Polym 15, 2386–2394 (2014). https://doi.org/10.1007/s12221-014-2386-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-014-2386-y

Keywords

Navigation