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Adsorptive Treatment of Landfill Leachate using Activated Carbon Modified with Three Different Methods

  • Environmental Engineering
  • Published:
KSCE Journal of Civil Engineering Aims and scope

Abstract

Activated Carbon (AC) is an adsorbent having high surface area which makes the process of removing heavy metals from wastewater (such as landfill leachate) very effective. This study explored the utilization of three methods of modification of AC produced from coconut shell by treating it with nitric acid (HNO3), potassium permanganate (KMnO4) and heating at 600°C to improve the adsorption capacity. The AC can remove multi-pollutants in the filtration process which was used to treat landfill leachate. The water quality parameters such as pH, TSS, Ammonia-Nitrogen and a few heavy metals were considered in the present study. Results showed that the removal of these parameters was proportional with the increase of contact time and the bed depth of AC. The isotherm analysis of the adsorption of modified AC showed the best Removal Efficiency (RE) can be achieved when AC treated with KMnO4 for NH3-N, zinc, TSS and sulphide. The morphology of the AC was studied through Scanning Electron Microscopy (SEM), Energy Dispersive X-ray spectroscopy (EDX) pattern analysis and Fourier Transform Infrared (FTIR) analysis. It was found that various types of oxygen functional groups were introduced onto the surface of coconut shell derived AC through oxidation using HNO3. FTIR was used to characterize the surface oxygen functional groups. The surface functional groups such as N-H and C-H stretching played a significant role in heavy metals adsorption. Hence, it can be concluded that the hybrid technique by using electrolysis process with AC adsorption be an effective way to remove the suspended solids and heavy metals from landfill leachate and thus able to reduce environmental pollution.

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Authors and Affiliations

  1. Dept. of Civil Engineering, University Putra Malaysia, 43400 UPM, Serdang, Selangor, Malaysia

    I. K. Erabee, A. Ahsan, S. Idrus & N. N. N. Daud

  2. Civil Engineering Dept., Thi-Qar University, Nasiriyah, Iraq

    I. K. Erabee

  3. Department of Civil Engineering, Uttara University, Dhaka, Bangladesh

    A. Ahsan

  4. Housing Research Centre and Institute of Advanced Technology, University Putra Malaysia, Serdang, Selangor, Malaysia

    A. Ahsan

  5. Dept. of Civil Engineering, National Institute of Technology Karnataka, Surathkal, Mangalore, 575025, Karnataka, India

    Bipin Jose

  6. Faculty of Civil Engineering and UTM Construction Research Center (CRC), Universiti Teknologi Malaysia (UTM), 81310, Skudai, Johor, Malaysia

    M. Manniruzzaman A. Aziz

  7. Institute for Sustainability and Innovation, College of Engineering and Science, Victoria University, Melbourne, 14428, Australia

    A. W. M. Ng

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  1. I. K. Erabee
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  2. A. Ahsan
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Erabee, I.K., Ahsan, A., Jose, B. et al. Adsorptive Treatment of Landfill Leachate using Activated Carbon Modified with Three Different Methods. KSCE J Civ Eng 22, 1083–1095 (2018). https://doi.org/10.1007/s12205-017-1430-z

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  • DOI: https://doi.org/10.1007/s12205-017-1430-z

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