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Heavy main-group iodometallates hybridized by alkali metal via 1,10-Phenanthroline-5,6-dione

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Abstract

Alkali metals were introduced into heavy main-group iodometallates to get two new IA/IVAheterometallic frameworks [PbI3K(pdon)(H2O)2] n (1) and {[Pb3 I 9 K 2(pdon)2(H3O)] ⋅H 2O} n (2) (pdon =1,10-phenanthroline-5,6-dione), which were obtained as single phases by hydrothermal method at different pH values. Compounds 1 and 2 are three-dimensional heterometallic frameworks constructed from the linkage of pdon ligand between iodometallate chains and potassium oxides/iodide clusters. Specially, these two heterometallic frameworks exhibit broadened absorption bands at 700 and 750 nm compared with those of bulk PbI2 and pdon ligand. The band gap of 2 is wider than that of 1, which is due to the absence of π⋯π interaction in 2. Their thermal stabilities are also discussed.

Two new IA/IVA-heterometallic frameworks obtained under different pH conditions are described, which exhibit broadened absorption bands. The structure-property correlations are also discussed.

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Acknowledgement

We acknowledge support for this research by National Natural Science Foundation of China (NOS: 21271043).

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Authors and Affiliations

  1. College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350116, China

    MENGFAN YIN, GENGXING CAI, PENG WANG, XIHUI CHAO, JIBO LIU, HAOHONG LI & ZHIRONG CHEN

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  1. MENGFAN YIN
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  2. GENGXING CAI
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  3. PENG WANG
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  4. XIHUI CHAO
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  5. JIBO LIU
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  6. HAOHONG LI
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Corresponding authors

Correspondence to HAOHONG LI or ZHIRONG CHEN.

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Supplementary Information

Supplementary data associated with this article (optical band gaps and TGA curves) can be found in the online version available at www.ias.ac.in/chemsci. Crystallographic data have been deposited with the Cambridge Crystallographic Data Center as supplementary publication number CCDC-704836 (1), 696106 (2). These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.

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YIN, M., CAI, G., WANG, P. et al. Heavy main-group iodometallates hybridized by alkali metal via 1,10-Phenanthroline-5,6-dione. J Chem Sci 127, 1531–1538 (2015). https://doi.org/10.1007/s12039-015-0916-9

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  • DOI: https://doi.org/10.1007/s12039-015-0916-9

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