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Synthesis of novel 2-(benzhydryloxy) phenoxy-substituted zinc phthalocyanine, third-order nonlinear optical and fluorescence properties

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Abstract

In this study, firstly, 4-(2-(benzhydryloxy)phenoxy)phthalonitrile compound was synthesized. Then, a new 2, 10, 16, 24–tetrakis (2-(benzhydryloxy) phenoxy phthalocyaninato) zinc (II) complex was synthesized. The characterization of the obtained structure was investigated using spectroscopy techniques, including mass, nuclear magnetic resonance, infrared, electronic absorption spectroscopies. The nonlinear optical properties were investigated by virtue of femtosecond laser z-scan method. The aggregation–concentration relationship of zinc phthalocyanine compound, the photophysical and photochemical properties was dealt by UV–Vis spectroscopy and spectrofluorophotometer. In addition, the calculated values of the nonlinear absorption coefficient, β (~10–10 cm W–1), the nonlinear refraction index, n2 (~10–16 cm2 W–1) and third-order susceptibilities, χ(3) (~10–11 esu) for 2, 10, 16, 24–tetrakis (2-(benzhydryloxy) phenoxy phthalocyaninato) zinc (II) have been seen to be in line with literature.

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Acknowledgements

We would like to thank the Selcuk University Scientific Research Project (BAP) Coordination for the support with the Project Number 13301022, Selçuk University, High Technology Research and Application Center (İL-TEK) and SULTAN Center for infrastructures and Van Yüzüncü Yıl University Office of Scientific Research Projects for the financial support (BAP-ID-9776).

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Authors and Affiliations

  1. Faculty of Science, Department of Chemistry, Van Yuzuncu Yıl University, 65080, Van, Turkey

    D GÜNGÖRDÜ SOLĞUN & M S AĞIRTAŞ

  2. Department of Computer Technologies, Kadınhanı Faik İçil Vocational High School, University of Selçuk, 42800, Konya, Turkey

    Y GÜNDOĞDU

  3. Directorate of Laser Induced Proton Therapy Application and Research Center, University of Selçuk, 42031, Konya, Turkey

    Y GÜNDOĞDU & H Ş KILIÇ

  4. Faculty of Science, Department of Physics, University of Selçuk, 42031, Konya, Turkey

    H Ş KILIÇ

  5. Directorate of High Technology Research and Application Center, University of Selçuk, 42031, Konya, Turkey

    H Ş KILIÇ

Authors
  1. D GÜNGÖRDÜ SOLĞUN
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  2. Y GÜNDOĞDU
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  3. H Ş KILIÇ
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  4. M S AĞIRTAŞ
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Correspondence to M S AĞIRTAŞ.

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GÜNGÖRDÜ SOLĞUN, D., GÜNDOĞDU, Y., KILIÇ, H.Ş. et al. Synthesis of novel 2-(benzhydryloxy) phenoxy-substituted zinc phthalocyanine, third-order nonlinear optical and fluorescence properties. Bull Mater Sci 45, 235 (2022). https://doi.org/10.1007/s12034-022-02817-y

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  • DOI: https://doi.org/10.1007/s12034-022-02817-y

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