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Optical and dielectric properties of metal halide perovskites 2D

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Abstract

The two-dimensional (2D) metal halide hybrid (C2H5NH3)2MnCl4 has been grown by slow evaporation technique at room temperature. The phase-purity and morphology were confirmed using powder X-ray diffraction, scanning electron microscope and high-resolution transmission electron microscopy studies. Optical properties like reflectance and bandgap were determined from UV–visible spectrum. The dielectric properties of the studied compound have been investigated using impedance spectroscopy as a function of frequency for different temperatures from 1 Hz to 1 MHz between 353 and 453 K. The real and imaginary components Z′ and Z″ of impedance are fitted using an equivalent circuit model, consisted of a series combination of parallel resistance-constant phase elements of grain (Rg║CPEg), resistance-capacitance of grain boundary (Rgb║Cgb) and resistance-capacitance of electrode (Rel║Cel), which reveal the existence of distribution of relaxation times and thermally activated non-Debye-like relaxation. The frequency-dependent AC conductivity is well described by Jonscher’s universal power law, which follows the Arrhenuis relation. The above results indicate the semiconductor behaviour with wide bandgap energy.

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Authors and Affiliations

  1. Physics Department, Faculty of Science, Materials and Renewable Energies Team, LP2MS Laboratory, B.P. 11201, Meknes, 50000, Morocco

    M Ettakni, M Ouaaka, M Khechoubi & A Khmou

  2. Department of Physics, R&D Center for Membrane Technology and Center for Nanotechnology, Chung Yuan Christian University, Taoyuan, 32023, Taiwan, ROC

    S Kassou

  3. Département de matériaux et procédés, ENSAM Meknès, Université Moulay Ismail, Meknès, 50000, Morocco

    S Ghyati, S Yousfi & L Bih

  4. Process Engineering, Computer Science and Mathematics Laboratory (LIPIM), National School of Applied Engineering-Khouribga, Sultan Moulay Slimane University, Beni Mellal, 23000, Morocco

    H Bih

Authors
  1. M Ettakni
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  2. S Kassou
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  3. S Ghyati
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  4. M Ouaaka
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  6. M Khechoubi
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  7. L Bih
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  9. A Khmou
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Correspondence to M Ettakni.

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Ettakni, M., Kassou, S., Ghyati, S. et al. Optical and dielectric properties of metal halide perovskites 2D. Bull Mater Sci 44, 113 (2021). https://doi.org/10.1007/s12034-021-02418-1

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  • DOI: https://doi.org/10.1007/s12034-021-02418-1

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