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Preparation and characterization of biopolymer blend electrolyte membranes based on derived celluloses for lithium-ion batteries separator

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Abstract

Liquid electrolytes in commercial lithium-ion (Li-ion) batteries are corrosive, volatile and flammable. For these reasons, solid polymer electrolyte membranes are used to replace liquid electrolytes. This research focused on the fabrication of biopolymer blend electrolyte (BBE) membranes by blending commercial methylcellulose (MC) and carboxymethyl cellulose (CMC). CMC was synthesized by using microwave-assisted organic synthesis method at the optimum condition of 50°C, 60 min, 100 watts, and BBE membranes were prepared by casting solution technique at room temperature with various compositions. BBE membranes were characterized by Fourier transform infrared, electrochemical impedance spectroscopy, tensile tester, X-ray diffraction, scanning electron microscopy and thermogravimetry analysis/differential thermogravimetry/differential thermal analysis to analyse functional groups, ionic conductivities, mechanical properties, crystallinities, morphological and thermal stability, respectively. The blend membrane polymer host with a composition of MC/CMC (50/50) and 10% LiClO4 salt, which shows a good ionic conductivity, tensile strength, elongation at break and thermal decomposition temperature, i.e., 1.20 × 10−2 S cm−1; 11.02 MPa; 17.33% and 202.84°C, respectively. These characteristics of BBE membranes have potential to be applied as Li-batteries separator.

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Acknowledgements

This work has been supported by the Research Grant of Competition Research Program under the Directorate of Higher Education, the Ministry of Education and Culture, the Republic of Indonesia, and also the Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung (ITB). We are also thankful to the technicians for data analysis and measurement in Analytical Laboratory (ITB), Tensile Testing Laboratory-Center for Textile, Geological Survey Center Laboratory, Integrated Laboratory and Technology Innovation Center (Universitas Lampung).

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Authors and Affiliations

  1. Education Office, Province of North Sumatra, Medan, 20151, Indonesia

    Sun Theo Constan Lotebulo Ndruru

  2. Inorganic and Physical Chemistry Research Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung, 40132, Indonesia

    Sun Theo Constan Lotebulo Ndruru, Edi Pramono, Bunbun Bundjali & I Made Arcana

  3. Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Surakarta, 57126, Indonesia

    Edi Pramono

  4. Organic Chemistry Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung, 40132, Indonesia

    Deana Wahyuningrum

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  1. Sun Theo Constan Lotebulo Ndruru
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Correspondence to I Made Arcana.

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Ndruru, S.T.C.L., Pramono, E., Wahyuningrum, D. et al. Preparation and characterization of biopolymer blend electrolyte membranes based on derived celluloses for lithium-ion batteries separator. Bull Mater Sci 44, 104 (2021). https://doi.org/10.1007/s12034-021-02369-7

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