Abstract
The aim of this study was to produce graphene oxide (GO) coatings on biodegradable AZ31B magnesium (Mg) alloy. GO was synthesized by improved Hummers’ method, and a suspension was prepared in deionized water by ultrasonication. GO coatings were developed on AZ31B Mg alloy by electrophoretic deposition (EPD). The EPD parameters, such as voltage and time, were optimized to obtain uniform GO coatings. Characterization was carried out using Fourier transform infrared spectroscopy, X-ray diffraction, atomic force microscopy (AFM), and scanning electron microscopy. GO was found to have a thickness of approximately 0.7–1 nm as determined by AFM. Electrochemical behavior of coatings was evaluated by Tafel analysis and electrochemical impedance spectroscopy (EIS) in Ringer’s lactate solution. GO coatings improved the corrosion resistance of the AZ31B Mg alloy by 16× in Ringer’s lactate solution as compared to bare Mg alloy.
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References
Brusciotti, F, Snihirova, DV, Xue, H, Montemor, MF, Lamaka, SV, Ferreira, MG, “Hybrid Epoxy–Silane Coatings for Improved Corrosion Protection of Mg Alloy.” Corrosion Science, 67 82–90 (2013)
Hu, R-G, Zhang, S, Bu, J-F, Lin, C-J, Song, G-L, “Recent Progress in Corrosion Protection of Magnesium Alloys by Organic Coatings.” Progress in Organic Coatings, 73 (2) 129–141 (2012)
Gao, R, Liu, Q, Wang, J, Zhang, X, Yang, W, Liu, J, Liu, L, “Fabrication of Fibrous Szaibelyite with Hierarchical Structure Superhydrophobic Coating on AZ31 Magnesium Alloy for Corrosion Protection.” Chemical Engineering Journal, 241 352–359 (2014)
Chen, X-B, Zhou, X, Abbott, TB, Easton, MA, Birbilis, N, “Double-Layered Manganese Phosphate Conversion Coating on Magnesium Alloy AZ91D: Insights into Coating Formation, Growth and Corrosion Resistance.” Surface and Coatings Technology, 217 147–155 (2013)
Yang, J, Cui, F, Lee, IS, “Surface Modifications of Magnesium Alloys for Biomedical Applications.” Annals of Biomedical Engineering, 39 (7) 1857–1871 (2011)
Heublein, B, Rohde, R, Kaese, V, Niemeyer, M, Hartung, W, Haverich, A, “Biocorrosion of Magnesium Alloys: A New Principle in Cardiovascular Implant Technology?” Heart, 89 (6) 651–656 (2003)
Staiger, MP, Pietak, AM, Huadmai, J, Dias, G, “Magnesium and its Alloys as Orthopedic Biomaterials: A Review.” Biomaterials, 27 (9) 1728–1734 (2006)
Chen, Q, Thouas, GA, “Metallic Implant Biomaterials.” Materials Science and Engineering: R: Reports, 87 1–57 (2015)
Razavi, M, Fathi, M, Savabi, O, Vashaee, D, Tayebi, L, “In Vivo Assessments of Bioabsorbable AZ91 Magnesium Implants Coated with Nanostructured Fluoridated Hydroxyapatite by MAO/EPD Technique for Biomedical Applications.” Materials Science and Engineering: C, 48 21–27 (2015)
Asl, VZ, Zhao, J, Anjum, MJ, Wei, S, Wang, W and Zhao, Z, “The Effect of Cerium Cation on the Microstructure and Anti-Corrosion Performance of LDH Conversion Coatings on AZ31 Magnesium Alloy.” Journal of Alloys and Compounds, 821 153248 (2020)
Chaya, A, Yoshizawa, S, Verdelis, K, Myers, N, Costello, BJ, Chou, D-T, Pal, S, Maiti, S, Kumta, PN, Sfeir, C, “In Vivo Study of Magnesium Plate and Screw Degradation and Bone Fracture Healing.” Acta Biomaterialia, 18 262–269 (2015)
Neupane, MP, Lee, S, Kang, J, Park, IS, Bae, TS, Lee, MH, “Surface Characterization and Corrosion Behavior of Silanized Magnesium Coated with Graphene for Biomedical Application.” Materials Chemistry and Physics, 163 229–235 (2015)
Hoche, H, Groß, S, Oechsner, M, “Development of New PVD Coatings for Magnesium Alloys with Improved Corrosion Properties.” Surface and Coatings Technology, 259 102–108 (2014)
Kang, Z, Lai, X, Sang, J, Li, Y, “Fabrication of Hydrophobic/Super-Hydrophobic Nanofilms on Magnesium Alloys by Polymer Plating.” Thin Solid Films, 520 (2) 800–806 (2011)
Gray, J, Luan, B, “Protective Coatings on Magnesium and its Alloys—A Critical Review.” Journal of Alloys and Compounds, 336 (1) 88–113 (2002)
Chen, F, Zhou, H, Yao, B, Qin, Z, Zhang, Q, “Corrosion Resistance Property of the Ceramic Coating Obtained Through Microarc Oxidation on the AZ31 Magnesium Alloy Surfaces.” Surface and Coatings Technology, 201 (9) 4905–4908 (2007)
Hornberger, H, Virtanen, S, Boccaccini, A, “Biomedical Coatings on Magnesium Alloys–A Review.” Acta Biomaterialia, 8 (7) 2442–2455 (2012)
Prabhu, DB, Gopalakrishnan, P, Ravi, K, “Morphological Studies on the Development of Chemical Conversion Coating on Surface of Mg–4Zn Alloy and its Corrosion and Biomineralisation Behaviour in Simulated Body Fluid.” Journal of Alloys and Compounds, 812 152146 (2020)
Geim, AK, Novoselov, KS, “The Rise of Graphene.” Nature Materials, 6 (3) 183–191 (2007)
Liang, S, Shen, Z, Yi, M, Liu, L, Zhang, X, Ma, S, “In-Situ Exfoliated Graphene for High-Performance Water-Based Lubricants.” Carbon, 96 1181–1190 (2016)
Vicarelli, L, Heerema, SJ, Dekker, C, Zandbergen, HW, “Controlling Defects in Graphene for Optimizing the Electrical Properties of Graphene Nanodevices.” ACS Nano, 9 (4) 3428–3435 (2015)
Ettorre, V, De Marco, P, Zara, S, Perrotti, V, Scarano, A, Di Crescenzo, A, Petrini, M, Hadad, C, Bosco, D, Zavan, B, “In Vitro and In Vivo Characterization of Graphene Oxide Coated Porcine Bone Granules.” Carbon, 103 291–298 (2016)
Kotov, NA, “Materials Science: Carbon Sheet Solutions.” Nature, 442 (7100) 254–255 (2006)
Cui, G, Bi, Z, Zhang, R, Liu, J, Yu, X and Li, Z, “A Comprehensive Review on Graphene-Based Anti-Corrosive Coatings.” Chemical Engineering Journal, 373 104–121 (2019)
Prasai, D, Tuberquia, JC, Harl, RR, Jennings, GK, Bolotin, KI, “Graphene: Corrosion-Inhibiting Coating.” ACS Nano, 6 (2) 1102–1108 (2012)
An, SJ, Zhu, Y, Lee, SH, Stoller, MD, Emilsson, T, Park, S, Velamakanni, A, An, J, Ruoff, RS, “Thin Film Fabrication and Simultaneous Anodic Reduction of Deposited Graphene Oxide Platelets by Electrophoretic Deposition.” The Journal of Physical Chemistry Letters, 1 (8) 1259–1263 (2010)
He, W, Zhu, L, Chen, H, Nan, H, Li, W, Liu, H, Wang, Y, “Electrophoretic Deposition of Graphene Oxide as a Corrosion Inhibitor for Sintered NdFeB.” Applied Surface Science, 279 416–423 (2013)
Raza, MA, Rehman, ZU, Ghauri, FA, Ahmad, A, Ahmad, R, Raffi, M, “Corrosion Study of Electrophoretically Deposited Graphene Oxide Coatings on Copper Metal.” Thin Solid Films, 620 150–159 (2016)
Marcano, DC, Kosynkin, DV, Berlin, JM, Sinitskii, A, Sun, Z, Slesarev, A, Alemany, LB, Lu, W, Tour, JM, “Improved Synthesis of Graphene Oxide.” ACS Nano, 4 (8) 4806–4814 (2010)
Nekahi, A, Marashi, P, Haghshenas, D, “Transparent Conductive Thin Film of Ultra Large Reduced Graphene Oxide Monolayers.” Applied Surface Science, 295 59–65 (2014)
Takadoum, J, Bennani, HH, “Influence of Substrate Roughness and Coating Thickness on Adhesion, Friction and Wear of TiN Films.” Surface and Coatings Technology, 96 (2) 272–282 (1997)
Saud, SN, Bakhsheshi-Rad, H, Yaghoubidoust, F, Iqbal, N, Hamzah, E, Ooi, CR, “Corrosion and Bioactivity Performance of Graphene Oxide Coating on TiNb Shape Memory Alloys in Simulated Body Fluid.” Materials Science and Engineering: C, 68 687–694 (2016)
Gao, F, Xu, C, Hu, H, Wang, Q, Gao, Y, Chen, H, Guo, Q, Chen, D, Eder, D, “Biomimetic Synthesis and Characterization of Hydroxyapatite/Graphene Oxide Hybrid Coating on Mg Alloy with Enhanced Corrosion Resistance.” Materials Letters, 138 25–28 (2015)
Peng, F, Zhang, D, Wang, D, Liu, L, Zhang, Y and Liu, X, “Enhanced Corrosion Resistance and Biocompatibility of Magnesium Alloy by Hydroxyapatite/Graphene Oxide Bilayer Coating.” Materials Letters, 264 127322 (2020)
Soliman, H, Qian, J, Tang, S, Chen, Y, Makhlouf, A-S, Wan, G, “Hydroxyquinoline/Nano-Graphene Oxide Composite Coating of Self-Healing Functionality on Treated Mg Alloys AZ31.” Surface and Coatings Technology, 385 125395 (2020)
Macdonald, JR, “Impedance Spectroscopy: Emphasizing Solid Materials and Systems.” Applied Optics, 28 1083 (1989)
Jamesh, MI, Wu, G, Zhao, Y, McKenzie, DR, Bilek, MM, Chu, PK, “Electrochemical Corrosion Behavior of Biodegradable Mg–Y–RE and Mg–Zn–Zr Alloys in Ringer’s Solution and Simulated Body Fluid.” Corrosion Science, 91 160–184 (2015)
Ghauri, FA, Raza, MA, Baig, MS and Ibrahim, S, “Corrosion Study of the Graphene Oxide and Reduced Graphene Oxide-Based Epoxy Coatings.” Materials Research Express, 4 125601 (2017)
Anjum, MJ, Zhao, J, Asl, VZ, Yasin, G, Wang, W, Wei, S, Zhao, Z, Khan, WQ, “In-Situ Intercalation of 8-Hydroxyquinoline in Mg–Al LDH Coating to Improve the Corrosion Resistance of AZ31.” Corrosion Science, 157 1–10 (2019)
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Maqsood, M.F., Raza, M.A., Ghauri, F.A. et al. Corrosion study of graphene oxide coatings on AZ31B magnesium alloy. J Coat Technol Res 17, 1321–1329 (2020). https://doi.org/10.1007/s11998-020-00350-3
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DOI: https://doi.org/10.1007/s11998-020-00350-3