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Electrochemical preparation of poly 3-amino-5-hydroxypyrazole on copper and its corrosion protection efficiency

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Abstract

Electrochemical synthesis of poly 3-amino-5-hydroxypyrazole (PAHP) on copper electrode surface was carried out by cyclic voltammetry technique in 0.03 M 3-amino-5-hydroxypyrazole solution containing 0.3 M oxalic acid. The formation of dark brown PAHP on copper surface was characterized by cyclic voltammetry, FTIR and scanning electron microscopy techniques. The corrosion characteristics of copper/PAHP electrode were evaluated by electrochemical methods and electrochemical impedance spectroscopy in 3.5% NaCl solution. The obtained results indicated that PAHP thin film coating was an excellent inhibitor and controlled copper corrosion against corrosive agents in 3.5% NaCl solution.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Azarbaijan Shahid Madani University, Tabriz, Iran

    Nazila Khorrammaslack, Seyed Masoud Seyedahmadian & Biuck Habibi

  2. Department of Analytical Chemistry, Faculty of Chemistry, Urmia University, Urmia, Iran

    Khalil Farhadi

Authors
  1. Nazila Khorrammaslack
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  2. Khalil Farhadi
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  3. Seyed Masoud Seyedahmadian
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  4. Biuck Habibi
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Correspondence to Khalil Farhadi.

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Khorrammaslack, N., Farhadi, K., Seyedahmadian, S.M. et al. Electrochemical preparation of poly 3-amino-5-hydroxypyrazole on copper and its corrosion protection efficiency. J Coat Technol Res 17, 1269–1276 (2020). https://doi.org/10.1007/s11998-020-00345-0

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