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Development of Heat-Resistant Composites Based on Al-Mg-Si Alloy Mechanically Alloyed with Aluminide Particles

  • Powder-based Functional Materials for Extreme Environments: Processing and Characterization
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Abstract

Zr and Ti are important alloying elements for heat-resistant aluminum alloys due to the formation of the L12 aluminide phases which have anti-recrystallization and hardening effects. However, due to the low solubility of transition metals in aluminum, the concentration of aluminide dispersoids is small, and this limits their strengthening potential. In this work, aluminum was, for the first time to our knowledge, mechanically alloyed with additions of pre-synthesized Al3Ti and Al3Zr L12 strengthening particles (2.5 vol.%). The aim of this work was to compare the effects of Al3Ti and Al3Zr additives on the microstructure and strengthening of the test AA6063 alloy. Powders of alloy and aluminides were processed via planetary ball milling for 30 h. The composite granules were compacted by hot pressing at 400°C and 500°C. It was shown that addition of 1 wt.% Cu during milling leads to an abrupt increase in the microhardness of the alloy from 200 HV to 300 HV. The composites exhibited fine nanocrystalline microstructure consisting of aluminum crystallites about 100 nm in size, crushed intermetallic particles ranging from 1.5 μm to several dozens of nanometers, and secondary precipitates. The ultimate compressive strength at room temperature exceeds 900 MPa, and at 300°C it is 242–289 MPa.

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Acknowledgements

SEM, EDS and XRD studies were funded by the Ministry of Science and Higher Education in the framework of the State Task to MISIS University, project code FSME-2023-0005. TEM investigations were carried out on equipment of the Center for Collective Use "Materials Science and Metallurgy" (NUST MISIS) with the financial support of the Strategic Academic Leadership Program “Priority 2030” (project K2-2022-001). The authors are grateful to N. Yu Tabachkova for TEM studies and A.V. Posdniakov for fractographic analysis.

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  1. National University of Science and Technology MISIS, Leninskiy prospect 4, Moscow, Russia, 119049

    A. S. Prosviryakov, A. I. Bazlov & A. V. Mikhaylovskaya

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  1. A. S. Prosviryakov
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  2. A. I. Bazlov
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Prosviryakov, A.S., Bazlov, A.I. & Mikhaylovskaya, A.V. Development of Heat-Resistant Composites Based on Al-Mg-Si Alloy Mechanically Alloyed with Aluminide Particles. JOM 76, 1306–1318 (2024). https://doi.org/10.1007/s11837-023-06278-4

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