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Preparation and Microwave Absorption Properties of Annular Fe3O4/rGO@PANI

  • Advanced Magnetic Materials for Energy and Other Functional Applications and Devices
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Abstract

Annular Fe3O4 magnetic particles were prepared by hydrothermal method, and polyaniline (PANI) prepared by chemical oxidation polymerization was mixed with magnetic Fe3O4 in ethanol solution with graphene oxide. The structure and composition of the composites were studied by x-ray diffraction, x-ray photoelectron spectroscopy, and Fourier transforms infrared spectroscopy. The hollow ring shape of the product was determined by scanning electron microscope, and the microwave absorption performance was further evaluated by a vector network analyzer. Different composite ratios were designed to study the effects on microwave absorption performance. It was found that the Fe3O4/rGO@PANI showed an excellent reflection loss of − 50.4 dB at 9.9 GHz with the thickness of 2.6 mm when the composites were synthesized with a ratio of 2:1:2 for 5 h, which exhibited high EM absorption capacity. In addition, the effective absorption broadband range of the composite is 8.3–11.6 GHz (< − 10 dB). Therefore, the composite material can be used as a high-performance electromagnetic wave-absorbing material.

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Acknowledgements

This work is supported by the Joint R&D project of Zhonghao Chenguang Research Institute and Sichuan University of Science and Engineering (E10204272), the Project supported by The Innovation Fund of Postgraduate, Sichuan University of Science & Engineering (y2021013), Sichuan Science and Technology Program (2022YFG0134) and the Talent Introduction Project of Sichuan University of Science and Engineering (E10402736).

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Authors and Affiliations

  1. College of Chemical Engineering, Sichuan University of Science and Engineering, Zigong, 643000, People’s Republic of China

    Fanglan Fan, Zhichao Hu, Yuling Ye & Xiaonan Liu

  2. National Circular Economy Engineering Laboratory, Zigong, 643000, People’s Republic of China

    Xiaonan Liu

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FF finished the writing: first draft and conception. ZH assisted and improved the whole writing process. YY and XL are responsible for writing comments and editing.

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Correspondence to Yuling Ye or Xiaonan Liu.

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Fan, F., Hu, Z., Ye, Y. et al. Preparation and Microwave Absorption Properties of Annular Fe3O4/rGO@PANI. JOM 75, 1853–1863 (2023). https://doi.org/10.1007/s11837-023-05808-4

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