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Fabrication of palladium nanoparticles immobilized on an amine-functionalized ceramic membrane support using a nanoparticulate colloidal impregnation method with enhanced catalytic properties

  • Catalysis, Reaction Engineering
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Abstract

An efficient and reusable catalyst was developed by depositing palladium nanoparticles on an amine-functionalized ceramic membrane support using a nanoparticulate colloidal impregnation method. The as-prepared Pdloaded ceramic membrane support was characterized by XRD, SEM, EDS, TEM, XPS, ICP, and its catalytic properties were investigated in the liquid-phase p-nitrophenol hydrogenation. A comparative study was also made with the palladium nanoparticles deposited on an amine-functionalized ceramic membrane support by an impregnation-reduction method. The palladium nanoparticles could be homogeneously immobilized on the ceramic membrane support surface, and exhibited excellent catalytic performance in the p-nitrophenol hydrogenation. The catalytic activity of the Pdloaded ceramic membrane support prepared by the nanoparticulate colloidal impregnation method increased by 16.6% compared to that of impregnation-reduction method. In the nanoparticulate colloidal impregnation method, palladium nanoparticles were presynthesized, higher loading of Pd(0) could be obtained, resulting in better catalytic activity. The as-prepared Pd-loaded ceramic membrane support could be easily reused for several cycles without appreciable degradation of catalytic activity.

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Authors and Affiliations

  1. College of Environment, Nanjing Tech University, Nanjing, 210009, P. R. China

    Yan Du

  2. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China

    Rizhi Chen

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  1. Yan Du
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  2. Rizhi Chen
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Correspondence to Rizhi Chen.

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Du, Y., Chen, R. Fabrication of palladium nanoparticles immobilized on an amine-functionalized ceramic membrane support using a nanoparticulate colloidal impregnation method with enhanced catalytic properties. Korean J. Chem. Eng. 32, 1759–1765 (2015). https://doi.org/10.1007/s11814-015-0030-1

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  • DOI: https://doi.org/10.1007/s11814-015-0030-1

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