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High catalytic performance of Pt nanoparticles via support of conducting polymer for electrooxidation of methanol at carbon ceramic electrode

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Abstract

Carbon ceramic electrode (CCE), a new electrode substrate, was prepared by sol–gel procedure and used for the electropolymerization of aniline and dispersion of platinum nanoparticles into the resulting polyaniline (PANI) film. The microscopic structure and morphology of the CCE, CCE/PANI and CCE/PANI/Pt are characterized by scanning electron microscopy. The electrochemical and catalytic activities of the CCE/PANI/Pt were studied in 0.3 M H2SO4 solution. The electrocatalytic oxidation of methanol at the CCE/PANI/Pt has been investigated using cyclic voltammetric and chronoamperometric methods. The catalytic activity of Pt-coated PANI film on the CCE surface was compared with glassy carbon and Pt polyaniline/platinum-modified electrodes.

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Authors and Affiliations

  1. Electroanalytical Chemistry Research Laboratory, Faculty of Chemistry, Mazandaran University, Babolsar, Iran

    Parisa Hamidi & Reza Ojani

  2. Electrochemistry Research Laboratory, Faculty of Sciences, Azarbaijan Shahid Madani University, Tabriz, Iran

    Habib Razmi

  3. Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

    Iman Razavipanah

Authors
  1. Parisa Hamidi
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  2. Reza Ojani
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  3. Habib Razmi
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  4. Iman Razavipanah
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Correspondence to Parisa Hamidi.

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Hamidi, P., Ojani, R., Razmi, H. et al. High catalytic performance of Pt nanoparticles via support of conducting polymer for electrooxidation of methanol at carbon ceramic electrode. J IRAN CHEM SOC 12, 667–676 (2015). https://doi.org/10.1007/s13738-014-0525-4

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