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Evaluation of Rheological and Thermal Properties of a New Fluorocarbon Surfactant–Polymer System for EOR Applications in High-Temperature and High-Salinity Oil Reservoirs

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Journal of Surfactants and Detergents

An Erratum to this article was published on 14 September 2014

Abstract

Thermal stability and rheological properties of a novel surfactant–polymer system containing non-ionic ethoxylated fluorocarbon surfactant was evaluated. A copolymer of acrylamide (AM) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS) was used. Thermal stability and surfactant structural changes after aging at 100 °C were evaluated using TGA, 1H NMR, 13C NMR, 19F NMR and FTIR. The surfactant was compatible with AM–AMPS copolymer and synthetic sea water. No precipitation of surfactant was observed in sea water. The surfactant was found to be thermally stable at 100 °C and no structural changes were detected after exposure to this temperature. Rheological properties of the surfactant–polymer (SP) system were measured in a high pressure rheometer. The effects of surfactant concentration, temperature, polymer concentration and salinity on rheological properties were studied for several SP solutions. At low temperature (50 °C), the viscosity initially increased slightly with the addition of the surfactant, then decreased at high surfactant concentration. At a high temperature (90 °C), an increase in the viscosity with the increase in surfactant concentration was not observed. Overall, the influence of the fluorocarbon surfactant on the viscosity of SP system was weak particularly at high temperatures and high shear rate. Salts present in sea water reduced the viscosity of the polymer due to a charge shielding effect. However, the surfactant was found to be thermally stable in the presence of salts.

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References

  1. Wu Y, Mahmoudkhani A, Watson P, Fenderson T, Nair M (2012) Development of new polymers with better performance under conditions of high temperature and high salinity. In: SPE/EOR conference at oil and gas West Asia, Oman. doi:10.2118/155653-MS

  2. Thomas S (2007) Enhanced oil recovery—an overview. Oil Gas Sci Technol Rev IFP 63:9–19

    Article  Google Scholar 

  3. Al-Mjeni R, Arora S, Cherukupalli P, Van Wunnik J, Edwards J, Felber BJ, Gurpinar O, Hirasaki GJ, Miller CA, Jackson C (2010) Has the time come for EOR? Oilfield review. Winter 2011:16–35

    Google Scholar 

  4. Salager J-L, Forgiarini AM, Bullón J (2013) How to attain ultralow interfacial tension and three-phase behavior with surfactant formulation for enhanced oil recovery: a review. Part 1. Optimum formulation for simple surfactant–oil–water ternary systems. J Surfactant Deterg 16:449–472

    Article  CAS  Google Scholar 

  5. Salager J-L, Forgiarini AM, Márquez L, Manchego L, Bullón J (2013) How to attain an ultralow interfacial tension and a three-phase behavior with a surfactant formulation for enhanced oil recovery: a review. Part 2. Performance improvement trends from Winsor’s premise to currently proposed inter-and intra-molecular mixtures. J Surfactant Deterg 16:631–663

    Article  CAS  Google Scholar 

  6. Hirasaki G, Miller C, Puerto M (2011) Recent advances in surfactant EOR. SPE J 16:889–907

    Article  CAS  Google Scholar 

  7. Solairaj S, Britton C, Lu J, Kim DH, Weerasooriya U, Pope GA (2012) New correlation to predict the optimum surfactant structure for EOR. In: 18th SPE symposium, Tulsa, OK, USA, pp 14–18, April 2012

  8. Levitt D, Jackson A, Heinson C, Britton L, Malik T, Dwarakanath V, Pope G (2006) Identification and evaluation of high-performance EOR surfactants. In: SPE/DOE symposium on improved oil recovery, Tulsa, USA

  9. Levitt D, Pope G (2008) Selection and screening of polymers for enhanced-oil recovery. In: SPE/DOE symposium on improved oil recovery, USA. doi:10.2118/113845-MS

  10. Sabhapondit A, Borthakur A, Haque I (2003) Characterization of acrylamide polymers for enhanced oil recovery. J Appl Polym Sci 87:1869–1878

    Article  CAS  Google Scholar 

  11. Wang Y, Feng Y, Wang B, Lu Z (2010) A novel thermoviscosifying water-soluble polymer: synthesis and aqueous solution properties. J Appl Polym Sci 116:3516–3524

    Article  CAS  Google Scholar 

  12. Moawad T, Elhomadhi E, Gawish A (2007) Novel promising, high viscosifier, cheap, available and environmental friendly biopolymer (polymtea) for different applications at reservoir conditions under investigation part A: polymer properties. In: The seventh Egyptian–Syrian conference in chemical and petroleum engineering, Egypt

  13. Kulawardana E, Koh H, Kim DH, Liyanage P, Upamali K, Huh C, Weerasooriya U, Pope G (2012) Rheology and transport of Improved EOR polymers under harsh reservoir conditions. In: SPE improved oil recovery symposium, USA. doi:10.2118/154294-MS

  14. Wang Y, Lu ZY, Han YG, Feng YJ, Tang CL (2011) A novel thermoviscosifying water-soluble polymer for enhancing oil recovery from high-temperature and high-salinity oil reservoirs. Adv Mater Res 306:654–657

    Google Scholar 

  15. Liu X, Wang Y, Lu Z, Chen Q, Feng Y (2012) Effect of inorganic salts on viscosifying behavior of a thermoassociative water-soluble terpolymer based on 2-acrylamido-methylpropane sulfonic acid. J Appl Polym Sci 125:4041–4048

    Article  CAS  Google Scholar 

  16. Chen Q, Wang Y, Lu Z, Feng Y (2013) Thermoviscosifying polymer used for enhanced oil recovery: rheological behaviors and core flooding test. Polym Bull 70:391–401

    Article  CAS  Google Scholar 

  17. Petit L, Karakasyan C, Pantoustier N, Hourdet D (2007) Synthesis of graft polyacrylamide with responsive self-assembling properties in aqueous media. Polymer 48:7098–7112

    Article  CAS  Google Scholar 

  18. Parker WO, Lezzi A (1993) Hydrolysis of sodium-2-acrylamido-2-methylpropanesulfonate copolymers at elevated temperature in aqueous solution via 13C NMR spectroscopy. Polymer 34(23):4913–4918

    Article  CAS  Google Scholar 

  19. Zaitoun A, Makakou P, Blin N, Al-Maamari R, Al-Hashmi A-A, Abdel-Goad M (2012) Shear stability of EOR polymers. SPE J 17:335–339

    Article  CAS  Google Scholar 

  20. Ye Z, Gou G, Gou S, Jiang W, Liu T (2013) Synthesis and characterization of a water‐soluble sulfonates copolymer of acrylamide and N‐allylbenzamide as enhanced oil recovery chemical. J Appl Polym Sci 128:2001–2003

    Google Scholar 

  21. Zhong C, Luo P, Ye Z, Chen H (2009) Characterization and solution properties of a novel water-soluble terpolymer for enhanced oil recovery. Polym Bull 62:79–89

    Article  CAS  Google Scholar 

  22. Taylor KC, Nasr-El-Din HA (1998) Water-soluble hydrophobically associating polymers for improved oil recovery: a literature review. J Pet Sci Eng 19:265–280

    Article  CAS  Google Scholar 

  23. Goddard ED (2002) Polymer/surfactant interaction: interfacial aspects. J Colloid Interface Sci 256:228–235

    Article  CAS  Google Scholar 

  24. Zhang L, Shi J, Xu A, Geng B, Zhang S (2013) Synthesis and surface activities of novel succinic acid monofluoroalkyl sulfonate surfactants. J Surfactant Deterg 16:183–190

    Article  Google Scholar 

  25. Abe M (1999) Synthesis and applications of surfactants containing fluorine. Curr Opin Colloid Interface Sci 4:354–356

    Article  CAS  Google Scholar 

  26. Shinoda K, Hato M, Hayashi T (1972) Physicochemical properties of aqueous solutions of fluorinated surfactants. J Phys Chem 76:909–914

    Article  CAS  Google Scholar 

  27. Murphy PM, Hewat T (2008) Fluorosurfactants in enhanced oil recovery. Open Pet Eng J 1:58–61

    Article  CAS  Google Scholar 

  28. Sheng J (2010) Modern chemical enhanced oil recovery: theory and practice. Gulf Professional Publishing, Elsevier, Inc., The Boulevard, Oxford, UK. ISBN: 978-1-85617-745-0

  29. Robert J, Laurer JH, Spontak RJ, Khan SA (2002) Hydrophobically modified associative polymer solutions: rheology and microstructure in the presence of nonionic surfactants. Ind Eng Chem Res 41:6425–6435

    Article  Google Scholar 

  30. Wang L, Tiu C, Liu TJ (1996) Effects of nonionic surfactant and associative thickener on the rheology of polyacrylamide in aqueous glycerol solutions. Colloid Polym Sci 274:138–144

    Article  CAS  Google Scholar 

  31. Kientz E, Holl Y (1994) Interactions in solution between a hydrophobic polymer and various kinds of surfactants. Colloid Polym Sci 272:141–150

    Article  CAS  Google Scholar 

  32. Kim D-H, Kim J-W, Oh S-G, Kim J, Han S-H, Chung DJ, Suh K-D (2007) Effects of nonionic surfactant on the rheological property of associative polymers in complex formulations. Polymer 48:3817–3821

    Article  CAS  Google Scholar 

  33. Zhao G, Khin CC, Chen SB, Chen B-H (2005) Nonionic surfactant and temperature effects on the viscosity of hydrophobically modified hydroxyethyl cellulose solutions. J Phys Chem B 109:14198–14204

    Article  CAS  Google Scholar 

  34. Kuru E, Trivedi J, Urbissinova T (2010) Effect of elasticity during viscoelastic polymer flooding a possible mechanism of increasing the sweep efficiency. In: SPE western regional meeting, California. doi:10.2118/133471-PA

  35. Wang D, Cheng J, Xia H, Li Q, Shi J (2001) Viscous-elastic fluids can mobilize oil remaining after water-flood by force parallel to the oil–water interface. In: SPE Asia Pacific improved oil recovery conference, Kuala Lumpur. doi:10.2118/72123-MS

  36. Wang D, Xia H, Liu Z, Yang Q (2001) Study of the mechanism of polymer solution with visco-elastic behavior increasing microscopic oil displacement efficiency and the forming of steady “oil thread” flow channels. In: SPE Asia Pacific oil and gas conference and exhibition, Indonesia. doi:10.2118/68723-MS

  37. Xia H, Ju Y, Kong F, Wu J (2004) Effect of elastic behavior of HPAM solutions on displacement efficiency under mixed wettability conditions. In: SPE annual technical conference and exhibition, USA. doi:10.2118/90234-MS

  38. Xia H, Wang D, Wu J, Kong F (2004) Elasticity of HPAM solutions increases displacement efficiency under mixed wettability conditions. In: SPE Asia Pacific oil and gas conference and exhibition, Australia, 2004. Society of Petroleum Engineers. doi:10.2118/88456-MS

  39. Xia H, Wang D, Wu W, Jiang H (2007) Effect of the visco-elasticity of displacing fluids on the relationship of capillary number and displacement efficiency in weak oil-wet cores. In: Asia Pacific oil and gas conference and exhibition, Indonesia. doi:10.2118/109228-MS

  40. Zhang Z, Li J, Zhou J (2011) Microscopic roles of “viscoelasticity” in HPMA polymer flooding for EOR. Transp Porous Media 86:199–214

    Article  Google Scholar 

  41. Gao C (2011) Advances of polymer flood in heavy oil recovery. In: SPE heavy oil conference and exhibition, Kuwait. doi:10.2118/150384-MS

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Acknowledgments

This research was supported by Saudi Aramco through project # CPM 2297. The authors would like to thank King Fahd University of Petroleum & Minerals (KFUPM) for supporting this research. SNF and DuPont are also acknowledged for providing polymer and surfactant samples.

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Authors and Affiliations

  1. Department of Chemical Engineering, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    Muhammad Shahzad Kamal, Usamah A. Al-Mubaiyedh & Ibnelwaleed A. Hussien

  2. Department of Petroleum Engineering and Center of Petroleum and Minerals, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    Abdullah Saad Sultan

  3. DuPont Chemicals and Fluoroproducts, DuPont, International Sarl, Le Grand-Saconnex, Switzerland

    Martial Pabon

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  1. Muhammad Shahzad Kamal
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  2. Abdullah Saad Sultan
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Correspondence to Abdullah Saad Sultan.

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Kamal, M.S., Sultan, A.S., Al-Mubaiyedh, U.A. et al. Evaluation of Rheological and Thermal Properties of a New Fluorocarbon Surfactant–Polymer System for EOR Applications in High-Temperature and High-Salinity Oil Reservoirs. J Surfact Deterg 17, 985–993 (2014). https://doi.org/10.1007/s11743-014-1600-7

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  • DOI: https://doi.org/10.1007/s11743-014-1600-7

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