Skip to main content
Log in

Pore structure characteristics of low-rank coal reservoirs with different ash yields and their implications for recoverability of coalbed methane—a case study from the Erlian Basin, northeastern China

  • Research Article
  • Published:
Frontiers of Earth Science Aims and scope Submit manuscript

Abstract

Pores are the main accumulation sites and migration pathways for coalbed methane (also referred to as CBM). Pore structure restricts the content and recoverability of CBM from coal reservoirs. In this study, 12 representative coal samples with different ash yields that have similar tectonic characteristics and burial depths were collected from different mining areas in the Jiergalangtu and Huolinhe depressions in the Erlian Basin. These samples were used to study the restrictions of ash yield on the characteristics of coal pore structures and the recoverability of CBM through macroscopic and microscopic structure observation, scanning electron microscope observations, vitrinite reflectance tests, low-temperature N2 adsorption, nuclear magnetic resonance (NMR), and micro-computed tomography. The results show that coal reservoirs in the study area vary greatly in ash yield, based on which they can be divided into three types, i.e., low-ash-content, ash-bearing, and high-ash-content coal reservoirs. In addition, the ash yield has a certain impact on the development of coal pores; coal samples with lower ash yields indicate the presence of well-developed medium-large pores and better connectivity. Ash yield also has a certain impact on the brittleness of coal wherein a lower ash yield implies the development of brittle coal that is more liable to fracture as compared to less brittle samples at the same pressure. Absorbed gas content also varies significantly with ash yield; a low ash yield impacts the gas saturation of coal. Overall, for coal reservoirs in the study area, their porosity, pore diameter, movable fluid porosity, adsorbed gas amount, and recoverability decrease as the ash yield increases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Cai Y D, Liu D M, Pan Z J, Che Y, Liu Z H (2016). Investigating the effects of seepage-pores and fractures on coal permeability by fractal analysis. Transp Porous Media, 111(2): 479–497

    Google Scholar 

  • Cai Y D, Liu D M, Pan Z J, Yao Y B, Li J Q, Qiu Y K (2014). Pore structure of selected Chinese coals with heating and pressurization treatments. Sci China Earth Sci, 57(7): 1567–1582

    Google Scholar 

  • Clarkson C R, Bustin R M (1999). The effect of pore structure and gas pressure upon the transport properties of coal: a laboratory and modeling study. 2. Adsorption rate modeling. Fuel, 78(11): 1345–1362

    Google Scholar 

  • Clarkson C R, Solano N, Bustin R M, Bustin A M M, Chalmers G R L, He L, Melnichenko Y B, Radlinski A P, Blach T P (2013). Pore structure characterization of North American shale gas reservoirs using USANS/SANS, gas adsorption, and mercury intrusion. Fuel, 103: 606–616

    Google Scholar 

  • Fu H J, Tang D Z, Xu T, Xu H, Tao S, Li S, Yin Z Y, Chen B L, Zhang C, Wang L L (2017). Characteristics of pore structure and fractural dimension of low-rank coal: a case study of Lower Jurassic Xishayao coal in the southern Junggar Basin, NW China. Fuel, 193: 254–264

    Google Scholar 

  • Fu X H, Qin Y, Wei C T (2007). Coalbed Methane Geology. Xuzhou: China University of Mining and Technology Press (in Chinese)

    Google Scholar 

  • Golab A, Ward C R, Permana A, Lennox P, Botha P (2013). High-resolution three-dimensional imaging of coal using microfocus X-ray computed tomography, with special reference to modes of mineral occurrence. Int J Coal Geol, 113: 97–108

    Google Scholar 

  • Harris L A, Yust C S (1976). Transmisssion electron microscope observations of porosity in coal. Fuel, 55(3): 233–236

    Google Scholar 

  • Hou S H, Wang X M, Wang X J, Yuan Y D, Pan S, Wang X (2017). Pore structure characterization of low volatile bituminous coals with different particle size and tectonic deformation using low pressure gas adsorption. Int J Coal Geol, 183: 1–13

    Google Scholar 

  • Huang T, Liu Z (2019). Analysis on pore structure characteristics and influencing factors of coal reservoir in Yushe-Wuxiang Block. Coal Sci Technol, 47(7): 227–233

    Google Scholar 

  • Jia T F, Wang M, Gao X Y, Zhao J G, Zhu J Q (2021). Pore structure characteristics of low-rank coal reservoirs and evaluation of fractal models. Nat Gas Geosci, 32(3): 423–436

    Google Scholar 

  • Jiang W P, Song X Z, Zhong L W (2011). Research on the pore properties of different coal body structure coals and the effects on gas outburst based on the low-temperature nitrogen adsorption method. China Coal Soc, 36(4): 609–614 (in Chinese)

    Google Scholar 

  • Jing Y, Armstrong R T, Mostaghimi P (2017). Digital coal: generation of fractured cores with microscale features. Fuel, 207: 93–101

    Google Scholar 

  • Jing Y, Armstrong R T, Ramandi H L, Mostaghimi P (2016). Coal cleat reconstruction using micro-computed tomography imaging. Fuel, 181: 286–299

    Google Scholar 

  • Jiu B, Huang W H, Shi J, Hao R L (2021). A method to extract the content, radius and specific surface area of maceral compositions in coal reservoirs based on image modeling. J Petrol Sci Eng, 201: 108419

    Google Scholar 

  • Kang J Q, Fu X H, Li X, Liang S (2019). Nitrogen injection to enhance methane and water production: an experimental study using the LF-NMR relaxation method. Int J Coal Geol, 211: 103228

    Google Scholar 

  • Li S, Tang D Z, Xu H, Yang Z (2012). The pore-fracture system properties of coalbed methane reservoirs in the Panguan Syncline, Guizhou, China. Geosci Front, 3(6): 853–862

    Google Scholar 

  • Li Z T (2018). Evolution of Pore-fractures of Coal Reservoir and Its Impact on CBM Microcosmic Flow. Dissertation for Doctor Degree. Beijing: China University of Geosciences (Beijing) (in Chinese)

    Google Scholar 

  • Li Z T, Liu D M, Cai Y D, Ranjith P G, Yao Y B (2017). Multi-scale quantitative characterization of 3-D pore-fracture networks in bituminous and anthracite coals using FIB-SEM tomography and X-ray μ-CT. Fuel, 209: 43–53

    Google Scholar 

  • Li Z T, Liu D M, Cai Y D, Shi T L (2016). Investigation of methane diffusion in low-rank coals by a multiparous diffusion model. J Nat Gas Sci Eng, 33: 97–107

    Google Scholar 

  • Liu D M, Liu Z H, Cai Y D (2020a). Research progress on accumulation mechanism and formation geological conditions of coalbed methane. Coal Sci Technol, 48(10): 1–16

    Google Scholar 

  • Liu D M, Wang Y J, Cai Y D (2018). Analysis of main geological controls on coalbed methane enrichment and accumulation patterns in low rank coals. Coal Sci Technol, 46(6): 1–8

    Google Scholar 

  • Liu H H, Farid I I, Sang S X, Shang J H, Wu H Y, Xu H J, Zhang P S, Liu Q M (2020b). Synthetical study on the difference and reason for the pore structure of the No.3 coal reservoir from the southern Qinshui Basin, China, using mercury intrusion porosimetry, low-temperature N2 adsorption, low field nuclear magnetic resonance, and nuclear magnetic resonance cryoporometry. Energy Rep, 6: 1876–1887

    Google Scholar 

  • Liu H H, Sang S X, Wang G G, Li M, Xu H, Liu S, Li J, Ren B, Zhao Z, Xie Y (2014). Block scale investigation on gas content of coalbed methane reservoirs in southern Qinshui Basin with statistical model and visual map. J Petrol Sci Eng, 114: 1–14

    Google Scholar 

  • Liu J H, Wang S W, Su D M (2021). Study on pore development characteristics of low rank coal reservoirs in Erlian Basin group. Safety Coal Mines, 52(2): 7–12 (in Chinese)

    Google Scholar 

  • Liu S Q, Sang S X, Wang G, Ma J S, Wang X, Wang W F, Du Y, Wang T (2017). FIB-SEM and X-ray CT characterization of interconnected pores in high-rank coal formed from regional metamorphism. J Nat Gas Sci Eng, 148: 21–31

    Google Scholar 

  • Meng Y J, Tang D Z, Xu H, Gan Q, Yan T T (2020). Identifying the key factor of medium-rank coalbed methane productivity with gray relational analysis: a case study in Liulin area, Ordos Basin, China. Energy Sources A Recovery Util Environ Effects: 1–14

  • Meng Y J, Tang D Z, Xu H, Li C, Li L, Meng S Z (2014). Geological controls and coalbed methane production potential evaluation: a case study in Liulin area, eastern Ordos Basin, China. J Nat Gas Sci Eng, 21: 95–111

    Google Scholar 

  • Meyers R A (1982). Coal Structure. New York: Academic Press

    Google Scholar 

  • Nie B S, Liu X F, Yang L, Meng J, Li X (2015). Pore structure characterization of different rank coals using gas adsorption and scanning electron microscopy. Fuel, 158: 908–917

    Google Scholar 

  • Okolo G N, Everson R C, Neomagus H W J P, Roberts M J, Sakurovs R (2015). Comparing the porosity and surface areas of coal as measured by gas adsorption, mercury intrusion and SAXS techniques. Fuel, 141: 293–304

    Google Scholar 

  • Sakurovs R, He L L, Melnichenko Y B, Radlinski A P, Blach T, Lemmel H, Mildner D F R (2012). Pore size distribution and accessible pore size distribution in bituminous coals. Int J Coal Geol, 100: 51–64

    Google Scholar 

  • Song X X, Tang L W, Li W, Zeng F G, Xiang J H (2014). Pore structure in tectonically deformed coals by small angle X-ray scattering. J China Coal Soc, 39(4): 719–724 (in Chinese)

    Google Scholar 

  • Sun F J, Li W Z, Sun Q P, Sun B, Tian W G, Chen Y J, Chen Z H (2017). Low-rank coalbed methane exploration in Jiergalangtu Sag, Erlian basin. Acta Petrol Sin, 38(2): 485–492

    Google Scholar 

  • Wang A M, Wei Y C, Yuan Y, Li C F, Li Y, Cao D Y (2017). Coalbed methane reservoir’s pore-structure characterization of different macrolithotypes in the southern Junggar Basin of northwest China. Mar Pet Geol, 86: 675–688

    Google Scholar 

  • Wang T, Deng Z, Hu H Y, Cao M L, Zhang B X, Jiao P F, Yu Z (2019). Study on characteristics comparison of low rank coal coalbed methane reservoirs at home and abroad. Coal Sci Technol, 47(9): 41–50 (in Chinese)

    Google Scholar 

  • Wang Y Z (2020). Fractal characteristics of coal rock pores in the Baliancheng Mining Area, Hunchun Basin. J Southwest Petrol U (Sci & Tech Edi), 42(1): 57–68 (in Chinese)

    Google Scholar 

  • Wang Y, Mao C (2021). Nano/micro pore structure and fractal characteristics of Baliancheng Coalfield in Hunchun Basin. J Nanosci Nanotechnol, 21(1): 682–692

    Google Scholar 

  • Watanabe N, Ishibashi T, Hirano N, Tsuchiya N, Ohsaki Y, Tamagawa T, Tsuchiya Y, Okabe H (2011). Precise 3D numerical modeling of fracture flow coupled with X-ray computed tomography for reservoir core samples. SPE J, 16(3): 683–691

    Google Scholar 

  • Yang F, He D, Ma D M, Duan Z H, Tian T, Fu D L (2020). Multi-scale joint characterization of micro-pore structure of low-rank coal reservoir. Lithologic Reservoirs, 32(3): 14–23 (in Chinese)

    Google Scholar 

  • Yao H P, Lv W B, Wang K F, Li L, Li W H, Lin H T, Li F C, Li Z (2020). Key geological factors and evaluation methods for huge low-rank coalbed methane reservoirs: taking Bayanhua depression in Erlian basin as an example. Coal Geo Explor, 48(1): 85–95 (in Chinese)

    Google Scholar 

  • Yao Y B, Liu D M (2012). Comparison of low-field NMR and mercury intrusion porosimetry in characterizing pore size distributions of coals. Fuel, 95: 152–158

    Google Scholar 

  • Yao Y B, Liu D M, Che Y, Tang D Z, Tang S H, Huang W H (2010). Petrophysical characterization of coals by low-field nuclear magnetic resonance (NMR). Fuel, 89(7): 1371–1380

    Google Scholar 

  • Yao Y B, Liu D M, Tang D Z, Tang S H, Huang W H (2008). Fractal characterization of adsorption-pores of coals from north China: an investigation on CH4 adsorption capacity of coals. Int J Coal Geol, 73(1): 27–42

    Google Scholar 

  • Yao Y B, Liu D M, Tang D Z, Tang S H, Huang W H, Liu Z H, Che Y (2009). Fractal characterization of seepage-pores of coals from China: an investigation on permeability of coals. Comput Geosci, 35(6): 1159–1166

    Google Scholar 

  • Zhang J J, Wei C T, Ju W, Yan G Y, Lu G W, Hou X W, Kai Z (2019a). Stress sensitivity characterization and heterogeneous variation of the pore-fracture system in middle-high rank coals reservoir based on NMR experiments. Fuel, 238: 331–344

    Google Scholar 

  • Zhang J J, Wei C, Vandeginste V, Ju W, Qin Z, Quan F, Soh Tamehe L (2019b). Experimental simulation study on water migration and methane depressurizing desorption based on nuclear magnetic resonance technology: a case study of middle-rank coals from the Panguan syncline in the western Guizhou region. Energy Fuels, 33(9): 7993–8006

    Google Scholar 

  • Zhao D F, Guo Y H, Mao X X, Lu C G, Li M, Qian F C (2017a). Characteristics of macro-nanopores in anthracite coal based on mercury injection, nitrogen adsorption and FE-SEM. J China Coal Soc, 42(6): 1517–1526 (in Chinese)

    Google Scholar 

  • Zhao J L, Xu H, Tang D Z, Mathews J P, Li S, Tao S (2016). A comparative evaluation of coal specific surface area by CO2 and N2 adsorption and its influence on CH4 adsorption capacity at different pore sizes. Fuel, 183: 420–431

    Google Scholar 

  • Zhao X Z, Liu G D, Jin F M, Huang Z L, Lu X J, Sun M L, Ding X J, Chen Z L (2015). Distribution features and pattern of effective source rock in small faulted lacustrine basin: a case study of the Lower Cretaceous in Erlian Basin. Acta Petrol Sin, 36(6): 641–652

    Google Scholar 

  • Zhao Y X, Liu S M, Elsworth D, Jiang Y D, Zhu J (2014). Pore structure characterization of coal by synchrotron small-angle X ray scattering and transmission electron microscopy. Energy Fuels, 28(6): 3704–3711

    Google Scholar 

  • Zhao Y X, Sun Y F, Liu S M, Wang K, Jiang Y D (2017b). Pore structure characterization of coal by NMR cryoporometry. Fuel, 190: 359–369

    Google Scholar 

  • Zheng S J, Yao Y B, Liu D M, Cai Y D, Liu Y (2018). Characterizations of full-scale pore size distribution, porosity and permeability of coals: a novel methodology by nuclear magnetic resonance and fractal analysis theory. Int J Coal Geol, 196: 148–158

    Google Scholar 

  • Zhou S D, Liu D M, Cai Y D, Yao Y B, Li Z T (2017). 3D characterization and quantitative evaluation of pore-fracture networks of two Chinese coals using FIB-SEM tomography. Int J Coal Geol, 174: 41–54

    Google Scholar 

  • Zhou Y L, Liu N, Liu Q R (2011). Plant Biology. Beijing: Higher Education Press (in Chinese)

    Google Scholar 

  • Zhu J F, Liu J Z, Yang Y M, Cheng J, Zhou J H, Cen K F (2016). Fractal characteristics of pore structures in 13 coal specimens: relationship among fractal dimension, pore structure parameter, and slurry ability of coal. Fuel Process Technol, 149: 256–267

    Google Scholar 

Download references

Acknowledgments

This study was financially supported by the National Natural Science Foundation of China (Grant No. 42072162), the Natural Science Foundation of Shandong Province (No. ZR2020MD036), and a forward-looking and basic technology research project of PetroChina (No. 2021DJ2301).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jiaosheng Yang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dong, D., Yang, J., Hu, Q. et al. Pore structure characteristics of low-rank coal reservoirs with different ash yields and their implications for recoverability of coalbed methane—a case study from the Erlian Basin, northeastern China. Front. Earth Sci. 17, 18–29 (2023). https://doi.org/10.1007/s11707-022-1015-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11707-022-1015-0

Keywords

Navigation