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The interaction and energetics of the mixture of SDS and paracetamol in presence of zinc sulfate in an aqueous media

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Abstract

Paracetamol (PCM) is one of the most commonly employed drugs for the treatment of fever and pain. The activity of the drug is dependent on the excipients utilized during formulation as well as on physiological conditions. Herein, the conductivity measurements are implied to deduce the possible molecular interactions occurring between sodium dodecyl sulfate (SDS) and PCM in the presence of ZnSO4 at various temperatures. The critical micelle concentration (cmc) of SDS was found to be lowered with the augmentation of PCM concentration. The cmc values of the SDS + PCM mixture were found to be reduced with the increase of temperature and concentration of ZnSO4. The counterion binding values were found to be temperature and additives dependent. The estimated values of free energies of micellization (\(\Delta G_{m}^{o}\)) signify the spontaneous aggregation of SDS + PCM mixture in all media studied. The spontaneity of self-assembly for SDS + PCM mixture augmented at a higher temperature. The estimated values of enthalpy of micellization (\(\Delta H_{m}^{o}\)) and entropy of micellization (\(\Delta S_{m}^{o}\)) were positive throughout. The values of \(\Delta H_{m}^{o}\) and \(\Delta S_{m}^{o}\) exhibit excellent linearity. The values of different transfer energies, intrinsic enthalpies, and compensation temperature were also calculated and explained properly.

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Acknowledgements

The Deanship of Scientific Research (DSR) at King Abdulaziz University, Jeddah, Saudi Arabia, has funded this project, under grant no. (KEP-38-130-42).

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Authors and Affiliations

  1. Department of Chemistry and Physics, Gono Bishwabidyalay, Savar, Dhaka, 1344, Bangladesh

    Sharmin Sultana Rakhi, Shurid Kishore Mahalanobish, Md. Ruhul Amin & Shamim Mahbub

  2. Industrial Physics Division, BCSIR Laboratories, Dhaka, 1205, Bangladesh

    Mohammad Robel Molla

  3. Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah, 21589, Saudi Arabia

    Malik Abdul Rub & Abdullah M. Asiri

  4. Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, 21589, Saudi Arabia

    Malik Abdul Rub, Maha Moteb Alotaibi & Abdullah M. Asiri

  5. Department of Chemistry, Jahangirnagar University, Savar, Dhaka, 1342, Bangladesh

    Md. Anamul Hoque

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  1. Sharmin Sultana Rakhi
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  2. Shurid Kishore Mahalanobish
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Correspondence to Malik Abdul Rub.

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Rakhi, S.S., Mahalanobish, S.K., Amin, M.R. et al. The interaction and energetics of the mixture of SDS and paracetamol in presence of zinc sulfate in an aqueous media. Chem. Pap. 76, 179–188 (2022). https://doi.org/10.1007/s11696-021-01836-z

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