Skip to main content
SpringerLink
Log in

The Tl2SnSe3-CdSe System and the Crystal Structure of the Tl2CdSnSe4 Compound

  • Published:
Journal of Phase Equilibria and Diffusion Aims and scope Submit manuscript

Abstract

Component interaction at the Tl2Se-CdSe-SnSe2 section was investigated by x-ray diffraction and differential thermal analysis, and the phase diagram was constructed. The existence of a new quaternary compound Tl2CdSnSe4 with two polymorphous modifications was established. The crystal structure of the low-temperature modification of Tl2CdSnSe4 was determined. The compound crystallizes in space group I-42m, Pearson symbol tI16, a = 0.80490(6) nm, c = 0.68573(8) nm, RI = 0.0815.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. M.A. McGuire, Th.J. Scheidemantel, J.V. Badding, and F.J. DiSalvo, Tl2AXTe4 (A = Cd, Hg, Mn; X = Ge, Sn): Crystal Structure, Electronic Structure, and Thermoelectric Properties, Chem. Mater., 2005, 17, p 6186-6191

    Article  Google Scholar 

  2. I.D. Olekseyuk, M.Yu. Mosolyuk, L.V. Piskach, and O.V. Parasyuk, Phase Equilibria in the Tl2S(Se)–HgS(Se)–SnS(Se)2 Systems at 520 K, Lesya Ukrainka Volyn Nat’l Univ. Sci. Bull., 2010, 30, p 19-21

    Google Scholar 

  3. V.B. Lazarev, E.Yu. Peresh, V.I. Starosta, and V.V. Mudriy, Phase Equilibria and Properties of Compounds in the Tl2S(Se)–SnS2(Se2) Systems, Zhurn. Neorg. Khim., 1985, 60, p 1502-1506

    Google Scholar 

  4. P. Houenou and R. Eholie, Etude du systeme SnSe2–Tl2Se, C. R. Acad. Sci. Paris, 1976, 283, p 731-733

    Google Scholar 

  5. N.K. Abrikosov, V.F. Bankina, L.V. Poretskaya et al., Semiconductor Chalcogenides and Their Alloys, Nauka, Moscow, 1975

    Google Scholar 

  6. I.D. Olekseyuk, Ed., Binary and Ternary Semiconductor Phases in Systems Me-B V-C VI(D VII), Vezha, Lutsk, 1995

    Google Scholar 

  7. S. Jaulmes and P. Houenou, Structure crystalline du seleniure d’etain (IV) et de thallium (I): Tl2SnSe3, Mater. Res. Bull., 1980, 15, p 911-915

    Article  Google Scholar 

  8. L.G. Akselrud, P.Yu. Zavalii, Yu.M. Grin et al., Software Package for Crystallographic Calculations (Version 4), J. Appl. Cryst., 2014, 47, p 803-805

    Article  Google Scholar 

  9. K. Brandenburg and H. Putz, Diamond-4.2, http://www.crystalimpact.com/download/diamond4/Diamond-4.2.0-Setup.exe. Accessed 31 May 2016

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic and Physical Chemistry, Eastern European National University, Voli Ave. 13, Lutsk, 43025, Ukraine

    A. O. Selezen, L. V. Piskach, O. V. Parasyuk & I. D. Olekseyuk

Authors
  1. A. O. Selezen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. V. Piskach
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. V. Parasyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. D. Olekseyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. O. Selezen.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Selezen, A.O., Piskach, L.V., Parasyuk, O.V. et al. The Tl2SnSe3-CdSe System and the Crystal Structure of the Tl2CdSnSe4 Compound. J. Phase Equilib. Diffus. 40, 797–801 (2019). https://doi.org/10.1007/s11669-019-00770-8

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11669-019-00770-8

Keywords

Search

Navigation