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Experimental Investigation of the 450 and 600 °C Sections of the Ti-V-Zn System

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The 450 and 600 °C isothermal sections of the Ti-V-Zn ternary system were constructed based on examination of equilibrated alloys by x-ray diffraction and Scanning electron microscopy coupled with Energy dispersive spectroscopy. A continuous solid solution phase (Ti,V)Zn3 was clearly identified. Its lattice parameter increased with the increasing of the Ti content. (Ti,V)Zn3 is in equilibrium with all phases except α-Ti and Ti2Zn at 450 and 600 °C. Four Ti-Zn intermetallic compounds, TiZn16, Ti3Zn22, TiZn3 and TiZn, and a V-Zn compound V4Zn5 were observed in the ≥50 at.%Zn region. The solubility of Ti in V4Zn5 is around 0.2 at.% and that of V in TiZn16, Ti3Zn22 and TiZn at 450 °C is 0.6, 1.3 and 2.6 at.%, respectively.

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Acknowledgments

The authors gratefully acknowledge the financial support from National Natural Science Foundation of China (Nos. 51271040 and 51301028), and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Materials Surface Science and Technology, Changzhou University, Changzhou, 213164, Jiangsu, People’s Republic of China

    Hao Tu, Changjun Wu, Ya Liu, Xuping Su & Haoping Peng

  2. Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou, 213164, Jiangsu, People’s Republic of China

    Xuping Su

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  1. Hao Tu
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  2. Changjun Wu
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Correspondence to Changjun Wu.

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Tu, H., Wu, C., Liu, Y. et al. Experimental Investigation of the 450 and 600 °C Sections of the Ti-V-Zn System. J. Phase Equilib. Diffus. 37, 651–657 (2016). https://doi.org/10.1007/s11669-016-0496-5

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  • DOI: https://doi.org/10.1007/s11669-016-0496-5

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