Abstract
The solution precursor plasma spray (SPPS) process is capable of depositing highly durable thermal barrier coatings (TBCs). In this study, an aqueous chemical precursor feedstock was injected into the plasma jet to deposit SrZrO3 thermal barrier coating on metal substrate. Taguchi design of experiments was employed to optimize the SPPS process. The thermal characteristics and phase evolution of the SrZrO3 precursor, as well as the influence of various spray parameters on the coating deposition rate, microhardness, microstructure, and phase stability, were investigated. The experimental results showed that, at given spray distance, feedstock flow rate, and atomization pressure, the optimized spray parameters were arc current of 600 A, argon flow rate of 40 L/min, and hydrogen flow rate of 10 L/min. The SrZrO3 coating prepared using the optimized spray parameters had single-pass thickness of 6.0 μm, porosity of ~18%, and microhardness of 6.8 ± 0.1 GPa. Phase stability studies indicated that the as-sprayed SrZrO3 coating had good phase stability in the temperature range from room temperature to 1400 °C, gradually exhibiting a phase transition from t′-ZrO2 to m-ZrO2 in the SrZrO3 coating at 1450 °C with increasing time, while the SrZrO3 phase did not change.
Similar content being viewed by others
References
D. Zhu and R.A. Miller, Thermal Conductivity and Sintering Behavior of Advanced Thermal Barrier Coatings, Ceram. Eng. Sci. Proc., 2002, 23, p 457-468
W.A. Nelson and R.M. Orenstein, TBC Experience in Land-Based Gas Turbines, J. Therm. Spray Technol., 1997, 6, p 176-180 (in English)
D.R. Clarke and S.R. Philpot, Thermal Barrier Coating Materials, Mater. Today, 2005, 5, p 22-29 (in English)
J.A. Krogstad, R.M. Leckie, S. Krämer, J.M. Cairney, D.M. Liplin, C.A. Jhonson, and C.G. Levi, Phase Evolution Upon Aging of Air Plasma Sprayed t′-Zirconia Coatings: I-Microstructure Evolution, J. Am. Ceram. Soc., 2013, 96, p 299-307 (in English)
W. Ma, D.E. Mack, R. Vassen, and D. Stöver, Perovskite-Type Strontium Zirconate as a New Material for Thermal Barrier Coatings, J. Am. Ceram. Soc., 2008, 91, p 2630-2635 (in English)
N.P. Padture, K.W. Schlichting, T. Bhatia, A. Ozturk, B. Cetegen, E.H. Jordan, M. Gell, S. Jiang, T.D. Xiao, P.R. Strutt, E. Garcia, P. Miranzo, and M.I. Osendi, Towards Durable Thermal Barrier Coatings with Novel Microstructures Deposited by Solution Precursor Plasma Spray, Acta Mater., 2001, 49, p 2251-2257 (in English)
M. Gell, L. Xie, X. Ma, E.H. Jordan, and N.P. Padture, Highly Durable Thermal Barrier Coatings Made by the Solution Precursor Plasma Spray Process, Surf. Coat. Technol., 2004, 177-178, p 97-102 (in English)
E.H. Jordan, L. Xie, X. Ma, M. Gell, N.P. Padture, B. Cetegen, A. Ozturk, J. Roth, T.D. Xiao, and P.E.C. Bryant, Superior Thermal Barrier Coatings Using Solution Precursor Plasma Spray, J. Therm. Spray Technol., 2004, 13, p 57-65 (in English)
C. Jiang, E.H. Jordan, A.B. Harris, M. Gell, and J. Roth, Double-Layer Gadolinium Zirconate/Yttria-Stabilized Zirconia Thermal Barrier Coatings Deposited by the Solution Precursor Plasma Spray Process, J. Therm. Spray Technol., 2015, 24, p 895-906 (in English)
D. Chen, E.H. Jordan, and M. Gell, Thermal and Crystallization Behavior of Zirconia Precursor Used in the Solution Plasma Spray Process, J. Mater. Sci., 2007, 42, p 5576-5580 (in English)
A.C. Geiculescu and H.G. Spencer, Thermal Decomposition and Crystallization of Aqueous Sol-Gel Derived Zirconium Acetate Gels: Effects of the Additive Anions, J. Sol-Gel Sci. Technol., 2000, 17, p 25-35 (in English)
N. Jacobson, Thermodynamic Properties of Some Metal Oxide-Zirconia Systems, NASA TM 102351, 1989 (in English)
U. Schulz, B. Saruhan, K. Fritscher, and C. Leyens, Review on Advanced EB-PVD Ceramic Topcoats for TBC Applications, Int. J. Appl. Ceram. Technol., 2004, 1, p 302-315 (in English)
Acknowledgments
The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (Nos. 51462026, 51672136), the Inner Mongolia Natural Science Foundation (No. 2014MS0509), and Shanghai technical platform for testing and characterization on inorganic materials (No. 14DZ2292900). The authors would also like to thank Prof. E. Jordan from University of Connecticut for valuable discussion.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Li, X., Ma, W., Wen, J. et al. Preparation of SrZrO3 Thermal Barrier Coating by Solution Precursor Plasma Spray. J Therm Spray Tech 26, 371–377 (2017). https://doi.org/10.1007/s11666-017-0527-8
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11666-017-0527-8