Abstract
This study investigated the thermal insulation and thermal shock resistance behavior of nanostructured versus conventional yttria-stabilized zirconia (YSZ) thermal barrier coatings. To evaluate their coating performance in service conditions, samples were furnace sintered at 1150 °C for 100 h in ambient atmosphere. The results show that the nanostructured coatings exhibited better heat transfer resistance and thermal shock resistance compared with the conventional coating. In addition, the larger size of the initial agglomerates in the nanostructured coatings increased the percentage area of nanozones and decreased the heat transfer resistance. The thermal insulation behavior of the conventional coating was improved after heat treatment because of horizontal cracking. Disappearance of cracks, bridging between grains, and their growth by connecting with each other were observed in the conventional coating. However, in the nanostructured coatings, the nanoareas and their related properties disappeared. Microstructural and phase investigations were carried out by optical microscopy, field-emission scanning electron microscopy (FE-SEM), and x-ray diffraction (XRD) analysis. The thermal behavior was investigated by thermal insulation capability testing.
Similar content being viewed by others
References
C.U. Hardwicke and Y.C. Lau, Advances in Thermal Spray Coatings for Gas Turbines and Energy Generation: A Review, J. Therm. Spray Technol., 2013, 22(5), p 564-576
X.Q. Cao, R. Vassen, and D. Stoever, Ceramic Materials for TBC, J. Eur. Ceram. Soc., 2004, 24, p 1-10
D. Zhu and R.A. Miller, Thermal Conductivity and Sintering Behavior of Advanced TBC, NASA/TM 2002, Task Number 211481.
C.J. Li and A. Ohmori, Relationships Between the Microstructure and Properties of Thermally Sprayed Deposits, J. Therm. Spray Technol., 2002, 11(3), p 365-374
L. Wang, Y. Wang, and X.G. Sun, Influence of Pores on the Thermal Insulation Behavior of Thermal Barrier Coatings Prepared by APS, Mater. Des., 2011, 32, p 36-47
Z. Wang, A. Kulkarni, and S. Deshpande, Effects of Pores and Interfaces on Effective Properties of Plasma Sprayed Zirconia Coatings, Acta Mater., 2003, 51, p 5319-5334
V.E. Oliker and T.Ya. Gridasova, Effect of the Porous Structure of TBCs on Their Heat Conductivity, Powder Metall. Met. Ceram., 2008, 47, p 117-125
Q. Yu, A. Rauf, and N. Wang, Thermal Properties of Plasma-Sprayed TBC with Bimodal Structure, Ceram. Int., 2011, 37, p 1093-1099
N. Markocsan, P. Nyleń, and J. Wigren, Effect of Thermal Aging on Microstructure and Functional Properties of Zirconia-Base Thermal Barrier Coatings, J. Therm. Spray Technol., 2009, 18, p 201-208
A. Cipitria and I.O. Golosnoy, A Sintering Model for Plasma-Sprayed Zirconia TBCs. Part I: Free-Standing Coatings, Acta Mater., 2009, 57, p 980-992
J.A. Thompson and T.W. Clyne, The Effect of Heat Treatment on the Stiffness of Zirconia Top Coats is Plasma-Sprayed TBCs, Acta Mater., 2001, 49, p 1565-1575
S.R. Choi, D. Zhu, and R.A. Miller, Effect of Sintering on Mechanical Properties of Plasma-Sprayed Zirconia-Based Thermal Barrier Coatings, Am. Ceram. Soc., 2005, 88(10), p 2859-2867
J. Chevalier, L. Gremillard, and D. Clarke, The Tetragonal-Monoclinic Transformation in Zirconia: Lessons Learned and Future Trends, Am. Ceram. Soc., 2009, 92(9), p 1901-1920
R.S. Lima and B.R. Marple, Nanostructured YSZ Thermal Barrier Coatings Engineered to Counteract Sintering Effects, Mater. Sci. Eng., 2008, 485, p 182-193
G. Di Girolamo, F. Marra, and C. Blasi, Microstructure, Mechanical Properties and Thermal Shock Resistance of Plasma Sprayed Nanostructured Zirconia Coatings, Ceram. Int., 2011, 37, p 2711-2717
W.B. Gong and C.K. Sha, Microstructures and Thermal Insulation Capability of PS Nanostructured Ceria Stabilized Zirconia Coatings, Surf. Coat. Technol., 2006, 201, p 3109-3115
R.S. Lima, A. Kucuk, and C.C. Berndt, Evaluation of Microhardness and Elastic Modulus of Thermally Sprayed Nanostructured Zirconia Coatings, Surf. Coat. Technol., 2001, 135, p 166-172
S. Karthikeyana, V. Balasubramanian, and R. Rajendran, Developing Empirical Relationships to Estimate Porosity and Microhardness of Plasma-Sprayed YSZ Coatings, Ceram. Int., 2013, 37, p 2730-2744
B. Liang and C. Ding, Thermal Shock Resistance of Nanostructured and Conventional Zirconia Coatings Deposited by Atmospheric Plasma Spraying, Surf. Coat. Technol., 2005, 197, p 185-192
W.Q. Wang, C.K. Sha, D.Q. Sun, and X.J. Gu, Microstructural Feature, Thermal Shock Resistance and Isothermal Oxidation Resistance of Nanostructured Zirconia Coating, Mater. Sci. Eng., 2006, 424, p 1-5
Ch Zhou, N. Wang, and S. Gong, Thermal Cycling Life and Thermal Diffusivity of a Plasma-Sprayed Nanostructured TBCs, Scripta Mater., 2004, 51, p 945-948
A.M. Limarga, S. Shian, and M. Baram, Effect of High-Temperature Aging on the Thermal Conductivity of Nanocrystalline Tetragonal Yttria-Stabilized Zirconia, Acta Mater., 2012, 60, p 5417-5424
A. Keyvani, M. Saremi, and M. Heydarzadeh Sohi, Microstructural Stability of Zirconia–Alumina Composite Coatings During Hot Corrosion Test at 1050 °C, J. Alloys Compd., 2010, 506, p 103-108
R.W. Trice, Y.J. Su, J.R. Mawdsley, and K.T. Faber, Effect of Heat Treatment on Phase Stability, Microstructure and Thermal Conductivity of PS YSZ, J. Mater. Sci., 2002, 37, p 2359-2365
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tamaddon Masoule, S., Valefi, Z., Ehsani, N. et al. Thermal Insulation and Thermal Shock Behavior of Conventional and Nanostructured Plasma-Sprayed TBCs. J Therm Spray Tech 25, 1684–1691 (2016). https://doi.org/10.1007/s11666-016-0476-7
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11666-016-0476-7