Skip to main content
Log in

Joining of Cast ZE41A Mg to Wrought 6061 Al by the Cold Spray Process and Friction Stir Welding

  • Peer Reviewed
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

This paper presents a novel method for joining cast ZE41A-T5 Mg to wrought 6061-T6 Al, without forming deleterious, coarse intermetallic compounds, which is not currently possible with conventional technologies. The novel aspect of the process includes the development of a joint design using cold spray (CS) as the enabling technology, to produce a transitional layer onto which a conventional welding technique can be employed to join the two dissimilar materials. The emphasis in this study will be on the CS transitional layer (T-layer) which enables the joining of cast ZE41A-T5 magnesium (Mg) and wrought 6061-T6 aluminum (Al) by friction-stir welding and the subsequent materials characterization to show the structural integrity of the entire joint. In order to join Mg and Al plates by this method, a transitional layer of CS Al is first deposited along the edge of cast ZE41A Mg plate. The CS Al T-layer enables the Mg to be friction stir welded to a plate of wrought 6061 Al, thereby completing the Mg plate to Al plate joint. Friction stir welding was chosen in this study to join the CS Al T-layer to the wrought Al plate; however, other conventional welding techniques could also be employed for joining Mg to Al in this manner. The CS Al T-layer is compatible to the wrought 6061 Al plate and serves as an insulating layer that prevents heat generated during the friction stir welding process from extending into the magnesium, thus preventing the formation of intermetallics. In this study, two sets of samples were produced joining cast ZE41A-T5 magnesium (Mg) and wrought 6061-T6 aluminum: one set using CS 6061 Al as the transition material between the ZE41A Mg plate and 6061 Al plate and the other set using CS 5056 Al as the transition material. Microstructural analysis by scanning and transmission electron microscopy and optical microscopy, along with mechanical test results including triple lug shear, tension, and micro hardness will be presented. Comparisons will be made to conventional joining techniques and the importance, as well as the applications of this technique, will be discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18
Fig. 19
Fig. 20
Fig. 21
Fig. 22
Fig. 23
Fig. 24
Fig. 25

Similar content being viewed by others

References

  1. L.M. Zhao and Z.D. Zhang, Effect of Zn Alloy Interlayer on Interface Microstructure and Strength of Diffusion-Bonded Mg-Al Joints, Scr. Mater., 2008, 58, p 283-286

    Article  Google Scholar 

  2. P. Liu, Y.J. Li, H.R. Geng, and J. Wang, Mater. Lett., 2005, 59, p 2001

    Article  Google Scholar 

  3. A. Kostka, R.S. Coelho, J. Santos, and A.R. Pyzalla, Microstructure of Friction Stir Welded Aluminium Alloy to Magnesium Alloy, Scr. Mater., 2009, 60(11), p 953-956

    Article  Google Scholar 

  4. A. Ben-Artzy, A. Sternb, N. Frage, V. Shribman, and O. Sadot, Wave Formation Mechanism in Magnetic Pulse Welding, Int. J. Impact Eng., 2010, 37, p 397-404

    Article  Google Scholar 

  5. L. Liu and H. Wang, Microstructure and Properties Analysis of Laser Welding and Laser Weld Bonding Mg to Al Joints, Metall. Mater. Trans. A., 2011, 42(4), p 1044-1050

  6. Rattana Borrisutthekul, Yukio Miyashita, and Yoshiharu Mutoh, Dissimilar Material Laser Welding between Magnesium Alloy AZ31B and Aluminum Alloy A5052-O, Sci. Technol. Adv. Mater., 2005, 6, p 199-204

    Article  Google Scholar 

  7. Peng Liu, Yajiang Li, Haoran Geng, and Juan Wang, Microstructure Characteristics in TIG Welded Joint of Mg/Al Dissimilar Materials, Mater. Lett., 2007, 61, p 1288-1291

    Article  Google Scholar 

  8. A. Ben-Artzy, A. Munitz, G. Kohn, B. Bronfin, and A. Shtechman, TMS Meeting 2002, Magnesium Technology, 2002, p 295.

  9. O. Tomiharu, J. Light. Metal. Weld. Const, 2004, 42, p 2

    Google Scholar 

  10. J. Shang, K. Wang, Q. Zhou, D. Zhang, J. Huang, and G. Li, Microstructure Characteristics and Mechanical Properties of Cold Metal Transfer Welding Mg/Al Dissimilar Metals, Mater. Des., 2011, 34, p 559

    Article  Google Scholar 

  11. A.C. Somasekharan and L.E. Murr, Microstructures in Friction-Stir Welded Dissimilar Mg Alloys and Mg Alloys to 6061-T6 Aluminum Alloy, Mater. Charact., 2004, 52, p 49-64

    Article  Google Scholar 

  12. C. Toma, E. Cicala, P. Sallamand, and D. Grevey, CMT Joining of Aluminum Magnesium Alloys in a Statistical Experiment, Metal, 2012, Brno, 5, p 23-25.

  13. A. Papyrin, Cold Spray Technology, Adv. Mater. Process., 2001, 159, p 49–51.

  14. T.H. Van Steenkiste, Kinetic Spray Coatings, Surf Coat Tech., 1999, 111, p 62

    Article  Google Scholar 

  15. T. Stoltenhoff, H. Kreve, and H. Richter, An Analysis of the Cold Spray Process and its Coatings, J. Therm. Spray Technol., 2002, 11(4), p 542

    Article  Google Scholar 

  16. R. Dykhuisen and M. Smith, Gas Dynamic Principles of Cold Spray, J. Therm. Spray Technol., 1998, 7(2), p 205

    Article  Google Scholar 

  17. V.F. Kosarev, S.V. Klinkov, A.P. Alkhimov, A.N. Papyrin, and 2, On Some Aspects of Gas Dynamic Principles of Cold Spray Process, J. Therm. Spray Technol., 2003, 12, p 265

    Article  Google Scholar 

  18. M. Gujicic, C.L. Zhao, C. Tong, W.S. DeRosset, and D. Helfritch, Analysis of the Impact Velocity of Powder Particles in the Cold-Gas Dynamic-Spray Process, Mater. Sci. Eng. A, 2004, 368, p 222

    Article  Google Scholar 

  19. R.C. Dykhuizen, M.F. Smith, D.L. Gilmore, R.A. Neiser, X. Jiang, and S. Sampath, Impact of High Velocity Cold Spray Particles, J. Therm. Spray Technol., 1999, 8(4), p 559

    Article  Google Scholar 

  20. M. Grujicic, J.R. Saylor, D.E. Beasley, W.S. Derosset, and D. Helfritch, Computational Analysis of the Interfacial Bonding between Feed-Powder Particles and the Substrate in the Cold-Gas Dynamic-Spray Process, Appl. Surf. Sci., 2003, 219, p 211

    Article  Google Scholar 

  21. V. Champagne, Ed., The Cold Spray Materials Deposition Process: Fundamentals and Applications, Woodhead Publishing Limited, Abington Hall, Abington, 2007, p 57

    Google Scholar 

  22. M.P. Walsh, Plat. Met. Rev., 2000, 44, p 22-30

    Google Scholar 

  23. S.M. Bernard, J.M. Samet, A. Grambsch, K.L. Ebi, and I. Romieu, Environ. Health Perspect., 2001, 109, p 199-209

    Article  Google Scholar 

  24. A. Buxton and I. Norris, Dissimilar materials…Novel Solutions to Joining the Unjoinable, TWI Bulletin, 2008.

  25. J. Gould, Automakers Look to Solid State Welding of Dissimilar Metals. Fastening/Joining/Assembly Supplement.

  26. R. Huang and H. Fukanuma, Study of the Influence of Particle Velocity on Adhesive Strength of Cold Spray Deposits, J. Therm. Spray, 2012, 548(3-4), p 541-549

    Article  Google Scholar 

  27. MIL-J-24445A, Joint, Bimetallic Bonded, Aluminum to Steel, Commander, Naval Ship Engineering Center, SEC 6124, Department of Navy, Washington, 20362, http://everyspec.com/MIL-SPECS/MIL-SPECS-MIL-J/MIL-J-24445A_11054/. Accessed June 2014

  28. R. Maev, V. Leshchynsky, and A. Papyrin, Structure Formation of Ni-based Composite Coatings During Low Pressure Gas Dynamic Spraying. Proceedings of the 2006 ITSC, ASM, Seattle, 2006.

  29. MATWEB. Chemical Composition of ZE41A Magnesium

  30. W. Kasprzak et al., Correlating Hardness Retention and Phase Transformations of Al and Mg Cast Alloys for Aerospace Applications, J. Mater. Eng. Perform., 2015, 24(3), p 1365-1378

    Article  Google Scholar 

  31. Y. Riddle, L. Barber, Y. Riddle, L. Barber, and M. Makhlouf, Characterization of Mg Alloy Solidification and As-Cast Microstructure, Magnesium Technology, TMS, 2004, p 203-208.

  32. I.J. Polmear, Light Alloys-Metallurgy of the Light Metals, Metallurgy and Materials Science Series, 3rd ed., Butterworth-Heinemann, Burlington, 1995,

    Google Scholar 

  33. M.R. Rockni, C.A. Widener, and V.K. Champagne, Microstructural Evolution of 6061 Al Gas-Atomized Powder and High- Pressure Cold-Sprayed Deposition”, J. Therm. Spray, 2013, doi:10.1007/s11666-013-0049-y

    Google Scholar 

  34. G.E. Dieter, Mechanical Metallurgy, McGraw-Hill Series in Materials Science and Engineering McGraw-Hill, Singapore, 2001

    Google Scholar 

  35. V.K. Champagne, The Cold Spray Materials Deposition Process: Fundamentals and Applications, Woodhead Publishing Limited, Cambridge, 2007

    Book  Google Scholar 

  36. Mechanical Properties of 6061-T6 Aluminum. ASM MATWEB.

  37. T. Stoltenhoff and F. Zimmermann, LOXPlate® Coatings for Aluminum Aerospace Components Exposed to High Dynamic Stresses”, Praxair Surface Technologies GmbH, Ratingen

  38. J.A. Schneider and A.C. Nunes, Thermo-mechanical processing in friction stir welds, Proceedings of symposium sponsored by the shaping and forming committee of the materials processing and manufacturing division of the minerals, metals, and materials society (TMS), Warrendale, TMS, 2003, p 43-51.

  39. P.L. Threadgill, Friction-Stir Welding-State of the Art, TWI, Report 678, England, 1999

  40. S. Ravikumar et al., Effect of Process Parameters on Mechanical Properties of Friction Stir Welded Dissimilar Materials between AA6061-T651 and AA7075-T651 Alloys, Int. J. Adv. Mech. Eng., 2014, 4(1), p 101-114

    Google Scholar 

  41. A. Lugovskoy, Al-Mg Phase Diagram. al-chemist.info/node/161

  42. Liming Liu, Daxin Ren, and Fei Liu, A Review of Dissimilar Welding Techniques for Magnesium Alloys to Aluminum Alloys, Materials, 2014, 7, p 3735-3757. doi:10.3390/ma7053735

    Article  Google Scholar 

  43. T. Schmidt et al., From Particle Acceleration to Impact and Bonding in Cold Spray, J. Therm. Spray Technol., 2009, 18(5-6), p 794

    Article  Google Scholar 

Download references

Acknowledgments

This work was funded by the National Science Foundation through the South Dakota School of Mines and Technology. A joint patent application was filed through the Army Research Laboratory (ARL 13-44, Application #61930613).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Victor Kenneth Champagne III.

Additional information

This article is an invited paper selected from presentations at the 2015 International Thermal Spray Conference, held May 11-14, 2015, in Long Beach, California, USA, and has been expanded from the original presentation.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Champagne, V.K., West, M.K., Reza Rokni, M. et al. Joining of Cast ZE41A Mg to Wrought 6061 Al by the Cold Spray Process and Friction Stir Welding. J Therm Spray Tech 25, 143–159 (2016). https://doi.org/10.1007/s11666-015-0301-8

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-015-0301-8

Keywords

Navigation