Skip to main content
Log in

Deposition of Metal Oxide Films from Metal–EDTA Complexes by Flame Spray Technique

  • Technical Note
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

R2O3 (R = Y, Eu, Er) metal oxides were synthesized from metal–ethylenediaminetetraacetic acid (EDTA) complexes using a flame spray technique. As this technique enables high deposition rates, films with thickness of several tens of micrometers were obtained. Films of yttria, europia, and erbia phase were synthesized on stainless-steel substrates with reaction assistance by H2–O2 combustion gas. The oxide films consisted of the desired crystalline phase with micropores. The porosity of the films was in the range of 6–15%, varying with the metal used. These results suggest that the true density of the metal oxide obtained from metal–EDTA powder through the thermal reaction process plays an important role in achieving film with the desired porosity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig.3
Fig.4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. W. Ma, S. Gong, H. Xu, and X. Cao, The Thermal Cycling Behavior of Lanthanum-Cerium Oxide Thermal Barrier Coating Prepared by EB-PVD, Surf. Coat. Technol., 2006, 200, p 5113-5118

    Article  Google Scholar 

  2. A. Feuerstein, J. Knapp, T. Taylor, A. Ashary, A. Bolcavage, and N. Hitchman, Technical and Economical Aspects of Current Thermal Barrier Coating Systems for Gas Turbine Engines by Thermal Spray and EBPVD: a Review, J. Therm. Spray Technol., 2008, 17, p 199-213

    Article  Google Scholar 

  3. H.J.C. Voorwald, R.C. Souza, W.L. Pigatin, and M.O.H. Cioffi, Evaluation of WC-17Co and WC-10Co-4Cr Thermal Spray Coatings by HVOF on the Fatigue and Corrosion Strength of AISI, 4340 Steel, Surf. Coat. Technol., 2005, 190, p 155-164

    Article  Google Scholar 

  4. V. Shklover, L. Braginsky, G. Witz, M. Mishrikey, and C. Hafner, High-Temperature Photonic Structures. Thermal Barrier Coatings, Infrared Sources and Other Applications, J. Comput. Theor. Nanosci., 2008, 5, p 862-893

    Google Scholar 

  5. R.A. Rosu, I. Bran, M. Popescu, and C. Opriş, In Vitro Characterization of Hydroxyapatite Layers Deposited by APS and HVOF Thermal Spraying Methods, Ceram. Sililk., 2012, 56, p 25-31

    Google Scholar 

  6. M.S. Hussain, The Synthesis of Nanostructured NiCrAlY Powders for Plasma Sprayed Thermal Barrier Coatings, Adv. Phys. Theor. Appl., 2013, 13, p 1-9

    Google Scholar 

  7. G.C. Saha and T.I. Khan, Comparative Abrasive Wear Study of HVOF Coatings Obtained by Spraying WC-17Co Microcrystalline and Duplex Near-Nanocrystalline Cermet Powders, J. Eng. Mater. Technol., 2011, 133,041002-1-041002-8 (8 page)

  8. F. Chen, F. Li, Q. Shen, and L. Zhang, Cold Spray and Pressureless Sintering of Zirconium Phosphate Bonded Silicon Nitride Ceramics with Porous Gradient Structure, J. Phys. Conf. Ser., 2013, 419, 012006 (6 pages).

  9. H. Saitoh, K. Kawahara, S. Ohshio, A. Nakamura, and N. Nambu, Synthesis of Blue Phosphor by Decomposition of Metal Complex Powder, J. Ceram. Sci. Jpn., 2002, 110, p 874-876

    Article  Google Scholar 

  10. H. Saitoh, R. Satoh, A. Nakamura, N. Nambu, and S. Ohshio, Metal Oxide Powder Synthesized with Amorphous Metal Chelates, J. Mater. Sci., 2002, 37, p 4315-4320

    Article  Google Scholar 

  11. H. Saitoh, K. Kawahara, S. Ohshio, A. Nakamura, and N. Nambu, Metal Composition of Y2O3:Eu Powder Evaluated Using Particle Analyzer, Sci. Technol. Adv. Mater., 2005, 6, p 205-209

    Article  Google Scholar 

  12. N. Tanaka, S. Ohshio, H. Saitoh, and K. Uematsu, Crystal Growth of Highly Oriented Zinc Oxide by Laser Deposition Technique with Metal-EDTA (Ethylene Diamine Tetra-Acetic Acid) Complexes, Jpn. J. Appl. Phys., 1998, 37, p L1165-L1168

    Article  Google Scholar 

  13. N. Tanaka, H. Wakabayashi, S. Mochizuki, S. Ohshio, and H. Saitoh, Synthesis of Y-Ba-Cu-O Films with Ethylene Diamine Tetraacetic Acid Complexes Assisted by Excimer-Laser Ablation, J. Mater. Res., 1998, 13, p 2775-2778

    Article  Google Scholar 

  14. A. Nakamura, R. Satoh, S. Ohshio, N. Nambu, and H. Saitoh, Laser Deposition of (Sr, Ba)TiO3 Films with Metal-Ethylenediaminetetraaceticacid Complexes, Jpn. J. Appl. Phys., 2002, 41, p 3033-3038

    Article  Google Scholar 

  15. H. Akasaka, M. Ohto, Y. Hasebe, A. Nakamura, S. Ohshio, and H. Saitoh, Yttria Coating Synthesized by Reactive Flame Spray Process Using Y-EDTA Complex, Surf. Coat. Technol., 2012, 205, p 3877-3880

    Article  Google Scholar 

  16. J. Kitamura, H. Mizuno, N. Kato, and I. Aoki, Plasma-Erosion Properties of Ceramic Coating Prepared by Plasma Spraying, Mater. Trans., 2006, 47, p 1677-1683

    Article  Google Scholar 

  17. K. Komatsu,T. Tsuchiya, Y. Hasebe, T. Sekiya, A. Toyama, A. Nakamura, H. Akasaka, H. Saitoh, Synthesis of Metal Oxide Particles Using Reaction Route from Rare-Earth Metal-EDTA Complexes, accepted to J. Therm. Spray Technol.

  18. K. Daijiten 3 (in Japanese), Kyoritsu Shuppan Co., Ltd., p. 895

  19. E.R. Andrievskaya, Phase Equilibria in the Refractory Oxide Systems of Zirconia, Hafnia and Yttria with Rare-Earth Oxides, J. Eur. Ceram. Soc., 2008, 28, p 2363-2388

    Article  Google Scholar 

  20. X. Li, P. Wu, H. Qiu, S. Chen, and B. Song, Crystallization Behavior and Mechanical Properties of Erbium Oxide Coatings Fabricated by Pulsed Magnetron Sputtering, Thin Solid Films, 2011, 520, p 2316-2320

    Article  Google Scholar 

  21. K.-R. Ernst, J. Braeutigam, F. Gaertner, and T. Klassen, Effect of Substrate Temperature on Cold-Gas-Sprayed Coatings on Ceramic Substrates, J. Therm. Spray Technol., 2013, 22, p 422-432

    Article  Google Scholar 

  22. J. Wu, H. Fang, S. Yoon, C. Lee, and H.-J. Kim, Critical Velocities for High Speed Particle Deposition in Kinetic Spraying, Mater. Trans., 2006, 47, p 1723-1727

    Article  Google Scholar 

  23. P. Fogarassy, D. Gerday, and A. Lodini, Agglomerated Nanostructured Particles Disintegration During the Plasma Thermal Spraying Process, Mech. Res. Commun., 2005, 32, p 221-239

    Article  Google Scholar 

  24. K. Daijiten 3(in Japanese), Kyoritsu Shuppan, p 944

  25. K. Daijiten 3(in Japanese), Kyoritsu Shuppan, p 897

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Keiji Komatsu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Komatsu, K., Sekiya, T., Toyama, A. et al. Deposition of Metal Oxide Films from Metal–EDTA Complexes by Flame Spray Technique. J Therm Spray Tech 23, 833–838 (2014). https://doi.org/10.1007/s11666-014-0104-3

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-014-0104-3

Keywords

Navigation