Abstract
This report deals with the sensing characteristics of hydrogen (H2) and carbon monoxide (CO) gases using a tin oxide (SnO2) functional coating deposited on an alumina plate using air plasma spraying technique. This coating exhibits a porous morphology that contains both mesoporous and macroporous regions conducive to superior gas sensing. Initially, gas sensing measurements were performed by varying the operating temperature at a fixed gas concentration using a dynamic sensing setup. The coating showed maximum response % at 275 °C for H2 and CO gases. However, higher response % was obtained in the presence of H2 over CO. Sensing performance was further investigated by varying the target gas concentration at 275 °C. The coating exhibited a higher response for H2 compared to that of other plasma-sprayed SnO2 coating reported in the literature. The SnO2 coating under investigation demonstrated good sensor response and repeatability, moderate operating temperature and quick response time.
Similar content being viewed by others
References
V. Aroutiounian, Metal Oxide Hydrogen, Oxygen, and Carbon Monoxide Sensors for Hydrogen Setups and Cells, Int. J. Hydrogen Energy, 2007, 32(9), p 1145–1158
S. Verhelst, Recent Progress in the Use of Hydrogen as a Fuel for Internal Combustion Engines, Int. J. Hydrogen Energy, 2014, 39(2), p 1071–1085. https://doi.org/10.1016/j.ijhydene.2013.10.102
S.G. Leonardi, A. Bonavita, N. Donato, and G. Neri, Development of a Hydrogen Dual Sensor for Fuel Cell Applications, Int. J. Hydrogen Energy, 2018, 43(26), p 11896–11902. https://doi.org/10.1016/j.ijhydene.2018.02.019
I. Dincer and C. Acar, Review and Evaluation of Hydrogen Production Methods for Better Sustainability, Int. J. Hydrogen Energy, 2014, 40(34), p 11094–11111. https://doi.org/10.1016/j.ijhydene.2014.12.035
K. Mukherjee and S.B. Majumder, Hydrogen Sensing Characteristics of Nano-Crystalline Mg0.5Zn0.5Fe2O4 Thin Film: Effect of Film Thickness and Operating Temperature, Int. J. Hydrogen Energy, 2014, 39(2), p 1185–1191. https://doi.org/10.1016/j.ijhydene.2013.10.158
T. Hübert, L. Boon-Brett, G. Black, and U. Banach, Hydrogen Sensors: A Review, Sensors Actuators B Chem., 2011, 157(2), p 329–352
J. Yanez, M. Kuznetsov, and A. Souto-Iglesias, An Analysis of the Hydrogen Explosion in the Fukushima-Daiichi Accident, Int. J. Hydrogen Energy, 2015, 40(25), p 8261–8280. https://doi.org/10.1016/j.ijhydene.2015.03.154
T. Nishiguchi, T. Matsumoto, H. Kanai, K. Utani, Y. Matsumura, W.J. Shen, and S. Imamura, Catalytic Steam Reforming of Ethanol to Produce Hydrogen and Acetone, Appl. Catal. A, 2005, 279(1–2), p 273–277
H. Chen and Z. Mao, The Study on the Results of Hydrogen Pipeline Leakage Accident of Different Factors, IOP Conf. Ser. Earth Environ. Sci., 2017, 64(1), p 012002
K.K. Bhargav, S. Ram, and S.B. Majumder, The Role of Catalytic Cobalt-Modified Lanthanum Ferrite Nano-Crystals in Selective Sensing of Carbon Monoxide, J. Mater. Sci., 2014, 50(2), p 644–651
A. Ghosh, T. Bhowmick, N. Labhasetwar, and S.B. Majumder, Catalytic Oxidation and Selective Sensing of Carbon Monoxide for Sense and Shoot Device Using ZnO–CuO Hybrids, Materialia, Elsevier Ltd, 2018, 2019(5), p 100177. https://doi.org/10.1016/j.mtla.2018.11.026
G. Reumuth, Z. Alharbi, K.S. Houschyar, B.S. Kim, F. Siemers, P.C. Fuchs, and G. Grieb, Carbon Monoxide Intoxication: What We Know, Burns, 2019, 45(3), p 526–530
S.C. Jambagi, S. Kar, P. Brodard, and P.P. Bandyopadhyay, Characteristics of Plasma Sprayed Coatings Produced from Carbon Nanotube Doped Ceramic Powder Feedstock, Mater. Des., 2016, 112, p 392–401. https://doi.org/10.1016/j.matdes.2016.09.095
M. Hadad, P.P. Bandyopadhyay, J. Michler, and J. Lesage, Tribological Behaviour of Thermally Sprayed Ti-Cr-Si Coatings, Wear, 2009, 267(5–8), p 1002–1008
P.P. Bandyopadhyay, Processing and Characterisation of Plasma Sprayed Ceramic Coatings on Steel Substrate.”Ph.D Dissertation, Indian Institute of Technology, Kharagpur, (2000)
S. Datta, D.K. Pratihar, and P.P. Bandyopadhyay, Modeling of Plasma Spray Coating Process Using Statistical Regression Analysis, Int. J. Adv. Manuf. Technol., 2013, 65(5–8), p 967–980. https://doi.org/10.1007/s00170-012-4232-y
S. Kar, S. Paul, and P.P. Bandyopadhyay, Processing and Characterisation of Plasma Sprayed Oxides: Microstructure, Phases Residual Stress Surface Coat. Technol., 2016, 304(September), p 364–374
S.C. Jambagi and P.P. Bandyopadhyay, Plasma Sprayed Carbon Nanotube Reinforced Splats and Coatings, J. Eur. Ceram. Soc., 2017, 37(5), p 2235–2244. https://doi.org/10.1016/j.jeurceramsoc.2017.01.028
J. Longtin, S. Sampath, R.J. Gambino, S. Tankiewicz, and R. Greenlaw, Sensors for Harsh Environments by Direct Write Thermal Spray, Proc. IEEE Sensors, 2002, 1(1), p 598–601. https://doi.org/10.1109/ICSENS.2002.1037168
T.S. Theophilou, J.P. Longtin, S. Sampath, S. Tankiewicz, and R.J. Gambino, Integrated Heat-Flux Sensors for Harsh Environments Using Thermal-Spray Technology, IEEE Sens. J., 2006, 6(5), p 1126–1132
A.F. Ahlström-Silversand and C.U.I. Odenbrand, Thermally Sprayed Wire-Mesh Catalysts for the Purification of Flue Gases from Small-Scale Combustion of Bio-Fuel Catalyst Preparation and Activity Studies, Appl. Catal. A, 1997, 153(1), p 177–201
C. Zhang, M. Debliquy, A. Boudiba, H. Liao, and C. Coddet, Sensing Properties of Atmospheric Plasma-Sprayed WO3 Coating for Sub-Ppm NO2 Detection, Sensors Actuators B Chem., 2010, 144(1), p 280–288
C. Zhang, M. Debliquy, and H. Liao, Deposition and Microstructure Characterization of Atmospheric Plasma-Sprayed ZnO Coatings for NO2 Detection, Appl. Surface Sci., 2010, 256(20), p 5905–5910. https://doi.org/10.1016/j.apsusc.2010.03.072
M. Gardon, O. Monereo, S. Dosta, G. Vescio, A. Cirera, and J.M. Guilemany, New Procedures for Building-up the Active Layer of Gas Sensors on Flexible Polymers, Surf. Coat. Technol., 2013, 235, p 848–852. https://doi.org/10.1016/j.surfcoat.2013.09.011
G. Korotcenkov, Handbook of Gas Sensor Materials, Prop. Adv. Short. Appl., 2014, 2, p 15. https://doi.org/10.1007/978-1-4614-7388-6
V. Ambardekar, P.P. Bandyopadhyay, and S.B. Majumder, Atmospheric Plasma Sprayed SnO2 Coating for Ethanol Detection, J. Alloys Compd., 2018, 752(2), p 440–447. https://doi.org/10.1016/j.jallcom.2018.04.151
V. Ambardekar, P.P. Bandyopadhyay, and S.B. Majumder, Hydrogen Sensing Performance of Atmospheric Plasma Sprayed Tin Dioxide Coating, Int. J. Hydrogen Energy, 2019, 44, p 14092–14104. https://doi.org/10.1016/j.ijhydene.2019.04.013
G.J. Li, X.H. Zhang, and S. Kawi, Relationships between sensitivity, catalytic activity, and surface areas of SnO2 gas sensors, Sensors Actuators B Chem., 1999, 60(1), p 64–70
M. Gardon and J.M. Guilemany, A Review on Fabrication, Sensing Mechanisms and Performance of Metal Oxide Gas Sensors, J. Mater. Sci. Mater. Electron., 2013, 24(5), p 1410–1421
K. Sabiruddin, P.P. Bandyopadhyay, G. Bolelli, and L. Lusvarghi, Variation of Splat Shape with Processing Conditions in Plasma Sprayed Alumina Coatings, J. Mater. Process. Technol., 2011, 211(3), p 450–462. https://doi.org/10.1016/j.jmatprotec.2010.10.020
S. Ghosh, S. Das, T.K. Bandyopadhyay, P.P. Bandyopadhyay, and A.B. Chattopadhyay, Indentation Responses of Plasma Sprayed Ceramic Coatings, J. Mater. Sci., 2003, 38(7), p 1565–1572
N. Yamazoe, G. Sakai, K. Shimanoe, N.Y.Ã.G. Sakai, and K. Shimanoe, Oxide Semiconductor Gas Sensors, Cata. Surv. Asia, 2003, 7(1), p 63–75. https://doi.org/10.1023/a:1023436725457
S. Pati, P. Banerji, and S.B. Majumder, MOCVD Grown ZnO Thin Film Gas Sensors: Influence of Microstructure, Sens. Actuators, A, 2014, 2014(213), p 52–58. https://doi.org/10.1016/j.sna.2014.04.005
K. Mukherjee, D.C. Bharti, and S.B. Majumder, Solution Synthesis and Kinetic Analyses of the Gas Sensing Characteristics of Magnesium Ferrite Particles, Sensors Actuators B Chem., 2010, 146(1), p 91–97. https://doi.org/10.1016/j.snb.2010.02.020
A. Ghosh and S.B. Majumder, Modeling the Sensing Characteristics of Chemi-Resistive Thin Film Semi-Conducting Gas Sensors, Phys. Chem. Chem. Phys. R. Soc. Chem., 2017, 19, p 23431–23443. https://doi.org/10.1039/c7cp04241h
K. Mukherjee and S.B. Majumder, Analyses of Response and Recovery Kinetics of Zinc Ferrite as Hydrogen Gas Sensor, J. Appl. Phys., 2009, 106(6), p 064912
A. Maity, A. Ghosh, and S.B. Majumder, Engineered Spinel-Perovskite Composite Sensor for Selective Carbon Monoxide Gas Sensing, Sensors Actuators B Chem., 2016, 225(2), p 128–140. https://doi.org/10.1016/j.snb.2015.11.025
K. Mukherjee, Gas Sensing Characteristics of Wet Chemical Sythesized Spinel Ferrites. Ph.D Dissertation, Indian Institute of Technology, Kharagpur, 2011.
A. Maity and S.B. Majumder, NO2 Sensing and Selectivity Characteristics of Tungsten Oxide Thin Films, Sensors Actuators B Chem., 2015, 206(2), p 423–429. https://doi.org/10.1016/j.snb.2014.09.082
H.E. Endres, H.D. Jander, and W. Göttler, A Test System for Gas Sensors, Sensors and Actuators B Chem., 1995, 23(2–3), p 163–172
S. Pati, A. Maity, P. Banerji, and S.B. Majumder, Qualitative and Quantitative Differentiation of Gases Using ZnO Thin Film Gas Sensors and Pattern Recognition Analysis, The Analyst, 2014, 139(7), p 1796. https://doi.org/10.1039/c3an02021e
T. Wagner, S. Haffer, C. Weinberger, D. Klaus, and M. Tiemann, Mesoporous Materials as Gas Sensors, Chem. Soc. Rev., 2013, 42(9), p 4036–4053
I. Kocemba and J. Rynkowski, The Influence of Catalytic Activity on the Response of Pt/SnO2 Gas Sensors to Carbon Monoxide and Hydrogen, Sensors and Actuators B Chem., 2011, 155(2), p 659–666. https://doi.org/10.1016/j.snb.2011.01.026
Y. Shimizu, T. Maekawa, Y. Nakamura, and M. Egashira, Effects of Gas Diffusivity and Reactivity on Sensing Properties of Thick Film SnO2 -Based Sensors 1, Sensors and Actuators B Chem., 1998, 46, p 163–168
A. Mirzaei, S.G. Leonardi, and G. Neri, Detection of Hazardous Volatile Organic Compounds (VOCs) by Metal Oxide Nanostructures-Based Gas Sensors: A Review, Ceram. Int., 2016, 42(14), p 15119–15141. https://doi.org/10.1016/j.ceramint.2016.06.145
S. Pati, P. Banerji, and S.B. Majumder, N- to p- Type Carrier Reversal in Nanocrystalline Indium Doped ZnO Thin Film Gas Sensors, Int. J. Hydrogen Energy, 2014, 39(27), p 15134–15141. https://doi.org/10.1016/j.ijhydene.2014.07.075
A. Ghosh and S.B. Majumder, Addressing the Selectivity Issue of Cobalt Doped Zinc Oxide Thin Film Iso-Butane Sensors: Conductance Transients and Principal Component Analyses, J. Appl. Phys., 2017, 122(3), p 034506
K. Mukherjee and S.B. Majumder, Hydrogen Sensing Characteristics of Wet Chemical Synthesized Tailored Mg0.5Zn0.5Fe2O4 Nanostructures, Nanotechnology, 2010, 21(25), p 255504
A. Ghosh, T. Schneller, R. Waser, and S.B. Majumder, Understanding on the Selective Carbon Monoxide Sensing Characteristics of Copper Oxide-Zinc Oxide Composite Thin Films, Sensors Actuators B Chem., 2017, 253, p 685–696. https://doi.org/10.1016/j.snb.2017.06.154
Acknowledgments
The above research work was partially supported by the research grant obtained from CSIR, Government of India; vide sanction Letter No. 03/(1371)/16/EMR-II, dated 10-05-2016 and DST, Government of India; vide sanction letter Nos. 5(1)/2017-NANO dated 28-03-2018 and DST/NM/NNETRA/2018(G)-IITKGP dated 21-03-2018.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Ambardekar, V., Bandyopadhyay, P.P. & Majumder, S.B. Sensing Capability of Air Plasma-Sprayed SnO2 Coating in the Presence of Hydrogen and Carbon Monoxide. J. of Materi Eng and Perform 28, 6728–6735 (2019). https://doi.org/10.1007/s11665-019-04415-2
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-019-04415-2