Skip to main content
Log in

Microstructure Evolution and Mechanical Properties of the AZ91 Magnesium Alloy with Sr and Ti Additions in the As-Cast and As-Aged Conditions

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

Effect of different amounts of Sr and Ti additions with T6 heat treatment on microstructure and mechanical properties of the AZ91 alloy was investigated. The microstructure of the AZ91 alloy is consisted of the α-Mg phase surrounded by the semicontinuous network of β-Mg17Al12 intermetallics. The average grain size and volume fraction of β phase decreased up to 1 wt.% Sr and 0.1 wt.% Ti additions. Exceeding Ti additions led to increase in both grain size and volume fraction. It was found that the grain refinement mechanism of AZ91 alloys with Sr additions was grain restriction factor. Also, 0.1 wt.% Ti addition could refine the grain structure of the AZ91 alloy by the formation of Al3Ti particles that act as nucleation sites for the α-Mg phase. Furthermore, adding 1 wt.% Sr and 0.1 wt.% Ti enhanced the hardness values for both cast and aged AZ91 alloy. Moreover, ultimate tensile strength and tensile elongation values reached their maximum amounts with the 0.5 wt.% Sr and 0.1 wt.% Ti additions and more Sr and Ti additions deteriorated the mechanical properties of cast and aged AZ91 alloys. The fracture surface characterizations had good relations with the tensile properties. The fracture modes were cleavage and quasi-cleavage in the cast and aged AZ91 alloys. Furthermore, the optimum levels of Sr and Ti additions altered the fracture modes to more quasi-cleavage fractures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. F. Pan, M. Yang, and X. Chen, A Review on Casting Magnesium Alloys: Modification of Commercial Alloys and Development of New Alloys, J. Mater. Sci. Technol., 2016, 32, p 1211–1221

    Article  Google Scholar 

  2. C. Dehghanian, M. Lotfpour, and M. Emamy, The Microstructure, and Mechanical and Corrosion Properties of As-Cast and As-Extruded Mg-2%Zn-x%Cu Alloys After Solution and Aging Heat Treatments, J. Mater. Eng. Perform., 2019, https://doi.org/10.1007/s11665-019-03978-4

    Article  Google Scholar 

  3. D. Zhang, D. Zhang, B. Fanqiang, X. Li, K. Guan, Q. Yang, S. Liu, X. Liu, and J. Meng, Effects of Minor Sr Addition on the Microstructure, Mechanical Properties and Creep Behavior of High Pressure Die Casting AZ91-0.5RE Based Alloy, Mater. Sci. Eng. A., 2017, 693, p 51–59

    Article  CAS  Google Scholar 

  4. B.N. Sahoo, F. Khan, S. Babu, S.K. Panigrahi, and G.D. Janaki Ram, Microstructural Modification and Its Effect on Strengthening Mechanism and Yield Asymmetry of In Situ TiC-TiB2/AZ91 Magnesium Matrix Composite, Mater. Sci. Eng. A, 2018, 724, p 269–282

    Article  CAS  Google Scholar 

  5. H. Lin, M. Yang, H. Tang, H. Tang, and F. Pan, Effect of Minor Sc on the Microstructure and Mechanical Properties of AZ91 Magnesium Alloy, Proc. Nat. Sci. Mater., 2018, 28, p 66–73

    CAS  Google Scholar 

  6. P. Mónica, P.M. Bravo, and D. Cárdenas, Deep cryogenic Treatment of HPDC AZ91 Magnesium Alloys Prior to Aging and Its Influence on Alloy Microstructure and Mechanical Properties, J. Mater. Process. Technol., 2017, 239, p 297–302

    Article  Google Scholar 

  7. J.U. Lee, S.-H. Kim, Y.J. Kim, and S.H. Park, Effects of Homogenization Time on Aging Behavior and Mechanical Properties of AZ91 Alloy, Mater. Sci. Eng. A, 2018, 714, p 49–58

    Article  CAS  Google Scholar 

  8. H.L. Zhao, S.K. Guan, and F.Y. Zheng, Effects of Sr and B Addition on Microstructure and Mechanical Properties of AZ91 Magnesium Alloy, J. Mater. Res., 2007, 22, p 2423–2428

    Article  CAS  Google Scholar 

  9. M. Suresh, A. Srinivasan, K.R. Ravi, U.T.S. Pillai, and B.C. Pai, Influence of Boron Addition on the Grain Refinement and Mechanical Properties of AZ91 Mg Alloy, Mater. Sci. Eng. A, 2009, 525, p 207–210

    Article  Google Scholar 

  10. Y. Guangyin, S. Yangshan, and D. Wenjiang, Effects of Bismuth and Antimony Additions on the Microstructure and Mechanical Properties of AZ91 Magnesium Alloy, Mater. Sci. Eng. A, 2001, 308, p 38–44

    Article  Google Scholar 

  11. E. Koc, M. Unal, Y. Turen, H.A. Goren, and E. Candan, Effect of Lead Additions on Microstructure and Casting properties of AZ magnesium alloy, Int. J. Mater. Sci. Appl., 2018, 7, p 13–17

    CAS  Google Scholar 

  12. M. Vlasceanu, S. Lun Sin, A. Elsayed, and C. Ravindran, Effect of Al-5Ti-1B on Grain Refinement, Dendrite Coherency and Porosity of AZ91E Magnesium Alloy, Int. J. Cast Met. Res., 2015, 28, p 39–46

    Article  CAS  Google Scholar 

  13. S.C. Kurnaz, H. Sevik, S. Acikgöz, and A. Özel, Influence of Titanium and Chromium Addition on the Microstructure and Mechanical Properties of Squeeze Cast Mg-6Al Alloy, J. Alloys Compd., 2011, 590, p 1390–3196

    Google Scholar 

  14. S. Candan, M. Celik, and E. Candan, Effectiveness of Ti-Micro Alloying in Relation to Cooling Rate on Corrosion of AZ91 Mg Alloy, J. Alloys Compd., 2016, 672, p 197–203

    Article  CAS  Google Scholar 

  15. A. Srinivasan, U.T.S. Pillai, and B.C. Pai, Effect of Pb Addition on Ageing Behavior of AZ91 Magnesium Alloy, Mater. Sci. Eng. A, 2007, 452, p 87–92

    Article  Google Scholar 

  16. A. Srinivasan, U.T.S. Pillai, and B.C. Pai, Effects of Elemental Additions (Si and Sb) on the Ageing Behavior of AZ91 Magnesium Alloy, Mater. Sci. Eng. A, 2010, 527, p 6543–6550

    Article  Google Scholar 

  17. B. Amir Esgandari, H. Mehrjoo, B. Nami, and S.M. Miresmaeili, Effect of Ca and RE Elements on the Precipitation Kinetics of Mg Phase During Artificial Aging of Magnesium Alloy AZ91, Mater. Sci. Eng. A, 2011, 528, p 5018–5024

    Article  Google Scholar 

  18. H. Chandler, Heat Treater’s Guide Practices and Procedures for Nonferrous Alloys, Materials Park, ASM International, 1996, p 436

    Google Scholar 

  19. G. Petzow and V. Carle, Metallographic Etching, 2nd ed., ASM International, Materials Park, 2008, p 114–117

    Google Scholar 

  20. A. Maltais, D. Dubé, M. Fiset, G. Laroche, and S. Turgeon, Improvements in the Metallography of As-cast AZ91 Alloy, Mater. Charact., 2004, 52, p 103–119

    Article  CAS  Google Scholar 

  21. M. Ohno, D. Mirkovic, and R. Schmid-Fetzer, Liquidus and Solidus Temperatures of Mg-Rich Mg-Al-Mn-Zn Alloys, Acta Mater., 2006, 54, p 3883–3891

    Article  CAS  Google Scholar 

  22. W. Lu, F. Pan, M. Yang, and R. Cheng, An Investigation of Second Phases in As-Cast AZ31 Magnesium Alloys with Different Sr Contents, J. Mater. Res., 2013, 48, p 54

    Google Scholar 

  23. A. Koltygin, V. Bazhenov, and U. Mahmadiyorov, Influence of Al-5Ti-1B Master Alloy Addition on the Grain Size of AZ91 Alloy, J. Magnes. Alloys, 2017, 5, p 313–319

    Article  CAS  Google Scholar 

  24. D. St John, M. Easton, M. Qian, and J. Taylor, Grain Refinement of Magnesium Alloys: A Review of Recent Research, Theoretical Developments, and Their Application, Metall. Mater. Trans. A, 2013, 44, p 2935–2949

    Article  CAS  Google Scholar 

  25. J.L. Murray, The Mg-Ti (Magnesium-Titanium) System, Bull Alloy Phase Diagr., 1986, 7, p 245–247

    Article  CAS  Google Scholar 

  26. Y. Wang, X. Zeng, and W. Ding, Effect of Al-4Ti-5B Master Alloy on the Grain Refinement of AZ31 Magnesium Alloy, Scripta Mater., 2006, 54, p 269–273

    Article  CAS  Google Scholar 

  27. S. Liu, Y. Zhang, H. Han, and B. Li, Effect of Mg-TiB2 Master Alloy on the Grain Refinement of AZ91D Magnesium Alloy, J. Alloys Compd., 2009, 487, p 202–205

    Article  CAS  Google Scholar 

  28. Y. Watanabe, Y.B. Gao, J.Q. Guo, H. Sato, S. Miura, and H. Miura, Heterogeneous Nucleation of Pure Magnesium on Al3Ti, TiC, TiB2, and AlB2 Particles, Jpn. J. Appl. Phys., 2013, 52, p 1S

    Article  Google Scholar 

  29. B.L. Bramfitt, The Effect of Carbide and Nitride Additions on the Heterogeneous Nucleation Behavior of Liquid Iron, Metall. Trans. A, 1970, 1, p 1987–1995

    Article  CAS  Google Scholar 

  30. X. Zeng, Y. Wang, W. Ding, A.A. Luo, and A.K. Sachdev, Effect of Strontium on the Microstructure, Mechanical Properties, and Fracture Behavior of AZ31 Magnesium Alloy, Metall. Mater. Trans. A, 2006, 37, p 1333–1341

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mehdi Malekan.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Afsharnaderi, A., Malekan, M., Emamy, M. et al. Microstructure Evolution and Mechanical Properties of the AZ91 Magnesium Alloy with Sr and Ti Additions in the As-Cast and As-Aged Conditions. J. of Materi Eng and Perform 28, 6853–6863 (2019). https://doi.org/10.1007/s11665-019-04396-2

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-019-04396-2

Keywords

Navigation