Abstract
Rubber-based insulation materials have been widely used in the field of electrical engineering. To develop rubber with excellent nonlinear electrical conductivity can relieve the electric field concentration in the stress cone of a cable accessory. In this study, ethylene propylene diene monomer (EPDM) was selected as the rubber matrix, and copper nanoparticles (CuNPs) were grown on hexagonal boron nitride (BN) using a liquid-phase chemical reduction method. The prepared CuNPs/BN fillers were introduced into the EPDM matrix to obtain CuNPs/BN/EPDM composites. The microstructures of fillers and composites were systematically characterized. Specifically, the electrical conductivity and breakdown field strength at different temperatures were measured and analyzed. The results show that filling CuNPs/BN enables the EPDM to have outstanding nonlinear electrical conductivity and weakens the temperature dependence of the electric breakdown strength. The simulation analyses also prove that CuNPs/BN/EPDM composites with nonlinear conductivity can avoid the electric field concentration in the stress cone, which is beneficial to ensure the safety and reliability operation of a cable accessory.
Graphical Abstract
![](http://media.springernature.com/lw685/springer-static/image/art%3A10.1007%2Fs11664-021-09397-3/MediaObjects/11664_2021_9397_Figa_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11664-021-09397-3/MediaObjects/11664_2021_9397_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11664-021-09397-3/MediaObjects/11664_2021_9397_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11664-021-09397-3/MediaObjects/11664_2021_9397_Fig3_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11664-021-09397-3/MediaObjects/11664_2021_9397_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11664-021-09397-3/MediaObjects/11664_2021_9397_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11664-021-09397-3/MediaObjects/11664_2021_9397_Fig6_HTML.png)
Similar content being viewed by others
References
Z. Chong, J.W. Zha, S.J. Wang, Y.H. Wu, H.D. Yan, W.K. Li, C. Xin, and Z.M. Dang, Insul. Mater. 49, 1 (2016).
J.L. He, J.C. Xie, and J. Hu, High Volt. Eng. 40, 637 (2014).
C.Y. Liu, Y. Zheng, B. Zhang, X.Q. Zheng, S.Q. Hu, and K. Han, IEEE Access 7, 50536 (2019).
J.C. Xie, J. Hu, and J.L. He, High Volt. Eng. 41, 446 (2015).
B.Z. Han, M.L. Fu, C.Y. Li, Z. Hong, S. Hou, and Z.H. Li, High Volt. Eng. 40, 2627 (2014).
L. Donzel, F. Greuter, and T. Christen, IEEE Electr. Insul. Mater. 27, 18 (2011).
C. Önneby, E. Mårtensson, U. Gafvert, A. Gustafsson, and L. Palmqvist, ICSD'01. Proceedings of the 20001 IEEE 7th International Conference on Solid Dielectrics (Cat. No.01CH37117) (2001), p. 43.
Q.G. Chi, M.J. Feng, T.D. Zhang, C.H. Zhang, and Q.Q. Lei, 2019 2nd International Conference on Electrical Materials and Power Equipment (ICEMPE) (2019), p. 268.
H. Peng, J.W. Zha, M.S. Zheng, H.Y. Li, Y.Q. Wen, and Z.M. Dang, J. Appl. Phys. 123, 205113 (2018).
J. Li, B.X. Du, X.X. Kong, and Z.L. Li, IEEE Trans. Dielectr. Electr. Insul. 24, 1566 (2017).
M. Wåhlander, F. Nilsson, R.L. Andersson, C.C. Sanchez, N. Taylor, A. Carlmark, H. Hillborg, and E. Malmström, J. Mater. Chem. A. 5, 14241 (2017).
Q.G. Chi, X.B. Wang, Z. Wei, C.H. Zhang, T.D. Zhang, W. Xuan, and Q.Q. Lei, Results Phys. 11, 52 (2018).
S. Vudayagiri, S. Zakaria, L. Yu, S.S. Hassouneh, and A.L. Skov, Smart Mater. Struct. 23, 105017 (2014).
Z. Li, C. Zhao, and H. Zhang, Materials 11, 9 (2018).
Q.G. Chi, Z. Li, T.D. Zhang, and C.H. Zhang, IEEE Trans. Dielectr. Electr. Insul. 26, 681 (2019).
Q.G. Chi, Y.Y. Hao, T.D. Zhang, C.H. Zhang, Q.G. Chen, and X. Wang, J. Mater. Sci. Mater. Electron. 29, 19678 (2018).
P. Yang, M. He, X.C. Ren, and K. Zhou, J. Polym. Res. 27, 132 (2020).
Q.L. Zhang, Z.M. Yang, B.J. Ding, X.Z. Lan, and Y.J. Guo, Trans. Nonferrous Met. Soc. China 20, s240 (2010).
Q.G. Chi, M. Yang, C.H. Zhang, T.D. Zhang, Y. Feng, and Q.G. Chen, IEEE Trans. Dielectr. Electr. Insul. 26, 1081 (2019).
X.F. Tang, Z.G. Yang, and W.J. Wang, Colloids Surf. A 360, 99 (2010).
B. Dong, Y.X. Zhang, and Y.W. Wu, Powder Metall. Ind. 28, 8 (2018).
Q.G. Chi, S. Cui, T.D. Zhang, M. Yang, and Q.G. Chen, IEEE Trans. Dielectr. Electr. Insul. 27, 535 (2020).
W.M. Guo, Y. Wang, Z. Rong, and Z.H. Li, Proceedings of 2011 6th International Forum on Strategic Technology (2011), p. 133.
Z.H. Yang, P.H. Hu, S.J. Wang, J.W. Zha, Z.C. Guo, and Z.M. Dang, IEEE Trans. Dielectr. Electr. Insul. 24, 1735 (2017).
Q.G. Chi, S. Cui, T. D. Zhang, M. Yang, and Q. Q. Lei, AIP Adv. 10, (2020).
P. Budenstein, IEEE Trans. Electr. Insul. 15, 225 (2007).
Acknowledgments
This work was supported by the National Natural Science Foundation of China (No. 51807042), Outstanding Youth Fund of Heilongjiang Province (No. YQ2020E031), China Postdoctoral Science Foundation (No. 2021T140166), Fundamental Research Foundation for Universities of Heilongjiang Province, (2019-KYYWF-0208), Open Foundation of State Key Laboratory of Electronic Thin Films and Integrated Devices (No. KFJJ201904).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors have no conflicts of interest to declare that are relevant to the content of this article.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Zhang, T., Dai, C., Zhang, C. et al. Investigations on the Electrical Performances of CuNPs/BN/EPDM Composites. J. Electron. Mater. 51, 1349–1357 (2022). https://doi.org/10.1007/s11664-021-09397-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11664-021-09397-3