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The Role of the Substrate on Photophysical Properties of Highly Ordered 15R-SiC Thin Films

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Abstract

We report on the structural optimization and photophysical properties of in situ RF-sputtered single crystalline 15R-SiC thin films deposited on various substrates (ZrO2, MgO, SiC, and Si). The role of the substrates on the structural, electronic, and photodynamic behavior of the grown films have been demonstrated using x-ray diffraction, photoluminescence (PL) and time-resolved photoluminescence spectroscopy. The appropriate bonding order and the presence of native oxide on the surface of the grown samples are confirmed by x-ray photoelectron spectroscopy measurement. A deep-blue PL emission has been observed corresponding to the Si-centered defects occurring in the native oxide. Deconvolution of the PL spectra manifested two decay mechanisms corresponding to the radiative recombination. The PL intensity and carrier lifetime were found to be substrate- dependent which may be ascribed to the variation in the trap-density of the films grown on different substrates.

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  • 21 September 2018

    The wrong issue and volume number are indicated on the published article. This article appears in Volume 47, Number 9.

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Correspondence to Ramesh Chandra.

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Mourya, S., Jaiswal, J., Malik, G. et al. The Role of the Substrate on Photophysical Properties of Highly Ordered 15R-SiC Thin Films. J. Electron. Mater. 47, 5259–5268 (2018). https://doi.org/10.1007/s11664-018-6411-6

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  • DOI: https://doi.org/10.1007/s11664-018-6411-6

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