Abstract
In this study, ultra-low-fire ceramic composites of Zn2Te3O8-30 wt.%TiTe3O8 (ZTT) were prepared by a solid-state reaction method. Densified at 600°C, the best microwave dielectric properties at 8.5 GHz were measured with the ε r , tanδ, Q × f, and τ f as 25.6, 1.5 × 10−4, 56191 GHz and 1.66 ppm/°C, respectively. Thin films of ultra-low-fire ZTT were prepared by a radio-frequency magnetron sputtering method. ZTT films which deposited on Au/NiCr/SiO2/Si (100) substrates at 200°C showed good adhesion. From ultra-low-fire ceramic to ultra-low-fire ZTT thin films, the latter maintained all the good high-frequency dielectric properties of the former: high dielectric constant (ε r ∼ 25) and low dissipation factor (tanδ < 5×10−3), low leakage current density (∼ 10−9 A/cm2) and ultra low processing temperature. These excellent properties of the ultra-low-fire ZTT thin film make it possible to be integrated in MMIC and be applied in the research of GaN and GaAs MOSFET devices.
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C.H. Ng, K.W. Chew, and S.F. Chu, IEEE Electron Device Lett. 24, 506 (2003).
L.Y. Tu, H.L. Lin, L.L. Chao, D. Wu, C.S. Tsai, C. Wang, C.F. Huang, C.H. Lin, and J. Sun, Symposium on VLSI Technology (2003), p. 79–80.
S.B. Chen, J.H. Lai, K.T. Chan, A. Chin, J.C. Hsieh, and J. Liu, IEEE Electron Device Lett. 23, 203 (2002).
C. Zhu, H. Hu, X.Yu, A. Chin, M.F. Li, and D.L. Kwong, IEDM Technical Digest (2003), p. 379–382.
S.J. Kim, B.J. Cho, M.-F. Li, C. Zhu, A. Chin, and D.L. Kwong, Symposium on VLSI Technology (2003), p. 77–78.
S.J. Kim, B.J. Cho, S.J. Ding, M.-F. Li, M.B. Yu, C. Zhu, A. Chin, and D.-L. Kwong, Symposium on VLSI Technology (2004), p. 218–219.
C. Zhu, H. Hu, X. Yu, and S.J. Kim, IEDM Technical Digest (2003), p. 879–882.
T. Ishikawa, D. Kodama, Y. Matsui, M. Hiratani, T. Furusawa, and D. Hisamoto, IEDM Technical Digest (2002), p. 940–942.
R.A. Bakar, S. Sulaiman, and N.F.M. Lazim, International Conference on Nanoscience and Nanotechnology, (NANO-Sci-Tech 2008), p. 385.
K. Sudheendran, K.C.J. Raju, and M.K. Singh, J. Appl. Phys. 104, 104104 (2008).
W. Chen, K.G. McCarthy, and A. Mathewson, IEEE Electron Device Lett. 31, 996 (2010).
T. Kim, A.I. Kingon, J.P. Maria, and R.T. Croswell, J. Mater. Res. 19, 2841 (2004).
A.I. Kingon and S. Srinivasan, Nat. Mater. 4, 233 (2005).
D. Zhou, C.A. Randall, H. Wang, L.X. Pang, and X. Yao, J. Am. Ceram. Soc. 93, 1096 (2010).
D. Zhou, C.A. Randall, L.X. Pang, H. Wang, X.G. Wu, J. Guo, G.Q. Zhang, L. Shui, and X. Yao, J. Am. Ceram. Soc. 94, 802 (2011).
W.H. Liu, H. Wang, D. Zhou, and K.C. Li, J. Am. Ceram. Soc. 93, 2202 (2010).
K.T. Kang, M.H. Lim, H.G. Kim, Y. Choi, H.L. Tuller, I.D. Kim, and J.M. Hong, Appl. Phys. Lett. 87, 242908 (2005).
K.C. Chiang, C.H. Lai, A. Chin, T.J. Wang, H.F. Chiu, J.R. Chen, S.P. McAlister, and C.C. Chi, IEEE Electron Device Lett. 26, 728 (2005).
C.H. Choi, J.Y. Choi, K.H. Cho, M.J. Yoo, J.H. Choi, S. Nahm, C.Y. Kang, S.J. Yoon, and H.J. Lee, J. Electrochem. Soc. 155, G87 (2008).
N. Dewan, V. Gupta, K. Sreenivas, and R.S. Katiyar, J. Appl. Phys. 101, 084910 (2007).
Y.H. Jeong, J.B. Lim, S. Nahm, H.J. Sun, and H.J. Lee, IEEE Electron Device Lett. 28, 17 (2007).
S.F. Wang, Y.F. Hsu, Y.R. Wang, and C.C. Sung, J. Am. Ceram. Soc. 94, 812 (2011).
S.F. Wang, Y.R. Wang, Y.F. Hsu, and J.S. Tsai, J. Eur. Ceram. Soc. 30, 1737 (2010).
S.J. Fiedziuszko, I.C. Hunter, T. Itoh, Y. Kobayashi, T. Nishikawa, S.N. Stitzer, and K. Wakino, IEEE Trans. Microwave Theory Tech. 50, 706 (2002).
D.K. Kwon, M.T. Lanagan, and T.R. Shrout, Mater. Lett. 61, 2007 (1827).
D. Zhou, D. Guo, W.B. Li, L.X. Pang, X. Yao, D.W. Wang, and I.M. Reaney, J. Mater. Chem. C 4, 5357 (2016).
L.X. Pang, D. Zhou, Z.M. Qi, W.G. Liu, Z.X. Yue, and I.M. Reaney, J. Mater. Chem. C 5, 2695 (2017).
S.-F. Wang, Y.-F. Hsu, Y.-R. Wang, and C.-C. Sung, J. Am. Ceram. Soc. 94, 812 (2011).
M. Udovic, M. Valant, and D. Suvorov, J. Am. Ceram. Soc. 87, 591 (2004).
G. He, J. Liu, H. Chen, Y. Liu, Z. Sun, X. Chen, M. Liu, and L. Zhang, J. Mater. Chem. C 2, 5299 (2014).
G. He, J. Gao, H. Chen, J. Cui, Z. Sun, X. Chen, and A.C.S. Appl, Mater. Interfaces 6, 22013 (2014).
J. Zhang, G. He, L. Zhou, H. Chen, X. Chen, B. Deng, J. Lv, and Z. Sun, Alloys Compd. 611, 253 (2014).
G. He, B. Deng, H. Chen, X. Chen, J. Lv, Y. Ma, and Z. Sun, APL Mater. 1, 012104 (2013).
J.C. Yang, X.Q. Meng, C.T. Yang, and Y. Zhang, Appl. Surf. Sci. 287, 355 (2013).
H.B. Zhou, H.Y. Zhang, L.W. Han, and J.C. Han, Superlattice Microst. 64, 563 (2013).
C.H. Choi, J.Y. Choi, K.H. Cho, M.J. Yoo, S. Nahm, C.Y. Kang, S.J. Yoon, and J.H. Kim, Electrochem. Solid St. 11, G51 (2008).
C.H. Choi, J.Y. Choi, K.H. Cho, M.J. Yoo, S. Nahm, C.Y. Kang, S.J. Yoon, and J.H. Kim, J. Electrochem. Soc. 155, G199 (2008).
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This work was supported by the Innovation Foundation of Collaboration Innovation Center of Electronic Materials and Devices (No. ICEM2015-4002).
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Qu, S., Zhang, J., Wu, K. et al. Study on Structural and Dielectric Properties of Ultra-Low-Fire Integratable Dielectric Film for High-Frequency and Microwave Application. J. Electron. Mater. 47, 1944–1951 (2018). https://doi.org/10.1007/s11664-017-5995-6
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DOI: https://doi.org/10.1007/s11664-017-5995-6