Abstract
The present study has focused on the detailed dilatometric and electron microscopic analysis of the formation of austenite and its decomposition in two Cerium (Ce) modified steels containing 0.6 and 0.03 wt pct Ce. Despite a long incubation time, the austenite formation is very fast in the high-Ce steel (0.6 wt pct Ce) during heating. Whereas, the low-Ce steel (0.03 wt pct Ce) promotes early nucleation of austenite but shows a significant delay in the completion of the transformation. Similar trend has been observed for the decomposition of austenite during cooling; the low-Ce steel shows early start of transformation with a sluggish kinetics. The role of Ce on the overall transformation kinetics of austenite during the heating–cooling cycle has been investigated and discussed from thermodynamic viewpoint and nucleation probability. Engineering stress–strain curves have shown a better combination of strength and ductility in the low-Ce steel compared to the high-Ce one. Coarse and spherical Ce2O3 particles (average dia. ~ 4 µm) in grain interior along with the brittle and grain boundary elongated Ce-C/Ce-Fe intermetallic phases (length ~ 8 µm and width ~ 3 µm) are responsible for the lower strain hardening as well as an early failure of the high-Ce steel. Finally, the microstructure-tensile property correlation has been established using chemical composition and fractographic analysis.
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F. Pan, J. Zhang, H.L. Chen, Y.H.H.H. Su, C.L. Kuo, Y.H.H.H. Su, S.H. Chen, K.J. Lin, P.H. Hsieh, and W.S. Hwang: Materials (Basel)., 2016, vol. 9, p. 417.
D.S. Sarma, A. V. Karasev, P.G. Jonsson, P.G. Jönsson (2009) ISIJ Int., 49, 1063–74.
Y. Ji, M.-X.X. Zhang, and H. Ren: Metals (Basel)., 2018, vol. 8, p. 884.
A. Karmakar and K. Barat: Philos. Mag. Lett., 2019, vol. 99, pp. 261–73.
A. Karmakar, A. Karani, S. Patra, and D. Chakrabarti (2013) Metall. Mater. Trans. A vol. 44, pp. 2041–52.
M.Z. Jiang, Y.C. Yu, H. Li, X. Ren, and S.B. Wang: High Temp. Mater. Process., 2017, vol. 36, pp. 145–53.
W. Bleck and K. Phiu-On: in Materials Science Forum, vol. 500–501, Materials Science Forum, San Sebastian, Spain, 2005, pp. 97–112.
B. Shakerifard, J. Galan Lopez, F. Hisker, and L.A.I.I. Kestens (2018) IOP Conf. Ser. Mater. Sci. Eng., 375, 12022.
A. Karmakar, R.D.K. Misra, S. Neogy, and D. Chakrabarti (2013) Metall. Mater. Trans. A, vol. 44, pp. 4106–18.
W. Longmei (2004) Chinese Rare. 22, 48–54.
D. Zhou, P. Peng, J.L.S. Xu, and R. Stud (2004) Foundry Equip, 40: 35–38.
F. Pan, J. Zhang, H.-L. Chen, Y.-H.Y.-H. Su, Y.-H.Y.-H. Su, and W.-S. Hwang: Sci. Rep., 2016, vol. 6, p. 35843.
G.M. Ecer and G.H. Meier: Oxid. Met., 1979, vol. 13, pp. 159–80.
D. Pilone, A. Brotzu, and F. Felli: Procedia Struct. Integr., 2016, vol. 2, pp. 2291–8.
X. Li, J. Shu, L. Chen, and H. Bi: Acta Metall. Sin. (English Lett., 2014, vol. 27, pp. 501–7.
M.F. Pillis, O.V. Correa, and L.V. Ramanathan: Mater. Res., 2016, vol. 19, pp. 611–7.
Y. Nishiyama, Y. Sawaragi, T. Matsuda, S. Kihara, and I. Kajigaya (1998) Sumitomo Searc 4: 27-33.
A. Bhattacharya, A. Karmakar, A. Karani, M. Ghosh, and D. Chakrabarti: J. Mater. Eng. Perform., 2019, vol. 28, pp. 753–68.
Z. Yu and C. Liu: Metals (Basel)., 2019, vol. 9, p. 804.
F. Pan, H.L. Chen, Y.H. Su, Y.H. Su, and W.S. Hwang: Sci. Rep., 2017, vol. 7, pp. 1–8.
P.E. Waudby: Int Met Rev, 1978, vol. 23, pp. 74–98.
B. Wen, B. Song, N. Pan, Q. Shu, X. Hu, and J. Mao: J. Iron Steel Res. Int., 2011, vol. 18, pp. 38–44.
P. Dutta, S. Pal, M.S. Seehra, Y. Shi, E.M. Eyring, and R.D. Ernst: Chem. Mater., 2006, vol. 18, pp. 5144–6.
J. Dhanalakshmi, S. Iyyapushpam, S.T. Nishanthi, M. Malligavathy, D. P. Padiyan(2017) Adv. Nat. Sci. Nanosci. Nanotechnol., 8, 1015015.
M. Song, B. Song, Z. Yang, S. Zhang, and C. Hu: High Temp. Mater. Process., 2017, vol. 36, pp. 683–91.
H. Zhang, I.E. Castelli, S. Santucci, S. Sanna, N. Pryds, and V. Esposito: Phys. Chem. Chem. Phys., 2020, vol. 22, pp. 21900–8.
Z. Adabavazeh, W.S. Hwang, and Y.H. Su: Sci. Rep., 2017, vol. 7, p. 46503.
H. Mabuchi, R. Uemori, and M. Fujioka: ISIJ Int., 1996, vol. 36, pp. 1406–12.
D. Loder, S.K. Michelic, and C. Bernhard: J. Mater. Sci. Res., 2016, vol. 6, p. 24.
F. Chai, H. Su, C. Yang, and D. Xue: J. Iron Steel Res. Int., 2014, vol. 21, pp. 369–74.
T. Nishizawa, I. Ohnuma, and K. Ishida: Mater. Trans. JIM, 1997, vol. 38, pp. 950–6.
C.-K.K. Lin, H.-H.H. Lai, Y.-H.H.F. Su, G.-R.R. Lin, W.-S.S. Hwang, and J.-C.C. Kuo: Materials (Basel)., 2018, vol. 11, p. 2241.
Z. Adabavazeh, W.-S. Hwang, and A.R.A. Dezfoli: Crystals, 2017, vol. 7, p. 308.
M. Tang, K. Wu, J. Liu, L. Cheng, X. Zhang, and Y. Chen: Materials (Basel)., 2019, vol. 12, pp. 30–5.
Y. Xiang, Z. Chen, X. Wei, and Z. Wu: Xiyou Jinshu Cailiao Yu Gongcheng, 2015, vol. 44, pp. 1335–9.
F. Hao, B. Liao, D. Li, T. Dan, X. Ren, Q. Yang, and L. Liu: J. Rare Earths, 2011, vol. 29, pp. 609–13.
Y. Wang, G. Cheng, W. Wu, and Y. Li: Corros. Sci., 2018, vol. 130, pp. 252–60.
C. Liu, R.I. Revilla, Z. Liu, D. Zhang, X. Li, and H. Terryn: Corros. Sci., 2017, vol. 129, pp. 82–90.
H. Fu, Q. Xiao, J. Kuang, Z. Jiang, and J. Xing: Mater. Sci. Eng. A, 2007, vol. 466, pp. 160–5.
B.L. Mordike: Physical Metallurgy Principles, vol. 17, Van Nostrand, 1965.
P. Paupler and G.E. Dieter: Mechanical Metallurgy., vol. 23, McGraw-Hill, New York, 2011.
Callister W. D. (1997) Materials Science and Engineering: An Introduction, 6th edn., Wiley: New York.
R.E.Smallman and R.J. Bishop (1999) Modern Physical Metallurgy and Materials Engineering, Elsevier, Amsterdam.
C. Halder, A. Karmakar, S.M. Hasan, D. Chakrabarti, M. Pietrzyk, N. Chakraborti (2016) Metall. Mater. Trans. A, vol. 47, pp. 5890–906.
S. Roy, A. Karmakar, S. Mukherjee, S. Kundu, D. Srivastava, and D. Chakrabarti: Mater. Sci. Technol. (United Kingdom), 2014, vol. 30, pp. 1142–53.
S. Patra, A. Mandal, M. Mandal, V. Kumar, R. Mitra, and D. Chakrabarti: Metall. Mater. Trans. A, 2019, vol. 50, pp. 947–65.
R. Pradhan, A. Karmakar, M. Ghosh, D. Chakrabarti, and S. Mukherjee: SN Appl. Sci., 2019, vol. 1, p. 663.
S.M. Hasan, M. Ghosh, D. Chakrabarti, and S.B. Singh: Mater. Sci. Eng. A, 2020, vol. 771, p. 138590.
S. Patra, S. Roy, V. Kumar, A. Haldar, D. Chakrabarti (2011) Metall. Mater. Trans. A, 42, 2575–90.
T.Y. Hsu: ISIJ Int., 1998, vol. 38, pp. 1153–64.
Y. Jingsheng, Y. Zongsen, and W. Chengjian: JOM, 1988, vol. 40, pp. 26–31.
X. Zhang, G. Ma, M. Liu, and Z. Li: Metals (Basel)., 2019, vol. 9, pp. 1–15.
B. Wen, B. Song, N. Pan, Q.Y. Hu, and J.H. Mao: Int. J. Miner. Metall. Mater., 2011, vol. 18, pp. 652–8.
C. García De Andrés, F.G. Caballero, C. Capdevila, and L.F. Álvarez: Mater. Charact., 2002, vol. 48, pp. 101–11.
C.-S. Oh, H.N. Han, C.G. Lee, T.-H. Lee, and S.-J. Kim: Met. Mater. Int., 2004, vol. 10, pp. 399–406.
R. Zhang, W. Zheng, X. Veys, G. Huyberechts, H. Springer, and M. Selleby: J. Phase Equilibria Diffus., 2018, vol. 39, pp. 476–89.
A. Karmakar, M. Ghosh, and D. Chakrabarti: Mater. Sci. Eng. A, 2013, vol. 564, pp. 389–99.
A. Karmakar, M. Mandal, A. Mandal, M. Basiruddin, S. Mukherjee, D. Chakrabarti (2016) J. Metall. Mater. Trans. A, https://doi.org/10.1007/s11661-015-3248-y.
A. Kaal (2010) Annu B. 4, pp. 1–27.
Y. Li, M. Sun, Z. Jiang, C. Chen, K. Chen, X. Huang, S. Sun, and H. Li: Metals (Basel)., 2019, vol. 9, p. 54.
H. Li, Y. Chong Yu, X. Ren, S. H. Zhang, and S. B. Wang (2017) J. Iron Steel Res. Int., vol. 24, pp. 925–34.
K.H.J. Buschow and J.S. van Wieringen: Phys. status solidi, 1970, vol. 42, pp. 231–9.
M. Mardani, I. Fartushna, A. Khvan, V. Cheverikin, D. Ivanov, A. Kondratiev, and A. Dinsdale: J. Alloys Compd., 2018, vol. 730, pp. 352–9.
J.P.Y. Tan, H.R. Tan, C. Boothroyd, Y.L. Foo, C. B. He, M. Lin: J. Phys. Chem. C, 2011, vol. 115, pp. 3544–51.
C. García De Andrés, F.G. Caballero, C. Capdevila, L.F. Álvarez, C. Garcıia de Andrés, F.G. Caballero, C. Capdevila, and L.F. Álvarez: Mater. Charact., 2002, vol. 48, pp. 101–11.
H. Yan, Y. Hu, and D. Zhao: Metall. Mater. Trans. A, 2018, vol. 49, pp. 5271–6.
G. Thewlis: Mater. Sci. Technol., 2006, vol. 22, pp. 153–66.
J. Gao, P. Fu, H. Liu, and D. Li: Metals (Basel)., 2015, vol. 5, pp. 383–94.
D.A. Porter, K.E. Easterling, and M.Y. Sherif: Phase Transformations in Metals and Alloys, Third Edition, Taylor & Francis, 2009.
H. Azizi-Alizamini, M. Militzer, and W.J. Poole: Metall. Mater. Trans. A, 2011, vol. 42, pp. 1544–57.
H.A.-A. Matthias, M.J. Poole (1975) Trans. ISIJ, vol. 15, pp. 305–12.
B.L. Bramfitt: Metall. Trans., 1970, vol. 1, pp. 1987–95.
J. Lan, J. He, W. Ding, Q. Wang, and Y. Zhu: ISIJ Int., 2000, vol. 40, pp. 1275–82.
B.K. Sokolov and V.D. Sadovskii: Met. Sci. Heat Treat. Met., 1959, vol. 1, pp. 7–14.
W.G. Wilson, D.A.R. Kay, and A. Vahed: J Met, 1974, vol. 26, pp. 14–23.
L. Daizhong, G. Shuqin, and Z. Liefu: Steel Res., 1987, vol. 58, pp. 167–71.
L. Daizhong, G. Shugin, and Z. Liefu: Steel Res., 1985, vol. 56, pp. 219–23.
H. Li Daizhong, Wang Zeyu, Zhang Liefu, Wang Xinshi, Shenyang, and Fan Zhanghua: Arch. Eisenhuttenwes.
D.J. Abson: Sci. Technol. Weld. Join., 2018, vol. 23, pp. 635–48.
H.M. Flower and T.C. Lindley: Mater. Sci. Technol., 2000, vol. 16, pp. 26–40.
S.K. Paul, A. Raj, P. Biswas, G. Manikandan, and R.K.K. Verma: Mater. Des., 2014, vol. 57, pp. 211–7.
Y.Y. Jiang, Z.D. Wang, X.T. Deng, and R.D.K. Misra: Key Eng. Mater., 2021, vol. 871, pp. 53–8.
Y. Bergström: Mater. Sci. Eng., 1970, vol. 5, pp. 193–200.
A.J. DeArdo: in HSLA Steels 2015, Microalloying 2015 and Offshore Engineering Steels 2015, T.C.S. for Metals and C.A. of Engineering, eds., Hangzhou, Zhejiang 2015, pp. 17–32.
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Manuscript submitted February 12, 2021; accepted June 7, 2021
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Kadgaye, C., Hasan, S.M., Patra, S. et al. Role of Cerium on Transformation Kinetics and Mechanical Properties of Low Carbon Steels. Metall Mater Trans A 52, 3978–3995 (2021). https://doi.org/10.1007/s11661-021-06358-7
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DOI: https://doi.org/10.1007/s11661-021-06358-7