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Hot Deformation Behavior and Processing Maps of Diamond/Cu Composites

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Abstract

The hot deformation behaviors of 50 vol pct uncoated and Cr-coated diamond/Cu composites were investigated using hot isothermal compression tests under the temperature and strain rate ranging from 1073 K to 1273 K (800 °C to 1000 °C) and from 0.001 to 5 s−1, respectively. Dynamic recrystallization was determined to be the primary restoration mechanism during deformation. The Cr3C2 coating enhanced the interfacial bonding and resulted in a larger flow stress for the Cr-coated diamond/Cu composites. Moreover, the enhanced interfacial affinity led to a higher activation energy for the Cr-coated diamond/Cu composites (238 kJ/mol) than for their uncoated counterparts (205 kJ/mol). The strain-rate-dependent constitutive equations of the diamond/Cu composites were derived based on the Arrhenius model, and a high correlation (R = 0.99) was observed between the calculated flow stresses and experimental data. With the help of processing maps, hot extrusions were realized at 1123 K/0.01 s−1 and 1153 K/0.01 s−1 (850 °C/0.01 s−1 and 880 °C/0.01 s−1) for the uncoated and coated diamond/Cu composites, respectively. The combination of interface optimization and hot extrusion led to increases of the density and thermal conductivity, thereby providing a promising route for the fabrication of diamond/Cu composites.

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Acknowledgments

We acknowledge the financial supports of the National Key R & D Plan (No. 2017YFB0703101) and the National Science Fund for Distinguished Young Scholars (No. 51425203).

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Authors and Affiliations

  1. State Key Laboratory for Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China

    Hongdi Zhang, Yue Liu, Fan Zhang, Di Zhang & Tongxiang Fan

  2. School of Engineering, Cardiff University, Cardiff, CF24 3AA, UK

    Hanxing Zhu

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  1. Hongdi Zhang
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  2. Yue Liu
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  3. Fan Zhang
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  4. Di Zhang
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Correspondence to Tongxiang Fan.

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Manuscript submitted August 14, 2017.

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Zhang, H., Liu, Y., Zhang, F. et al. Hot Deformation Behavior and Processing Maps of Diamond/Cu Composites. Metall Mater Trans A 49, 2202–2212 (2018). https://doi.org/10.1007/s11661-018-4547-x

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