Abstract
Commercial spherical activated carbon (SAC) was modified by impregnation to enhance the catalytic properties of SAC in acetylene hydrochlorination through melamine modification. Different modification conditions for SAC with nitrogen were compared by changing the SAC-Melamine ratios. The effect of carbonization temperature on the modification was also investigated. Surface chemistry and adsorption properties of the modified and unmodified SACs were studied by scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), elementary analysis, BET, and temperature-programmed desorption (TPD). Moreover, the catalytic properties of SAC in acetylene hydrochlorination under differently modified conditions were also investigated. Elemental analysis showed that the nitrogen content of the modified SAC was greatly improved. XPS revealed that nitrogen mainly exists in Pyrrole nitrogen and Pyridine nitrogen. TPD showed that desorption of C2H2 was changed by modification. The conversion rate of acetylene was up to 70% under the following reaction conditions: temperature, 150 °C; C2H2 hourly space velocity (GHSV), 36 h−1; feed volume ratio V (HCl)/V (C2H2) = 1.15. The catalytic properties of SAC were improved significantly via melamine modification.
Similar content being viewed by others
References
Liu ZC, Ling LC, Qiao WM, et al. Effect of Hydrogen on the Mesopore Development of Pitchbased Spherical Activated Carbon Containing Iron during Activation by Steam[J]. Carbon, 1999, 37(12): 2063–2066
Yoon SH, Park YD, Mochida I. Preparation of Carbonaceous Spheres from Suspensions of Pitch Materials[J]. Carbon, 1992, 30(5): 78l–786
Nakashima M, Inagaki M, Centeno TA, et al. On the Adsorption of CO2 by Molecular Sieve Carbons-Volumetric and Gravimetric Studies[J]. Carbon, 1995, 33(9): 1 301–1 306
Zhang HY, Dai B, Wang XG, et al. Hydrochlorination of Acetylene to Vinyl Chloride Monomer Over Bimetallic Au-La/SAC Catalysts[J]. Journal of Industrial and Engineering Chemistry, 2012, 18(1): 49–54
Liu ZC, Ling LC, Qiao WM, et al. Preparation of Pitch-based Spherical Activated Carbon with High Ratio of Mesopore Using Chemical Vapor Deposition Method[J]. Journal of Materials Science Letters, 2000, 19(2): 87–89
Chen Y, Mao YP, Zhu HS, et al. Catalytic Reduction of Hexaminecobalt( III) by Pitchbased Spherical Activated Carbon (PBSAC)[J]. Clean — Soil Air Water, 2010, 38(7): 601–607
Liu ZC, Ling LC, Qiao WM, et al. Preparation of Ppitch-based Spherical Activated Carbon with Developed Mesopore by the Aid of Ferrocene[J]. Carbon, 1999, 37(4): 663–667
Mitani S, Lee SI, Saito K, et al. Contrast Structure and EDLC Performances of Activated Spherical Carbons with Medium and Large Surface Areas[J]. Electrochim Acta, 2006, 51(25): 5 487–5 493
Zhu ZL, Li AM, Zhong S, et al. Preparation and Characterization of Polymer-Based Spherical Activated Carbons with Tailored Pore Structure[J]. Journal of Applied Polymer Science, 2008, 109(3): 1 692–1 698
Liu CJ, Liang XY, Liu XJ, et al. Surface Modification of Pitch-based Spherical Activated Carbon by CVD of NH3 to Improve its Adsorption to Uric Acid[J]. Applied Surface Science, 2008, 254(21): 6 701–6 705
Liu XJ, Zhan L, Liang XY, et al. Experimental Study of Pitch-based Spherical Activated Carbon Modified with Melamine[J]. Sciencepaper Online, 2009, 4(12): 893–899
Volodymyr D. Khavryuchenko. Structural Effects of SKS Active Carbon Modification with Melamine, Studied by SEM, TEM, EDX and Quantum-chemical Simulations[J]. Int. J. Mod. Phys. B, 2011, 25(10):1 377–1 383
Krasnyakova TV, Zhikharev IV, Mitchenko RS, et al. Acetylene catalytic Hydrochlorination Over Mechanically Pre-activated K2PdCl4 Salt: A Study of the Reaction Mechanism[J]. Journal of Catalysis, 2012, 288: 33–43
Mitchenko SA, Krasnyakova TV, Zhikharev IV. Kinetics and Mechanism of Catalytic Acetylene Hydrochlorination with Gaseous HCl on the Surface of Mechanically Activated K2PdCl4[J]. Kinetics and Catalysis, 2009, 50(5): 734–740
Wang SJ, Shen BX, Song QL. Kinetics of Acetylene Hydrochlorination over Bimetallic Au-Cu/C Catalyst[J]. Catalysis Letters, 2010, 134(1–2): 102–109
Song QL, Wang SJ, Shen BX, et al. Palladium-Based Catalysts for the Hydrochlorination of Acetylene: Reasons for Deactivation and Its Regeneration[J]. Petroleum Science and Technology, 2010, 28(18):1 825–1 833
Zhang JL, Liu N, Li W, et al. Progress on Cleaner Production of Vinyl Chloride Monomers Over Non-mercury Catalysts[J]. Frontiers of Chemical Science and Engineering, 2011, 5(4): 514–520
Mitchenko RS, Shubin AA, Vdovichenko AN. Kinetics of the Catalytic Hydrochlorination of Acetylene on the Surface of Mechanically Preactivated K2PtCl4[J]. Theoretical and Experimental Chemistry, 2006, 42(3): 186–189
Qiu S, Xu SW, Ma F, et al. The Photocatalytic Efficiency of the Metal Doped TiO2 with Ceramic Foam as Catalyst Carriers[J]. Powder Technology, 2011, 210(2): 83–86
Ciambelli P, Palma V, Palo E. Comparison of Ceramic Honeycomb Monolith and Foam as Ni Catalyst Carrier for Methane Autothermal Reforming[J]. Catalysis Today, 2010, 155(1–2): 92–100
Nguyen TV, Wu JCS. Photoreduction of CO2 in an Optical-fiber Photoreactor: Effects of Metals Addition and Catalyst Carrier[J]. Applied Catalysis A: General, 2008, 335(1): 112–120
Zhao YQ, Liang YH, Jia QY, et al. Preparation of CuO-CoOMnO/SiO2 Nanocomposite Aerogels as Catalyst Carriers and Their Application in the Synthesis of Diphenyl Carbonate[J]. Journal of Wuhan University of Technology-Materials Science Edition, 2011, 26(4): 595–599
Zhou Y, Yang Q, Luo Q, et al. Preparation and Optimization of a Newtype Low-mercury Catalyst for Hydrochlorination of Acetylene[J]. Applied Chemical Industry, 2011, 40(12): 2 147–2 155
Author information
Authors and Affiliations
Corresponding author
Additional information
Funded by the National Basic Research Program of China (973 Program, 2012CB720302), the Program for Changjiang Scholars and Innovative Research Team in University (No. IRT1161), and the Corps Science and Technology Innovation Team Scheme (2011CC001)
Rights and permissions
About this article
Cite this article
Han, W., Wang, X., Zhu, M. et al. Melamine modification of spherical activated carbon and its effects on acetylene hydrochlorination. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 29, 1147–1151 (2014). https://doi.org/10.1007/s11595-014-1057-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-014-1057-6