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Influence of Zn/Co ratio on dielectric behavior of Na2Zn1 ‐ xCoxP2O7 glasses

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Abstract

A series of zinc phosphate glass doped with cobalt Na2Zn(1 − x)CoxP2O7 (x = 0, 1, 2 and 5 mol%) was synthesized. These glasses were characterized by both infrared and large broadband dielectric spectroscopy. Infrared spectra indicate the increase of Zn/Co ratio creates defect in phosphate network due to the depolymeration of phosphate anions. The dc conductivity increases and activation energy decreases with the amount of cobalt ions in the glass network. The impedance measurements reveal that the total conductivity follows Jonscher’s power law. The dielectric constant and dielectric loss increased with the temperature and decreased with the frequency whatever the cobalt proportion.

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Authors and Affiliations

  1. Faculty of Sciences, Ziane Achour University, BP 3117, 17000, Djelfa, Algeria

    Mohamed Kharroubi, Hamza Assad, Lakhdar Gacem & Cherif Maghni

  2. Institut Européen des Membranes, UMR5635-CNRS–ENSCM, Université de Montpellier, Place Eugène Bataillon, 34095 Cedex 5, Montpellier, France

    Sebastien Balme

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  1. Mohamed Kharroubi
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  2. Hamza Assad
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  3. Sebastien Balme
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  4. Lakhdar Gacem
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  5. Cherif Maghni
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Correspondence to Mohamed Kharroubi.

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Kharroubi, M., Assad, H., Balme, S. et al. Influence of Zn/Co ratio on dielectric behavior of Na2Zn1 ‐ xCoxP2O7 glasses. Ionics 22, 2355–2361 (2016). https://doi.org/10.1007/s11581-016-1770-6

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  • DOI: https://doi.org/10.1007/s11581-016-1770-6

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