Skip to main content
SpringerLink
Log in

High dependency of dielectric properties on copper ions content in the Na2O–P2O5–ZnO glass matrix

  • Published:
Optical and Quantum Electronics Aims and scope Submit manuscript

Abstract

The work in the current study is mainly oriented to investigate the dielectric and some optical properties of (80 − x)[(Na2O)–(P2O5)]–20(ZnO)–x(CuO) glasses, with x-values ranging from 0.0 to 0.5 (x = 0, 1, 2, 3, 4 and 5 mol%). The frequency and composition dependences of the dielectric parameters are discussed and analyzed for insight into the dielectric properties of these glasses in an applied ac electric field of frequencies extending from 1.05 to 100 kHz. The max and min values of real part of dielectric constant (RPDC) and imaginary part of dielectric constant (IPDC) were estimated. The range of values of RPDC between 118.01 and 575.10 for RPDCMax, and 106.85–515.08 for RPDCMin were estimated. The range of values of IPDC between 9.28 and 57.08 for IPDCMax, and 2.85–18.92 for IPDCMin were estimated. The high dependencies of this type of glasses were obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  • Aboulfotoh, N., Elbashar, Y., Ibrahem, M., Elokr, M.: Characterization of copper doped phosphate glasses for optical applications. J. Ceram. Int. 40(7), 10395–10399 (2014)

    Article  Google Scholar 

  • Abrahams, I., Hadzifejzovic, E.: Lithium ion conductivity and thermal behaviour of glasses and crystallised glasses in the system Li2O–Al2O3–TiO2–P2O5. Solid State Ionics 134(3–4), 249–257 (2000)

    Article  Google Scholar 

  • Anderson, G.W., Compton, W.D.: Optical absorption properties of vanadate glasses. J. Chem. Phys. 52, 6166–6174 (1970)

    Article  ADS  Google Scholar 

  • Angell, A.: Dynamic processes in ionic glasses. Chem. Rev. 90, 523 (1990)

    Article  Google Scholar 

  • Arzeian, J.M., Hogarth, C.A.: Some structural, electrical and optical properties of copper phosphate glasses containing the rare-earth europium. J. Mater. Sci. 26, 5353–5366 (1991)

    Article  ADS  Google Scholar 

  • Atyia, H.E.: Deposition temperature effect on the electric and dielectric properties of InSbSe3 thin films. Vacuum 81, 590–598 (2007)

    Article  ADS  Google Scholar 

  • Austin, I.G., Sayer, M., Sussman, R.S.: Amorphous and liquid semiconductors. In: Stuke, J., Brenig, W. (eds.) Proceedings of the 5th International Conference, Garmisch–Partkenkirchen, Germany, p. 1343. Taylor and Francis, London (1973)

    Google Scholar 

  • Bae, B.-S., Weinberg, M.C.: Ultraviolet optical absorptions of semiconducting copper phosphate glasses. J. Appl. Phys. 73(11), 7760–7766 (1993)

    Article  ADS  Google Scholar 

  • Barsoum, M.: Fundamentals of Ceramics, p. 543. McGraw-Hill, New York (1997)

    Google Scholar 

  • Bergo, P., Pontuschka, W.M., Prison, J.M.: Dielectric properties and physical features of phosphate glasses containing iron oxide. Mater. Chem. Phys. 108(1), 142–146 (2008)

    Article  Google Scholar 

  • Bhardwaj, S., Paul, J., Chand, S., Raina, K.K., Kumar, R.: Oxygen vacancy induced dielectric relaxation studies in Bi4−xLaxTi3O12 (x = 0.0, 0.3, 0.7, 1.0) ceramics. J. Mater. Sci. Mater. Electron. 25(10), 4568–4576 (2014)

    Article  Google Scholar 

  • Bhide, A., Hariharan, K.: Sodium ion transport in NaPO3–Na2SO4 glasses. Mater. Chem. Phys. 105, 213–221 (2007)

    Article  Google Scholar 

  • Bottelberghs PH (1978) Low-frequency measurements on solid electrolytes and their interpretations. In: Solid electrolytes. General principles, characterization, materials, applications, chap 10. pp 145–172

  • Brow, R.K.: Review: the structure of simple phosphate glasses. J. Non Cryst. Solids 263–264, 1–28 (2000)

    Article  Google Scholar 

  • Carta, D., Knowles, J.C., Guerry, P., Smith, M.E., Newport, R.J.: Sol–gel synthesis and structural characterisation of P2O5–B2O3–Na2O glasses for biomedical applications. J. Mater. Chem. 19, 150–158 (2009)

    Article  Google Scholar 

  • Chen, R.H., Wang, R.J., Chen, T.M., Shern, C.S.: Studies on the dielectric properties and structural phase transition of K2SO4 crystal. J. Phys. Chem. Solids 61, 519–527 (2000)

    Article  ADS  Google Scholar 

  • Cheng, D.: Field and Wave Electromagnetics, 2nd edn. Addison-Wesley, New York (1989)

    Google Scholar 

  • Duran, A., Fernandez Navarro, J.M.: Structural considerations about SiO2 glasses prepared by sol–gel. J. Non Cryst. Solids 82(1–3), 69–77 (1986)

    Article  ADS  Google Scholar 

  • Edirisinghe, S.P., Hogarth, C.A.: Optical properties of some copper phosphate glasses containing calcium and barium. J. Mater. Sci. Lett. 8, 789–792 (1989)

    Article  Google Scholar 

  • Elbashar, Y.H.: Structural and spectroscopic analyses of copper doped P2O5–ZnOK2O–Bi2O3 glasses. Int. J. Process. Appl. Ceram. 9(3), 169–173 (2015)

    Article  Google Scholar 

  • Elbashar, Y.H., Saeed, A.: Computational spectroscopic analysis by using Clausius–Mossotti method for sodium borate glass doped neodymium oxide. Res. J. Pharm. Biol. Chem. Sci. (RJPBCS) 6(5), 320–326 (2015)

    Google Scholar 

  • ElBatal, F.H., Marzouk, S.Y., Nada, N., Desouky, S.M.: Gamma-ray interaction with copper-doped bismuth–borate glasses. Phys. B Condens. Matter 391(1), 88–97 (2007)

    Article  ADS  Google Scholar 

  • El-Desoky, M.M.: Dielectric behaviour and AC conductivity of sodium borate glass containing CoO. J. Phys. Chem. Solids 59(9), 1659–1666 (1998)

    Article  ADS  Google Scholar 

  • Elhaes, H., Attallah, M., Elbashar, Y., Ibrahim, M., El-Okr, M.: Application of Cu2O doped phosphate glasses for bandpass filter. J. Phys. B Condens. Matter 449, 251–254 (2014a)

    Article  ADS  Google Scholar 

  • Elhaes, H., Attallah, M., Elbashar, Y., Al-Alousi, A., El-Okr, M., Ibrahim, M.: Modeling and optical properties of P2O5–ZnO–CaO–Na2O glasses doped with copper oxide. J. Comput. Theor. Nanosci. 11(10), 2079–2084 (2014b)

    Article  Google Scholar 

  • Elliott, S.R.: A.C. conduction in amorphous chalcogenide and pnictide semiconductors. Adv. Phys. 36, 135 (1987)

    Article  ADS  Google Scholar 

  • Ertuğrul, R., Tataroğlu, A.: Influence of temperature and frequency on dielectric permittivity and ac conductivity of Au/SnO2/n-Si (MOS) Structures. Chin. Phys. Lett. 29, 077304 (2012)

    Article  ADS  Google Scholar 

  • Friebele, E.J., Griscom, D.L., Stapelbroek, M., Weeks, R.A.: Fundamental defect centers in glass: the peroxy radical in irradiated, high-purity, fused silica. Phys. Rev. Lett. 42(20), 1346 (1979)

    Article  ADS  Google Scholar 

  • Gandhi, Y., Purnachand, N., Sudhakar, K.S.V., Satyanarayana, T., Veeraiah, N.: Influence of modifier oxides on some physical properties of antimony borate glass system doped with V2O5. Mater. Chem. Phys. 120(1), 89–97 (2010)

    Article  Google Scholar 

  • Hazra, S., Ghosh, A.: AC conductivity of unconventional bismuth cuprate glass. J. Phys. Condens. Matter 9, 3981–3986 (1997)

    Article  ADS  Google Scholar 

  • Hench, L.L., West, J.K.: Principles of Electronic Ceramics, p. 187. Wiley, New York (1990)

    Google Scholar 

  • Hogarth, C.A., Novikov, A.A.: A study of optical absorption edges in copper–calcium phosphate glasses containing iodine. J. Phys. D Appl. Phys. 16(4), 675–678 (1983)

    Article  ADS  Google Scholar 

  • Ingram, M.D.: Ionic conductivity in glass. Phys. Chem. Glasses 28, 215–234 (1987)

    Google Scholar 

  • Jonscher, A.K.: The ‘universal’ dielectric response. Nature 267, 673 (1977)

    Article  ADS  Google Scholar 

  • Jonscher, K.: Analysis of the alternating current properties of ionic conductors. J. Mater. Sci. 13, 553 (1978)

    Article  ADS  Google Scholar 

  • Kawamura, J., Shimoji, M.: The AC conductivity of superionic conducting glasses (AgI)x−(Ag4P2O7)1−x (x = 0.8, 0.75, 0.7) experiment and analysis based on the generalized Langevin equation. J. Non Cryst. Solids 79(3), 367–381 (1986)

    Article  ADS  Google Scholar 

  • Khawaja, E.E., Tegally, F., Hwang, J.S., Li, A.S.W., Kutub, A.A.: Effect of annealing on the electrical and optical properties of V2O5–GeO2 glasses. J. Mater. Sci. 20(9), 3074–3080 (1985)

    Article  ADS  Google Scholar 

  • Kutub, A.A., Mohamed-Osman, A.E., Hogarth, C.A.: Some studies of the optical properties of copper phosphate glasses containing praseodymium. J. Mater. Sci. 21, 3517–3520 (1986)

    Article  ADS  Google Scholar 

  • Lal, B., Khosa, S.K., Tickoo, R., Bam-zai, K.K., Kotru, P.N.: Dielectric characteristics of melt grown doped KMgF3 crystals. Mater. Chem. Phys. 83, 158–168 (2004)

    Article  Google Scholar 

  • Lee, W.K., Liu, J.F., Nowick, A.S.: Limiting behavior of ac conductivity in ionically conducting crystals and glasses: a new universality. Phys. Rev. Lett. 67, 1559 (1991)

    Article  ADS  Google Scholar 

  • Lee, S., Hwang, S., Cha, M., Shin, H., Kim, H.: Role of copper ion in preventing silver nanoparticles forming in Bi2O3–B2O3–ZnO glass. J. Phys. Chem. Solids 69, 1498–1500 (2008)

    Article  ADS  Google Scholar 

  • List, R.S., Arko, A.J., Bartlett, R.J.: Evidence from photoemission of comparable oxygen-2p and copper-3d character in the states at the Fermi level of YBa2Cu3O6.9. J. Magn. Magn. Mater. 81(1–2), 151–154 (1989)

    Article  ADS  Google Scholar 

  • Maity, S., Bhattacharya, D., Ray, S.K.: Structural and impedance spectroscopy of pseudo-co-ablated (SrBi2Ta2O9)(1 − x)–(La0.67Sr0.33MnO3)x composites. J. Phys. D Appl. Phys. 44, 095403 (2011)

    Article  ADS  Google Scholar 

  • Mansingh, A., Tandon, R.T., Valid, J.D.: Dielectric relaxation in vanadium phosphate glasses. J. Phys. Chem. Solids 36, 1267 (1975)

    Article  ADS  Google Scholar 

  • Maurya, D., Kumar, J.: Dielectric-spectroscopic and ac conductivity studies on layered Na2–X K X Ti3O7 (X= 0.2, 0.3, 0.4) ceramics. J. Phys. Chem. Solids 66(10), 1614–1620 (2005)

    Article  ADS  Google Scholar 

  • Mcswain, B.D., Borrelli, N.F., Su, G.-J.: The effect of composition and temperature on the ultra-violet absorption of glass. Phys. Chem. Glasses 4, 1–10 (1963)

    Google Scholar 

  • Moridi, G.R., Hogarth, C.A.: In: Spear, W.E. (ed.) Proceedings of the 7th International Conference on Amorphous and Liquid Semiconductors, p. 688. CICL, Edinburgh (1977)

    Google Scholar 

  • Murowski, L., Barczynski, R.J.: Dielectric properties of transition metal oxide glasses. Journal of Non Crystalline Solids 185, 84 (1995)

    Article  ADS  Google Scholar 

  • Mustafaeva, S.N., Asadov, M.M., Qahramanov, K.S.: Frequency-dependent dielectric coefficients of TlInS2 amorphous films. Semicond. Phys. Quantum Electron. Optoelectron. 10(2), 58–61 (2007)

    Google Scholar 

  • Narula, K.A., Singh, R., Chandra, S.: Low frequency ac conduction and dielectric relaxation in poly(N-methyl pyrrole). Bull. Mater. Sci. 23(3), 227–232 (2000)

    Article  Google Scholar 

  • Norton, F.H.: Elements of Ceramics. Addison-Wesley Press, Boston (1952)

    Google Scholar 

  • Owen, A.E., Robertson, J.M.: Electronic properties of some simple chalcogenide glasses. J. Non Cryst. Solids 2, 40–51 (1970)

    Article  ADS  Google Scholar 

  • Pankove, J.I.: Optical Processes in Semiconductors, p. 93. Prentice-Hall, New Jersey (1971)

    Google Scholar 

  • Park, K.T., Terakura, K., Oguchi, T., Yanase, A., Ikeda, M.: Implications of band-structure calculations for High-Tc related oxides. J. Phys. Soc. Jpn. 57, 3445–3456 (1988)

    Article  ADS  Google Scholar 

  • Pascuta, P., Borodi, G., Jumate, N., Vida-Simiti, I., Viorel, D., Culea, E.: The structural role of manganese ions in some zinc phosphate glasses and glass ceramics. J. Alloys Compd. 504(2), 479–483 (2010)

    Article  Google Scholar 

  • Pavic, L., Moguš-Milankovic, A., Raghava Rao, P., Šantic, A., Ravi Kumar, V., Veeraiah, N.: Effect of alkali-earth modifier ion on electrical, dielectric and spectroscopic properties of Fe2O3 doped Na2SO4AMOAP2O5 glass system. J. Alloys Compd. 604, 352–362 (2014)

    Article  Google Scholar 

  • Prasad, S.V.G.V.A., Sahaya Baskaran, G., Veeraia, N.: Spectroscopic, magnetic and dielectric investigations of BaO–Ga2O3–P2O5 glasses doped by Cu ions. Phys. Status Solidi (a) 202(14), 2812–2828 (2005)

    Article  ADS  Google Scholar 

  • Proulx, P.P., Cormier, G., Capobianco, J.A., Champagnon, B., Bettinelli, M.: Raman and low frequency Raman spectroscopy of lead, zinc and barium metaphosphate glasses doped with Eu3+ ions. J. Phys. Condens. Matter 6, 275 (1994)

    Article  ADS  Google Scholar 

  • Qasrawi, A.F.: Refractive index, band gap and oscillator parameters of amorphous GaSe thin films. Res. Technol. 40, 610–614 (2005)

    Article  Google Scholar 

  • Qiu, J., Miyauchi, K., Kawamoto, N., Hirao, K.: Long-lasting phosphorescence in Sn2+–Cu2+Sn2+–Cu2+ codoped silicate glass and its high-pressure treatment effect. Appl. Phys. Lett. 81, 394 (2002)

    Article  ADS  Google Scholar 

  • Rami reddy, M., Ravi kumar, V., Veeraiah, N.: Effect of Chromium impurity on dielectric relaxation effects of ZnF2–PbO–TeO2 glasses. Ind. J. Pure Appl. Phys. 33, 48–51 (1995)

    Google Scholar 

  • Ramkumar, J., Sudarsan, V., Chandramouleeswaran, S., Shrikhande, V.K., Kothiyal, G.P., Ravindran, P.V., Kulshreshtha, S.K., Mukherjee, T.: Structural studies on boroaluminosilicate glasses. J. Non Cryst. Solids 354(15–16), 1591–1597 (2008)

    Article  ADS  Google Scholar 

  • Ravi Kumar, V., Veeraiah, N., Buddhudu, S., Jaya Tyaga Raju, V.: Dielectric dispersion in CuO doped ZnF2–PbO–TeO2 glasses. J. Phys. III Fr. 7, 951–961 (1977)

    Google Scholar 

  • Rayan, D.A., Elbashar, Y.H., Rashad, M.M., El-Korashy, A.: Spectroscopic analysis of phosphate barium glass doped cupric oxide for bandpass absorption filter. J. Non Cryst. Solids 382, 52–56 (2013)

    Article  ADS  Google Scholar 

  • Rayan, D.A., Elbashar, Y.H., El Basaty, A.B., Rashad, M.M.: Infrared spectroscopy of cupric oxide doped barium phosphate glass Res. J. Pharm. Biol. Chem. Sci. (RJPBCS) 6(3), 1026–1030 (2015)

    Google Scholar 

  • Saeed, A., El shazly, R.M., Elbashar, Y.H., Abou El-azm, A.M., El-Okr, M.M., Comsan, M.N.H., Osman, A.M., Abdal-monem, A.M., El-Sersy, A.R.: Gamma ray attenuation in developed borate glassy. J. Radiat. Phys Chem 102, 167–170 (2014)

    Article  ADS  Google Scholar 

  • Saeed, A., Elbashar, Y.H., El Kameesy, S.U.: Study of gamma ray attenuation of high-density bismuth silicate glass for shielding applications. Res. J. Pharm. Biol. Chem. Sci. (RJPBCS) 6(4), 1830–1837 (2015a)

    Google Scholar 

  • Saeed, A., Elbashar, Y.H., El Kameesy, S.U.: Towards modeling of copper-phosphate glass for optical bandpass absorption filter. Res. J. Pharm. Biol. Chem. Sci. (RJPBCS) 6(4), 1390–1397 (2015b)

    Google Scholar 

  • Saeed, A., Elbashar, Y.H., El shazly, R.M.: Optical properties of high density barium borate glass for gamma ray shielding applications. J. Opt. Quantum Electron. 48, 1–10 (2016)

    Article  Google Scholar 

  • Saleh, M.N., Gawish, M.M.: Conduction models of semiconducting calcium borate glasses containing iron oxide. J. Appl. Phys. 51, 459 (1980)

    Article  ADS  Google Scholar 

  • Sankır, N.D., Aydın, E., Sankır, M.: Impedance spectroscopy and dielectric properties of silver incorporated indium sulfide thin films. Int. J. Electrochem. Sci. 9, 3864–3875 (2014)

    Google Scholar 

  • Sattar, A.A., Rahman, S.A.: Dielectric properties of rare earth substituted Cu–Zn ferrites. Phys. Status Solidi (a) 200(2), 415–422 (2003)

    Article  ADS  Google Scholar 

  • Satyanarayana, T., Kityk, I.V., Piasecki, M., Bragiel, P., Brik, M.G., Gandhi, Y., Veeraiah, N.: Structural investigations on PbO–Sb2O3–B2O3:CoO glass ceramics by means of spectroscopic and dielectric studies. J. Phys. Condens. Matter 21, 245104 (2009)

    Article  ADS  Google Scholar 

  • Sayer, M., Mansingh, A.: Transport properties of semiconducting phosphate glasses. Phys. Rev. B 6, 4629 (1972)

    Article  ADS  Google Scholar 

  • Şentürk, E.: Dielectric characteristics of a Ce3+-doped Sr0.61Ba0.39Nb2O6 single crystal with cole–cole plots technique. J. Solid State Chem. 177(4–5), 1508–1512 (2004)

    Article  Google Scholar 

  • Sereda, Y., Polishchuk, I.Y., Burin, A.L.: Resonant susceptibility of dielectric glasses in magnetic field. Phys. Rev. B 75, 024207 (2007)

    Article  ADS  Google Scholar 

  • Shelby, J.E. (ed.): Rare Elements in Glasses, Key Engineering Materials, vol. 94–95, p. 161. Trans Tech Publications, Switzerland (1994)

    Google Scholar 

  • Tauc, J.: Amorphous and Liquid Semiconductors, p. 4. Plenum Ch, New York (1974)

    Book  Google Scholar 

  • van Bruggen, C.F.: Monovalent-copper (I; 3d10, S = 0) Induced Oxygen-2p valence band holes with concomitant attractive interaction inside low-dimensional oxygen networks. Phys. Status Solidi (b) 142(2), 537–550 (1987)

    Article  ADS  Google Scholar 

  • Venkateswara Rao, P., Satyanarayana, T., Srinivasa Reddy, M., Gandhi, Y., Veeraiah, N.: Nickel ion as a structural probe in PbO–Bi2O3–B2O3 glass system by means of spectroscopic and dielectric studies. Phys. B 403, 3751–3759 (2008)

    Article  ADS  Google Scholar 

  • Venkateswara Rao, P., Syamprasad, P., Naga Raju, G., RaviKumar, V., Laxmikanth, C., Veeraiah, N.: Dielectric and spectroscopic investigations of copper ions in PbO–Bi2O3–B2O3 glass matrix. Int. J. Eng. Res 2(1), 18–31 (2014)

    Google Scholar 

  • White, M.A.: Physical Properties of Materials. CRC Press, Boca Raton (2011)

    Google Scholar 

  • Yahia, I.S., Fadel, M., Sakr, G.B., Yakuphanoglu, F., Shenouda, S.S., Farooq, W.A.: Analysis of current–voltage characteristics of Al/p-ZnGa2 Se4/n-Si nanocrystalline heterojunction diode. J. Alloys Compd. 509(12), 4414–4419 (2011)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physics, Faculty of Science, Aswan University, Aswan, Egypt

    A. M. Badr & Y. H. Elbashar

  2. Research Center for NanoMaterial Studies and Their Promising Technologies, Aswan University, Aswan, Egypt

    A. M. Badr & Y. H. Elbashar

Authors
  1. A. M. Badr
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Y. H. Elbashar
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Y. H. Elbashar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Badr, A.M., Elbashar, Y.H. High dependency of dielectric properties on copper ions content in the Na2O–P2O5–ZnO glass matrix. Opt Quant Electron 48, 417 (2016). https://doi.org/10.1007/s11082-016-0682-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11082-016-0682-z

Keywords

Search

Navigation