Skip to main content
SpringerLink
Log in

Thermal behavior and dielectric and vibrational studies of Cs2(HAsO4)0.32(SO4)0.68·Te(OH)6

  • Original Paper
  • Published:
Ionics Aims and scope Submit manuscript

Abstract

A new compound from the tellurate family was synthesized under a slow evaporation conditions. A crystalline sample of Cs2(HAsO4)0.32(SO4)0.68·Te(OH)6 (CsAsSTe) was calorimetric and spectroscopically characterized. The infrared and Raman spectra of this new compound recorded at room temperature, in the frequency range 500–4,500 and 50–1,500 cm−1, respectively, confirm the presence and the independence of two types of anion HAs/SO4 and TeO6. The thermal analysis of the title compound shows one endothermal and intense peak at 512 K accompanied by a shoulder at 506 K. However, the conductivity evolution versus temperature showed the presence of the protonic super conduction phase transition. The conductivity relaxation parameters of some H+ and Cs+ conducting in the CsAsSTe material have been determined from an analysis of ac conductivity data measured in a wide temperature range. Transport properties in this compound appear due to H+ ions hopping mechanism.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig.1
Fig.2
Fig.3
Fig.4
Fig.5
Fig.6
Fig.7
Fig.8
Fig.9
Fig.10
Fig.11
Fig.12

Similar content being viewed by others

References

  1. Khemahem H, Ravez J, Daoud A (1996) Ferroelectrics 188:41

    Article  Google Scholar 

  2. Bechibani I, Litaiem H, Ktari L, Lhoste J, Dammak M (2013) J Mol Struct 1045:199–205

    Article  CAS  Google Scholar 

  3. Dammak M, Khemekhem H, Mhiri T, Kolsi AW, Daoud A etal (1998) J Alloys Compd 280:107

  4. Dammak M, Khemakhem H, Mhiri T (2001) J Phys Chem Solids 62:2069

    Article  CAS  Google Scholar 

  5. Khemekhem H (1999) Ferroelectrics 234:47

    Article  Google Scholar 

  6. Diosa JE, Vargas RA, Albinson I, Mellander B-E (2004) Phys Status Solidi B 241(6):1369

    Article  Google Scholar 

  7. Diosa JE, Vargas RA, Albinson I, Mellander B-E (2004) Solid State Commun 132:55

    Article  CAS  Google Scholar 

  8. Diosa JE, Vargas RA, Albinson I, Mellander B-E (2005) Solid State Commun 136:601

    Article  CAS  Google Scholar 

  9. Diosa JE, Vargas RA, Albinson I, Mellander B-E (2006) Ferroelectrics 333:253

    Article  CAS  Google Scholar 

  10. Almond DP, West AR, Grand R (1982) Solid State Commun 44:1277

    Article  CAS  Google Scholar 

  11. Chowdri BVR, Radhakrishnan K (1989) J Non-Cryst Solids 108:323

    Article  Google Scholar 

  12. Macedo PB, Moynihan CT, Bose R (1972) Phys Chem Glas 13:171

    CAS  Google Scholar 

  13. Hodge IM, Ingran MD, West AR (1975) J Electroanal Chem 58:429

    Article  CAS  Google Scholar 

  14. Howell FS, Bose RA, Macedo PB, Moynihan CT (1974) J Phys Chem 78:639

    Article  CAS  Google Scholar 

  15. Dhouib I, Elaoud Z, Mhiri T, Daoud A (2012) J Chem Crystallogr 42:513

    Article  CAS  Google Scholar 

  16. Naili H, Mhiri T, Jaud J (2001) J Solid State Chem 16:161

    Google Scholar 

  17. Hadrich A, Lautie A, Mhiri T (2000) J Raman Spectrosc 31:587

    Article  CAS  Google Scholar 

  18. Hadzi D, Bratos S (1977) The hydrogen bond, recent development in theory and experiments, North Holland, Amsterdam. Tome 2:588

    Google Scholar 

  19. Nakamoto (1986)

  20. Mhiri T (1991) Solid State Ionics 44:227

    Article  CAS  Google Scholar 

  21. Kamoun S, Gargouri M, Mhiri T, Daoud A etal (2003) J Phys Chem Solids 64:161

  22. Naili H, Vendier L, Jaud J, Mhiri T (2001) Solid State Sci 3:677

    Article  CAS  Google Scholar 

  23. Khemakhem H (1999) Ferroelectrics 1

  24. Dammak M, Khemekhem H, Mhiri T, Kolsi AW, etal. (1999) J Solid State Chem

  25. Cole KS, Cole RH (1941) J Chem Phys 43:341

    Article  Google Scholar 

  26. Bauerle JF (1969) J Chem Phys 30:2657

    CAS  Google Scholar 

  27. Masmoudi W, Kamoun S, Gargouri M (2012) Ionics 18:117–126

    Article  CAS  Google Scholar 

  28. Dammak M, Litaiem H, Mhiri T (2006) J Alloys Compd 416:228–235

    Article  CAS  Google Scholar 

  29. Litaiem H, Dammak M, Mhiri T, Cousson A (2005) J Alloys Compd 396:34–39

    Article  CAS  Google Scholar 

  30. Anantha PS, Hariharn K (2005) Mater Sci Eng B 121:12

    Article  Google Scholar 

  31. Kyritsis A, Pissi P, Grammatikakis I (1995) J Polym Sci B Polym Phys 33:1737

    Article  CAS  Google Scholar 

  32. Patel HK, Martin SW (1992) Phys Rev B45:10292

    Article  Google Scholar 

  33. Khemakhem H, Mhiri T, Daoud A (1999) Solid State Ionics 117:337

    Article  CAS  Google Scholar 

  34. Khemakhem H, Mnif M, Ravez J, Daoud A (1999) J Phys Soc Jpn 68:1031

    Article  CAS  Google Scholar 

  35. Allman R, Hasse W (1976) Inorg Chem 15:804

    Article  Google Scholar 

  36. Rao KS, Krishna PM, Prasad DM, Lee JH, Kim JS (2008) J Alloys Compd 464:497

    Article  CAS  Google Scholar 

  37. Kolodziej H, Sodczyk L (1971) Acta Phys Polon A 39:59

    CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the Spanish Ministry of Economy and Competitiveness project MAT2010-15094, ERDF, and the Minister of Higher Education and Research of Tunisia. All the authors would like to express their thanks to Dr. H. Khemakhem for his help in the spectroscopies Raman measurements and Dr. N. Zouari for his help in the dielectric measurements.

Author information

Authors and Affiliations

  1. Laboratoire de Chimie Inorganique, Faculté des Sciences de Sfax, Université de Sfax, B.P 1171, Sfax, 3000, Tunisia

    O. Mtioui, H. Litaiem, L. Ktari & M. Dammak

  2. Departamentos de Química Física y Analítica y Química Orgánica e Inorgánica, CINN, Universidad de Oviedo, 33006, Oviedo, Spain

    O. Mtioui & S. Garcia-Granda

Authors
  1. O. Mtioui
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Litaiem
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Garcia-Granda
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. Ktari
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Dammak
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Garcia-Granda.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mtioui, O., Litaiem, H., Garcia-Granda, S. et al. Thermal behavior and dielectric and vibrational studies of Cs2(HAsO4)0.32(SO4)0.68·Te(OH)6 . Ionics 21, 411–420 (2015). https://doi.org/10.1007/s11581-014-1196-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11581-014-1196-y

Keywords

Search

Navigation