Abstract
Topochemical polymerization of molecular crystals into porous materials is of significance due to their promising applications in the field of adsorption and catalysis, yet rarely reported due to the synthesis difficulty. Herein, a hydrogen-bonded organic framework (HOF-45) has been fabricated by the crystallization of a cage-like building block containing three alkynyl groups. It exhibits almost mesoporous structure demonstrated by single crystal X-ray diffraction study. Light-driven topochemical polymerization of HOF-45 with ethanedithiol covalently links alkynyl groups in HOF-45, generating a hydrogen-bond and covalent-bond cross-linked material (HOF-45C). In contrast to HOF-45, cross-linked HOF-45C retains the crystalline nature and displays improved solution resistence according to the powder X-ray diffraction data. In particular, HOF-45C is able to support the growth of ultrafine palladium nanoparticles with the average size of ca. 1.9 nm for rapidly promoting the degradation of nitrophenol, methyl orange, and congo red with the help of NaBH4 as well as Suzuki-Miyaura coupling reaction. This work inputs a new idea on the HOFs application in preparing covalent-linked porous organic materials.
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Acknowledgements
This work was supported by the Natural Science Foundation of China (22235001, 22175020, 22131005, 22011540002, 21631003), the Xiaomi Young Scholar Program, the Fundamental Research Funds for the Central Universities, and University of Science and Technology Beijing.
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Ding, X., Han, B., Yu, B. et al. Topochemical polymerization of hydrogen-bonded organic framework for supporting ultrafine palladium nanoparticles. Sci. China Chem. 66, 2019–2027 (2023). https://doi.org/10.1007/s11426-022-1555-9
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DOI: https://doi.org/10.1007/s11426-022-1555-9