Abstract
In this study, the fruit of Terminalia chebula, commonly known as chebulic myrobalan, is used as the precursor for carbon for its application in supercapacitors. The Terminalia chebula biomass-derived sponge-like porous carbon (TC-SPC) is synthesized using a facile and economical method of pyrolysis. TC-SPC thus obtained is subjected to XRD, FESEM, TEM, HRTEM, XPS, Raman spectroscopy, ATR-FTIR, and nitrogen adsorption–desorption analyses for their structural and chemical composition. The examination revealed that TC-SPC has a crystalline nature and a mesoporous and microporous structure accompanied by a disordered carbon framework that is doped with heteroatoms such as nitrogen and sulfur. Electrochemical studies are performed on TC-SPC using cyclic voltammetry, galvanostatic charge–discharge, and electrochemical impedance spectroscopy. TC-SPC contributed a maximum specific capacitance of 145 F g−1 obtained at 1 A g−1. The cyclic stability of TC-SPC is significant with 10,000 cycles, maintaining the capacitance retention value of 96%. The results demonstrated that by turning the fruit of Terminalia chebula into an opulent product, a supercapacitor, TC-SPC generated from biomass has proven to be a potential candidate for energy storage application.
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Funding
This work was supported by the Industrial-Linked Low Carbon Process Conversion Core Technology Development Program funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea) (Grant Number RS-2022–00155175). The project was also supported by the Researchers Supporting Project number (RSP2024R142), King Saud University, Riyadh, Saudi Arabia.
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Somasundaram Chandra Kishore: conceptualization, methodology, formal analysis, and writing—original draft. Suguna Perumal: visualization and writing—review and editing. Raji Atchudan: conceptualization, investigation, methodology, formal analysis, and writing-—original draft. Thomas Nesakumar Jebakumar Immanuel Edison: investigation, software, and formal analysis. Ashok Kumar Sundramoorthy: investigation and visualization. Devaraj Manoj: investigation and formal analysis. Muthulakshmi Alagan: Software and validation. Raju Suresh Kumar: formal analysis and visualization. Abdulrahman Ibrahim Almansour: validation and funding acquisition. Sangaraju Sambasivam: validation and visualization. Yong Rok Lee: project administration and supervision.
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Kishore, S.C., Perumal, S., Atchudan, R. et al. Sustainable synthesis of spongy-like porous carbon for supercapacitive energy storage systems towards pollution control. Environ Sci Pollut Res (2024). https://doi.org/10.1007/s11356-024-33437-0
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DOI: https://doi.org/10.1007/s11356-024-33437-0