Abstract
A simple, low-cost, and environmentally benign process for synthesizing nanostructured NiO/NiAl2O4 on multiple kinds of carbon nanostructures (CNS) is presented. This method develops polylactic acid (PLA) based waste plastic materials for the producing CNS. These composites (NiO@NiAl2O4/CNS) were examined as potential electrodes in supercapacitors (SC) as they exhibit good charge/discharge reversibility and provide adequate specific capacitance values with a maximum being 1984 F/g at 0.5 A g-1. It is noteworthy that the cycling stability of this sample at 10 A g-1 maintained 101.7% of its initial capacity even after 5000 GCD cycles. An asymmetric supercapacitor (ASC) was built and analyzed, with NiO@NiAl2O4/CNS serving as the cathode and activated carbon serving as the anode of the device. The concluded device has an energy density of 58 Wh kg-1 with a power density of 986 W kg-1 and a SCs of 216.5 F/g. The results showed that the materials mentioned are a great option to use as electrode materials in applications involving the storage of energy.
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References
Ansari MZ, Ansari SA, Kim SH (2022) Fundamentals and recent progress of Sn-based electrode materials for supercapacitors: a comprehensive review. J Energy Storage 53(September):105187. https://doi.org/10.1016/J.EST.2022.105187
Arora R, Nehra SP, Lata S (2023) In-situ composited g-C3N4/polypyrrole nanomaterial applied as energy-storing electrode with ameliorated super-capacitive performance. Environ Sci Pollut Res 30(44):98589–98600. https://doi.org/10.1007/s11356-022-21777-8
Beemarao M, Kanagambal P, Ravichandran K, Rajeswaran P, Ashraf IM, Chalapathi U, Park SH (2023) Hybrids of porous NiMoO4@reduced graphene oxide composites for asymmetric supercapacitor applications. Inorg Chem Commun 153(July):110853. https://doi.org/10.1016/J.INOCHE.2023.110853
Bhat VS, Kanagavalli P, Sriram G, Ramya Prabhu B, John NS, Veerapandian M, Kurkuri M, Hegde G (2020) Low cost, catalyst free, high performance supercapacitors based on porous nano carbon derived from agriculture waste. J Energy Storage 32(December):101829. https://doi.org/10.1016/J.EST.2020.101829
Bokobza L, Bruneel JL, Couzi M (2013) Raman spectroscopic investigation of carbon-based materials and their composites. comparison between carbon nanotubes and carbon black. Chem Phys Lett 590(December):153–159. https://doi.org/10.1016/J.CPLETT.2013.10.071
Chandra Sekhar S, Nagaraju G, Ramulu B, Yu JS (2019) Rapid design of a core-shell-like metal hydroxide/oxide composite and activated carbon from biomass for high-performance supercapattery applications. Inorganic Chem Front 6(7):1707–1720. https://doi.org/10.1039/c9qi00308h
Chen C, Deng H, Wang C, Luo W, Huang D, Jin T (2021) Petal-like CoMoO4 clusters grown on carbon cloth as a binder-free electrode for supercapacitor application. ACS Omega 6(30):19616–19622. https://doi.org/10.1021/acsomega.1c02166
Dincer I (2000) Renewable energy and sustainable development: a crucial review. Renew Sustain Energy Rev 4(2):157–175. https://doi.org/10.1016/S1364-0321(99)00011-8
Gajraj V, Azmi R, Indris S, Mariappan CR (2021) Boosting the Multifunctional properties of MnCo2O4-MnCo2S4 heterostructure for portable all-solid-state symmetric supercapacitor, methanol oxidation and hydrogen evolution reaction. ChemistrySelect 6(41). https://doi.org/10.1002/slct.202103138
Gao H, Joshi B, Samuel E, Khadka A, Kim SW, Aldalbahi A, Yoon SS (2024) Freestanding electrodes based on nitrogen-doped carbon nanofibers and zeolitic imidazolate framework-derived ZnO for flexible supercapacitors. Appl Surf Sci 651:159221. https://doi.org/10.1016/j.apsusc.2023.159221
Hao C, Guo Y, Xian S, Zheng W, Gao H, Wang X (2021) Fabrication of flower-shaped CuCo2O4@MgMoO4 nanocomposite for high-performance supercapacitors. J Energy Storage 41(September):102972. https://doi.org/10.1016/J.EST.2021.102972
He M, Chernov AI, Obraztsova ED, Sainio J, Rikkinen E, Jiang H, Zhu Z et al (2011) Low temperature growth of SWNTs on a nickel catalyst by thermal chemical vapor deposition. Nano Res 4(4). https://doi.org/10.1007/s12274-010-0088-3
Hekmat F, Hosseini H, Shahrokhian S, Unalan HE (2020) Hybrid energy storage device from binder-free zinc-cobalt sulfide decorated biomass-derived carbon microspheres and pyrolyzed polyaniline nanotube-iron oxide. Energy Storage Mater 25(March):621–635. https://doi.org/10.1016/J.ENSM.2019.09.022
Hu RY, Liu LY, He JH, Zhou Y, Wu SB, Zheng MX, Ma PP (2023) Preparation and electrochemical properties of bimetallic carbide Fe3Mo3C/Mo2C@carbon nanotubes as negative electrode material for supercapacitor. J Energy Storage 72:108656
Irshad A, Somaily HH, Zulfiqar S, Warsi MF, Din MI, Chaudhary K, Shahid M (2023) Silver doped NiAl2O4 nanoplates anchored onto the 2D graphitic carbon nitride sheets for high-performance supercapacitor applications. J Alloys Compd 934(February):167705. https://doi.org/10.1016/J.JALLCOM.2022.167705
Jokar E, Shahrokhian S, Iraji A, zad, Elham Asadian, and Hadi Hosseini. (2018) An efficient two-step approach for improvement of graphene aerogel characteristics in preparation of supercapacitor electrodes. J Energy Storage 17(February):465–473. https://doi.org/10.1016/j.est.2018.04.014
Jiao Z, Chen Y, Du M, Demir M, Yan F, Zhang Y, Zou J (2023) In-situ formation of morphology-controlled cobalt vanadate on CoO urchin-like microspheres as asymmetric supercapacitor electrode. J Alloys Compd 958:170489
Kunde GB, Sehgal B, Ganguli AK (2021) Modified EISA synthesis of NiAl2O4/MWCNT composite mesoporous free-standing film as a potential electrochemical capacitor material. J Alloys Compd 856(March):158019. https://doi.org/10.1016/J.JALLCOM.2020.158019
Li P, Ruan C, Jing X, Xie Y (2020) Supercapacitive performance of CoMoO4 with oxygen vacancy porous nanosheet. Electrochim Acta 330(January):135334. https://doi.org/10.1016/J.ELECTACTA.2019.135334
Liu R, Zhou A, Zhang X, Jingbo M, Che H, Wang Y, Wang TT, Zhang Z, Kou Z (2021) Fundamentals, advances and challenges of transition metal compounds-based supercapacitors. Chem Eng J 412(May):128611. https://doi.org/10.1016/J.CEJ.2021.128611
Liu L, Liu G, Wu S, He J, Zhou Y, Demir M, Ma P (2024) Fe-substituted SrCoO3 perovskites as electrode materials for wide temperature-tolerant supercapacitors. Ceram Int 50(1):1970–1980. https://doi.org/10.1002/aenm.202103820
Ma B, Hao W, Ruan W, Yuan C, Wang Q, Teng F (2022a) Unveiling capacitive behaviors of MoO2 in different electrolytes and flexible MoO2-based asymmetric micro-supercapacitor. J Energy Storage 52:104833. https://doi.org/10.1016/j.est.2022.104833
Ma Y, Zhang L, Yan Z, Cheng B, Yu J, Liu T (2022b) Sandwich-shell structured CoMn2O4/C hollow nanospheres for performance-enhanced sodium-ion hybrid supercapacitor. Adv Energy Mater 12(11):2103820
Mohamed AM, Allam NK (2022) Transition metal selenide (TMSe) electrodes for electrochemical capacitor devices: a critical review. J Energy Storage 47(March):103565. https://doi.org/10.1016/J.EST.2021.103565
Olabi AG, Abbas Q, Al Makky A, Abdelkareem MA (2022) Supercapacitors as next generation energy storage devices: properties and applications. Energy 248(June):123617. https://doi.org/10.1016/J.ENERGY.2022.123617
Østergaard PA, Duic N, Noorollahi Y, Mikulcic H, Kalogirou S (2020) Sustainable development using renewable energy technology. Renew Energy 146:2430–2437. https://doi.org/10.1016/j.renene.2019.08.094
Packiaraj R, Kamaraj Mahendraprabhu P, Devendran NN, Baskaran Palanivel KS, Venkatesh, and Ramesh Karuppannan. (2022) Electrochemical performances of ZnO-NiO-CuO mixed metal oxides as smart electrode material for solid-state asymmetric device fabrication. Energy Fuel 36(1):603–617. https://doi.org/10.1021/acs.energyfuels.1c02703
Pal B, Yang S, Ramesh S, Thangadurai V, Jose R (2019) Electrolyte selection for supercapacitive devices: a critical review. Nanoscale Adv 1(10):3807–3835. https://doi.org/10.1039/c9na00374f
Pamphile-Adrian AJ, Passos FB, Florez-Rodriguez PP (2022) Systematic Study on the properties of nickel aluminate (NiAl2O4) as a catalytic precursor for aqueous phase hydrogenolysis of glycerol. Catal Today 394–396. https://doi.org/10.1016/j.cattod.2021.07.002
Qiao Y, He J, Zhou Y, Wu S, Li X, Jiang G, Ma P (2023) Flexible all-solid-state asymmetric supercapacitors based on PPy-decorated SrFeO3−δ perovskites on carbon cloth. ACS Appl Mater Interfaces 15(45):52381–52391
Regulska E, Breczko J, Basa A, Szydlowska B, Kakareko K, Rydzewska-Rosołowska A, Hryszko T (2022) Graphene-quantum-dots-decorated NiAl2O4 nanostructure as supercapacitor and electrocatalyst in biosensing. Mater Today Commun 33(December):104166. https://doi.org/10.1016/J.MTCOMM.2022.104166
Ren B, Zhang X, An H, Ding S, Hong Zhang X, Zeng, Xiao’e Wang, Meiqing Fan, and Xiaodong Yang. (2023) Hollow cotton carbon based NiCo2S4/NiMoO4 hybrid arrays for high performance supercapacitor. J Energy Storage 59(March):106553. https://doi.org/10.1016/J.EST.2022.106553
Sahoo BB, Pandey VS, Dogonchi AS, Mohapatra PK, Thatoi DN, Nayak N, Nayak MK (2023) A state-of-art review on 2D material-boosted metal oxide nanoparticle electrodes: supercapacitor applications. J Energy Storage 65(August):107335. https://doi.org/10.1016/J.EST.2023.107335
Salunkhe AD, Pawar PS, Pagare PK, Kadam AN, Katkar PK, Torane AP (2023) MOF derived NiCo2O4 nanosheets for high performance asymmetric supercapacitor. J Electroanal Chem 939(June):117475. https://doi.org/10.1016/J.JELECHEM.2023.117475
Sharma S, Chand P (2023) Supercapacitor and electrochemical techniques: a brief review. Results Chem 5(November 2022):100885. https://doi.org/10.1016/j.rechem.2023.100885
Sui ZY, Meng YN, Xiao PW, Zhao ZQ, Wei ZX, Han BH (2015) Nitrogen-doped graphene aerogels as efficient supercapacitor electrodes and gas adsorbents. ACS Appl Mater Interfaces 7(3):1431–1438. https://doi.org/10.1021/am5042065
Vinu M, Prabu S, Chiang KY, Dharman RK, Oh TH (2024) Controllable morphology transformation of hierarchical-porous CoMoSi/C metal hydroxide nanosheets from sugarcane bagasse as green sources for high performance supercapacitors and oxygen evolution reaction. J Energy Storage 79:110151. https://doi.org/10.1016/j.est.2023.110151
Wu Y, Gui W, Liu X, Zhang L, Wang S, Wang Z, Zhang C (2020) Promotional effect of cu for catalytic amination of diethylene glycol with tertiarybutylamine over Ni–Cu/Al2O3 catalysts. Catal Lett 150(8). https://doi.org/10.1007/s10562-020-03145-8
Wu Z, Zhu Y, Ji X (2014) NiCo2O4-based materials for electrochemical supercapacitors. J Mater Chem A 2(36):14759–14772. https://doi.org/10.1039/c4ta02390k
Yao D, Li H, Mohan BC, Prabhakar AK, Dai Y, Wang CH (2022) Conversion of waste plastic packings to carbon nanomaterials: investigation into catalyst material, waste type, and product applications. ACS Sustain Chem Eng 10:(3). https://doi.org/10.1021/acssuschemeng.1c05945
Wu X, Fan H, Wang W, Lei L, Ma L (2022) A novel metal-free ternary core–shell carbon sphere/C3N4/PPy nanocomposite for high-performance supercapacitors. New J Chem 46(32):15292–15295. https://doi.org/10.1039/D2NJ03379H
Yao D, Zhang Y, Williams PT, Yang H, Chen H (2018) Co-production of hydrogen and carbon nanotubes from real-world waste plastics: influence of catalyst composition and operational parameters. Appl Catal B Environ 221(February):584–597. https://doi.org/10.1016/J.APCATB.2017.09.035
Yuan D, Chen J, Zeng J, Tan S (2008) Preparation of monodisperse carbon nanospheres for electrochemical capacitors. Electrochem Commun 10(7):1067–1070. https://doi.org/10.1016/j.elecom.2008.05.015
Xu RH, Ma PP, Liu GF, Qiao Y, Hu RY, Liu LY, Jiang GH (2023) Dual-phase coexistence design and advanced electrochemical performance of Cu2MoS4 electrode materials for Supercapacitor Application. Energy Fuel 37(8):6158–6167
Zhai Z, Zhang L, Tianmin D, Ren B, Yuelong X, Wang S, Miao J, Liu Z (2022) A review of carbon materials for supercapacitors. Mater Des 221:111017. https://doi.org/10.1016/j.matdes.2022.111017
Zhang S, Ying M, Jun Y, Zhan W, Wang L, Guo Y, Guo Y (2021) NixAl1O2-δ mesoporous catalysts for dry reforming of methane: the special role of NiAl2O4 spinel phase and its reaction mechanism. Appl Catal B Environ 291(August):120074. https://doi.org/10.1016/J.APCATB.2021.120074
Zhang M, Xu Y, Fan H, Zhao N, Yan B, Wang C, Wang W (2020) In situ synthesis of 3D Co@Co3O4 nanosheet arrays for hybrid supercapacitors with ultra-high rate performance. J Alloys Compd 826:154115. https://doi.org/10.1016/j.jallcom.2020.154115
Zhao J, Lai C, Dai Y, Xie J (2007) Pore structure control of mesoporous carbon as supercapacitor material. Mater Lett 61(23–24):4639–4642. https://doi.org/10.1016/j.matlet.2007.02.071
Zhao N, Fan H, Zhang M, Ma J, Wang C, Yadav AK, Cao X (2020b) Beyond intercalation-based supercapacitors: The electrochemical oxidation from Mn3O4 to Li4Mn5O12 in Li2SO4 electrolyte. Nano Energy 71:104626. https://doi.org/10.1016/j.nanoen.2020.104626
Zhao N, Fan H, Zhang M, Ma J, Du Z, Yan B, Jiang X (2020a) Simple electrodeposition of MoO3 film on carbon cloth for high-performance aqueous symmetric supercapacitors. Chem Eng J 390:124477. https://doi.org/10.1016/j.cej.2020.124477
Zhao N, Feng Y, Zhao H, Fan H, Tian S, Hu B (2022) Simple electrodeposition of 3D NiCoFe-layered double hydroxide nanosheet assembled nanospheres/nanoflowers on carbon cloth for high performance hybrid supercapacitors. J Alloys Compd 901:163566. https://doi.org/10.1016/j.jallcom.2021.163566
Acknowledgements
The authors would like to thank the Ministry of Science and Technology (MOST) Taiwan for financially supporting this work (Grant number: MOST-110-2211-E-008-042-MY3). The authors also appreciate the Precious Instruments Utilization Center of National Central University in providing analysis facilities. We thank Science and Engineering Research Board, New Delhi, India for the research grant and Department of Chemistry, School of Physical Sciences, Mizoram University, Aizawl, Mizoram, India and Department of Physics, Karpagam Academy of Higher Education, Coimbatore, India for providing facilities.
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This research work was supported by the Ministry of Science and Technology (MOST) Taiwan (Grant number: MOST-110-2211-E-008-042-MY3).
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Samikannu Prabu: Formal analysis, Writing-original draft, Methodology. Madhan Vinu: Formal analysis, Writing-original draft. Kung-Yuh Chiang: Supervision, Validation. George Rajendra Kumar and Ranjithkumar R: Writing-review & editing.
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Samikannu, P., Madhan, V., Chiang, KY. et al. Polylactic acid-based plastic activated NiAl2O4 nanoparticles as highly active positive electrode materials for energy storage supercapacitor. Environ Sci Pollut Res 31, 26606–26617 (2024). https://doi.org/10.1007/s11356-024-32721-3
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DOI: https://doi.org/10.1007/s11356-024-32721-3