Skip to main content

Advertisement

Log in

Cost-effective synthesis of NiCo2O4@nitrogen-doped carbon nanocomposite using waste PET plastics for high-performance supercapacitor

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

A cost-effective bimetallic NiCo2O4@nitrogen-doped carbon (NC) nanocomposite was prepared through bimetallic nickel/cobalt metal organic frameworks (Ni/Co-MOF) by employing a smart approach to utilize the waste Polyethylene terephthalate (PET) plastics for energy storage applications. The NiCo2O4@NC nanocomposite was characterized successfully using analytical techniques. The nanocomposite comprises high surface area (813 m2 g− 1) and mesoporosity (~ 15 nm). NiCo2O4@NC nanocomposite demonstrates excellent electrochemical performance with high specific capacitance of ~ 890 F g− 1 at 5 mV s− 1 and ~ 913 F g− 1 at 1 A g− 1 in 6 m KOH electrolyte. The cyclic stability tests confirm excellent retention capacity (~ 99%) with fifty cyclic segments. Low-cost, environmental friendly approach, and rich redox activity of NiCo2O4@NC nanocomposite make it an alternate potential electrode material for energy storage devices.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. H. Wang, Q.-L. Zhu, R. Zou, Q. Xu, Chemistry 2, 52 (2017)

    CAS  Google Scholar 

  2. S. Sankar, S. Saravanan, A.T.A. Ahmed, A.I. Inamdar, H. Im, S. Lee, D.Y. Kim, Mater. Lett. 240, 189 (2019)

    CAS  Google Scholar 

  3. X. Wang, Y. Yang, F. Zhang, J. Tang, Z. Guo, Mater. Lett. 261, 127141 (2020)

    CAS  Google Scholar 

  4. M.M. Sk, C.Y. Yue, K. Ghosh, R.K. Jena, J. Power Sources 308, 121 (2016)

    CAS  Google Scholar 

  5. N.A. El Essawy, S.M. Ali, H.A. Farag, A.H. Konsowa, M. Elnouby, H.A. Hamad, Ecotoxical. Environ. Saf. 145, 57 (2017)

    Google Scholar 

  6. C.-C. Hou, Q. Xu, Adv. Energy Mater. 9, 1801307 (2019)

    Google Scholar 

  7. C. Wang, D. Liu, W. Lin, J. Am. Chem. Soc. 135, 13222 (2013)

    CAS  Google Scholar 

  8. S. Anwar, K.S. Muthu, V. Ganesh, N. Lakshminarasimhan, J. Electrochem. Soc. 158, 976 (2011)

    Google Scholar 

  9. D.H. Deng, H. Pang, J.M. Du, J.W. Deng, S.J. Li, J. Chen, J.S. Zhang, Cryst. Res. Technol. 47, 1032 (2012)

    CAS  Google Scholar 

  10. V.S. Kumbhar, A.D. Jagadale, N.M. Shinde, C.D. Lokhande, Appl. Surf. Sci. 259, 39 (2012)

    CAS  Google Scholar 

  11. B. Bhujun, M.T.T. Tan, A.S. Shanmugam, Results Phys. 7, 345 (2017)

    Google Scholar 

  12. B. Qiu, Y. Deng, M. Du, M. Xing, J. Zhang, Sci. Rep. 6, 29099 (2016)

    CAS  Google Scholar 

  13. P. Xiong, H. Huang, X. Wang, J. Power Sources 245, 937 (2014)

    CAS  Google Scholar 

  14. M. Eskandari, C.A. García, D. Buceta, R. Malekfar, P. Taboada, J. Electroanal. Chem. 851, 113481 (2019)

    CAS  Google Scholar 

  15. S.M. Alshehri, A.N. Alhabarah, J. Ahmed, M. Naushad, T. Ahamad, J. Colloids Interface Sci. 514, 1 (2018)

    CAS  Google Scholar 

  16. S.M. Alshehri, J. Ahmed, A.N. Alhabarah, T. Ahamad, T. Ahmad, ChemElectroChem 4, 2952 (2017)

    CAS  Google Scholar 

  17. C. Young, R.R. Salunkhe, S.M. Alshehri, T. Ahamad, Z. Huang, J. Henzie, Y. Yamauchi, J. Mater. Chem. A 5, 11834 (2017)

    CAS  Google Scholar 

  18. Z. Cao, C. Liu, Y. Huang, Y. Gao, Y. Wang, Z. Li, Y. Yan, M. Zhang, J. Power Sources 449, 227571 (2020)

    CAS  Google Scholar 

  19. P. Siwatch, K. Sharma, S.K. Tripathi, Electrochim. Acta 329, 135084 (2020)

    CAS  Google Scholar 

  20. M. Chatterjee, S. Saha, S. Das, S.K. Pradhan, J. Alloys Compd. 821, 153503 (2020)

    CAS  Google Scholar 

  21. D. Chen, D. Pang, S. Zhang, H. Song, W. Zhu, J. Zhu, Electrochim. Acta 330, 135326 (2020)

    CAS  Google Scholar 

  22. A. Singh, S.K. Ojha, A.K. Ojha, Synthetic Met. 259, 116215 (2020)

    CAS  Google Scholar 

  23. J. Wang, Z. Wu, L. Han, R. Lin, H.L. Xin, D. Wang, ChemCatChem 8, 736 (2016)

    CAS  Google Scholar 

  24. Y. Ha, L. Shi, X. Yan, Z. Chen, Y. Li, W. Xu, R. Wu, ACS Appl. Mater. Interfaces 11, 45546 (2019)

    CAS  Google Scholar 

  25. W. Chu, Z. Shi, Y. Hou, D. Ma, X. Bai, Y. Gao, N. Yang, ACS Appl. Mater. Interfaces 12, 2763 (2020)

    CAS  Google Scholar 

  26. J.H. Lin, Y.T. Yan, T.X. Xu, C.Q. Qu, J. Li, J. Cao, J.C. Feng, J.L. Qi, J. Colloids Interface Sci. 560, 34 (2020)

    CAS  Google Scholar 

  27. D. Wu, H. Huang, Y. Zhou, Y. Liu, Z. Kang, J. Electroanal. Chem. 855, 113617 (2019)

    CAS  Google Scholar 

  28. G. Marimuthu, G. Palanisamy, T. Pazhanivel, G. Bharathi, M.M. Cristopher, K. Jeyadheepan, J. Mater. Sci. 31, 1951 (2020)

    CAS  Google Scholar 

  29. X. Xiao, X. Zhang, Z. Zhang, J. You, S. Liu, Y. Wang, Microchim. Acta 187, 64 (2019)

    Google Scholar 

  30. Z. Liu, W. Xi, H. Li, Environ. Sci. Wat. Res. 6, 283 (2020)

    CAS  Google Scholar 

  31. N. Narayanan, N. Bernaurdshaw, ChemCatChem 12, 771 (2020)

    CAS  Google Scholar 

  32. B. Han, J. Song, S. Liang, W. Chen, H. Deng, X. Ou, Y.-J. Xu, Z. Lin, Appl. Catal. B 260, 118208 (2020)

    CAS  Google Scholar 

  33. A. Bashir, S. Shukla, R. Bashir, R. Patidar, A. Bruno, D. Gupta, M.S. Satti, Z. Akhter, Sol. Energy 196, 367 (2020)

    CAS  Google Scholar 

  34. C. Chen, M.-K. Wu, K. Tao, J.-J. Zhou, Y.-L. Li, X. Han, L. Han, Dalton Trans. 47, 5639 (2018)

    CAS  Google Scholar 

  35. A.M. Al-Enizi, M. Ubaidullah, J. Ahmed, T. Ahamad, T. Ahmad, S.F. Shaikh, M. Naushad, Compos. Part B 183, 107655 (2020)

    CAS  Google Scholar 

  36. A.M. Al-Enizi, J. Ahmed, M. Ubaidullah, S.F. Shaikh, T. Ahamad, M. Naushad, G. Zheng, J. Clean. Prod. 248, 119251 (2020)

    CAS  Google Scholar 

  37. T. Yumak, D. Bragg, E.M. Sabolsky, Appl. Surf. Sci. 469, 983 (2019)

    CAS  Google Scholar 

  38. M. Naushad, T. Ahamad, B.M. Al-Maswari, A. Abdullah Alqadami, S.M. Alshehri, Chem. Eng. J. 330, 1351 (2017)

    CAS  Google Scholar 

  39. S. Wang, B.Y. Guan, X.W. Lou, Energ. Environ. Sci. 11, 306 (2018)

    CAS  Google Scholar 

  40. D. Yang, Q. Zhao, L. Huang, B. Xu, N.A. Kumar, X.S. Zhao, J. Mater. Chem. A 6, 14146 (2018)

    CAS  Google Scholar 

  41. C. Young, J. Kim, Y.V. Kaneti, Y. Yamauchi, ACS Appl. Energy Mater. 1, 2007 (2018)

    CAS  Google Scholar 

  42. W. Li, Y. Bu, H. Jin, J. Wang, W. Zhang, S. Wang, J. Wang, Energ. Fuel. 27, 6304 (2013)

    CAS  Google Scholar 

  43. C. Ji, F. Liu, L. Xu, S. Yang, J. Mater. Chem. A 5, 5568 (2017)

    CAS  Google Scholar 

  44. D. Zhao, F. Hu, A. Umar, X. Wu, New J. Chem. 42, 7399 (2018)

    CAS  Google Scholar 

  45. Y. Zhang, Y. Zhang, D. Zhang, L. Sun, Dalton Trans. 46, 9457 (2017)

    CAS  Google Scholar 

Download references

Acknowledgements

The authors extend their sincere appreciation to the Deanship of Scientific Research at King Saud University for funding this Research Group (RG-1435-007).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Jahangeer Ahmed or Saad M. Alshehri.

Ethics declarations

Conflict of interest

We state that the authors have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Alhokbany, N., Ahmed, J., Ubaidullah, M. et al. Cost-effective synthesis of NiCo2O4@nitrogen-doped carbon nanocomposite using waste PET plastics for high-performance supercapacitor. J Mater Sci: Mater Electron 31, 16701–16707 (2020). https://doi.org/10.1007/s10854-020-04224-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-020-04224-7

Navigation