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Plastic pyrolytic oils as renewable fuel: improving its physical properties and ignition patterns by waste renewable source—an experimental analysis

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Abstract

The increase in plastic products and disposal poses a severe environmental challenge because of their poor biodegradability and undesirable disposal by landfilling. Recycling is the best possible solution to the environmental challenges implemented by the plastic industry. Pyrolysis is a process that converts waste plastics into pyrolytic oil, and it can be used as fuel in a blended form. The viscosity and lubricity of the LDWP (low-density waste polyethylene) pyrolytic oil were lower than standard diesel. Capparis spinosa methyl ester (CME) is blended and experimented with to overcome the lubricity issue of pyrolytic oil. In this investigation, 5%, 10%, and 15% CME were blended with PD20 (20% LDWP oil + 80% diesel) blend on a volume basis. Experiments were conducted to examine the effects of CME on combustion, performance, and emissions using the combination of CME and PD20 blend tested at 0%, 25%, 50%, 75%, and 100% loading conditions. All three ternary mixtures showed enhanced combustion performance and increased NOx and smoke emissions. Due to better combustion, the efficiency of the blend PCD10 (10% CME + 20% LDWP oil + 70% diesel) was higher than the PD20 blend and significantly closer to diesel. Hence, PCD10 is suggested as an alternative to diesel fuel.

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Data Availability

All data generated or analysed during this study are included in this published article.

Abbreviations

ASTM:

American Society for Testing Materials

BTE:

Brake thermal efficiency

CA:

Crank angle

CME:

Capparis spinosa Methyl ester

CO:

Carbon monoxide

COV:

Coefficient of Variation

DI:

Direct injection

FT-IR:

Fourier Transform Infrared Spectroscopy

HC:

Hydrocarbon

HPPO:

Hydrogenated polypropylene pyrolysis oil

HRR:

Heat release rate

LDPE:

Low-density polyethylene

LDWP:

Low-density waste polyethylene oil (pyrolytic oil)

MSW:

Municipal Solid Waste

NOx :

Oxides of nitrogen

PCD10:

10% CME + 20% LDWP + 70% diesel

PCD15:

15% CME + 20% LDWP + 65% diesel

PCD5:

5% CME + 20% LDWP + 75% diesel

PD20:

20% LDWP + 80% diesel

PPO:

Plastic pyrolysis oil

SA:

Silica alumina

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Authors

Contributions

All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Gopinath Soundararajan, Bibin Chidambaranathan, Ashok Kumar Rajendran, and Dillibabu Venugopal. The first draft of the manuscript was written by Yuvarajan Devarajan and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

Corresponding author

Correspondence to Yuvarajan Devarajan.

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The authors declare no competing interests.

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Soundararajan, G., Chidambaranathan, B., Rajendran, A.K. et al. Plastic pyrolytic oils as renewable fuel: improving its physical properties and ignition patterns by waste renewable source—an experimental analysis. Environ Sci Pollut Res 31, 26497–26509 (2024). https://doi.org/10.1007/s11356-024-32668-5

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  • DOI: https://doi.org/10.1007/s11356-024-32668-5

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