Abstract
With the implementation of garbage classification, perishable waste has become increasingly concentrated. This has led to a significant change in the VOC release characteristics at residential garbage collection points, posing a potential risk with unknown characteristics. This study investigated the release characteristics, odor pollution, and health risks of VOCs at garbage collection points under different classification effectiveness, seasons, garbage drop-off periods, and garbage collection point types. The results showed that the average concentration of VOCs released from the garbage sorting collection points (SPs) was 341.43 ± 261.16 μg/m3, and oxygenated compounds (e.g., ethyl acetate and acetone) were the main VOC components. The VOC concentration increased as the community classification effectiveness improved, and it was higher in summer (followed by spring, autumn, and winter). Moreover, the VOC concentrations were higher in the evenings than in the mornings and at centralized garbage collection points (CPs) than at SPs. Further, odor activity value (OAV) assessments indicated that acrolein, styrene, and ethyl acetate were the critical odorous components, with an average OAV of 0.87 ± 0.85, implying marginal odor pollution in some communities. Health risk assessments further revealed that trichloroethylene, benzene, and chlorotoluene were the critical health risk substances, with an average carcinogenic risk (CR) value of 10−6–10−4, and a non-carcinogenic risk (HI) value < 1. These results indicated that HIs were acceptable, but potential CRs existed in the communities. Therefore, VOC pollution prevention and control measures should be urgently strengthened at the garbage collection points in high pollution risk scenarios.
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Data availability
The datasets used and analyzed during the current study are available from the corresponding author on reasonable request.
Abbreviations
- VOC:
-
Volatile organic compound
- GC-MS:
-
Gas chromatography coupled with mass spectrometry
- SP:
-
Garbage sorting collection point
- CP:
-
Centralized garbage collection point
- OAV :
-
Odor activity value
- CR :
-
Carcinogenic risk
- H I :
-
Non-carcinogenic risk
References
Agapios A, Andreas V, Marinos S, Katerina M, Antonis ZA (2020) Waste aroma profile in the framework of food waste management through household composting. J Clean Prod 257:120340. https://doi.org/10.1016/j.jclepro.2020.120340
Agapiou A, Vamvakari JP, Andrianopoulos A, Pappa A (2016) Volatile emissions during storing of green food waste under different aeration conditions. Environ Sci Pollut Res 23(9):8890–8901. https://doi.org/10.1007/s11356-016-6131-5
Allen MR, Braithwaite A, Hills CC (1997) Trace organic compounds in landfill gas at seven U.K. waste disposal sites. Environ Sci Technol 31(4):1054–1061. https://doi.org/10.1021/es9605634
Bai R, Lin B (2022) Are residents willing to pay for garbage recycling: evidence from a survey in Chinese first-tier cities. Environ Impact Assess Rev 95:106789. https://doi.org/10.1016/j.eiar.2022.106789
Capelli L, Sironi S, Del Rosso R, Céntola P, Il Grande M (2008) A comparative and critical evaluation of odour assessment methods on a landfill site. Atmos Environ 42(30):7050–7058. https://doi.org/10.1016/j.atmosenv.2008.06.009
Chai F, Li P, Li L, Qiu Z, Han Y, Yang K (2022) Dispersion, olfactory effect, and health risks of VOCs and odors in a rural domestic waste transfer station. Environ Res 209:112879. https://doi.org/10.1016/j.envres.2022.112879
Chang H, Tan H, Zhao Y, Wang Y, Wang X, Li Y, Lu W, Wang H (2019) Statistical correlations on the emissions of volatile odorous compounds from the transfer stage of municipal solid waste. Waste Manag 87:701–708. https://doi.org/10.1016/j.wasman.2019.03.014
Chen X, Geng Y, Fujita T (2010) An overview of municipal solid waste management in China. Waste Manag 30(4):716–724. https://doi.org/10.1016/j.wasman.2009.10.011
Chen S, Huang J, Xiao T, Gao J, Bai J, Luo W, Dong B (2020) Carbon emissions under different domestic waste treatment modes induced by garbage classification: case study in pilot communities in Shanghai, China. Sci Total Environ 717:137193. https://doi.org/10.1016/j.scitotenv.2020.137193
China MEP (2014) Standard Method HJ 732–2014, Emission from stationary sources—sampling of volatile organic compounds—bags method. Ministry of Environmental Protection of the People’s Republic of China. https://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/jcffbz/201501/W020150115565034743613.pdf. Accessed 12/31/2014
China MEP (2015) Standard Method HJ 759–2015, Ambient air determination of volatile organic compounds—collected by specially-prepared canisters and analyzed by gas chromatography/mass spectrometry. Ministry of Environmental Protection of the People’s Republic of China. https://www.mee.gov.cn/ywgz/fgbz/bz/bzwb/jcffbz/201510/W020151030573530793420.pdf. Accessed 10/22/2015
Dehghani M, Fazlzadeh M, Sorooshian A, Tabatabaee HR, Miri M, Baghani AN, Delikhoon M, Mahvi AH, Rashidi M (2018) Characteristics and health effects of BTEX in a hot spot for urban pollution. Ecotoxicol Environ Saf 155:133–143. https://doi.org/10.1016/j.ecoenv.2018.02.065
Diaz R, Otoma S (2014) Cost–benefit analysis of waste reduction in developing countries: a simulation. J Mater Cycles Waste Manag 16(1):108–114. https://doi.org/10.1007/s10163-013-0148-3
Duan Z, Lu W, Li D, Wang H (2014) Temporal variation of trace compound emission on the working surface of a landfill in Beijing, China. Atmos Environ 88:230–238. https://doi.org/10.1016/j.atmosenv.2014.01.051
Guo Y, Zhu Z, Zhao Y, Zhou T, Lan B, Song L (2021) Simultaneous annihilation of microorganisms and volatile organic compounds from municipal solid waste storage rooms with slightly acidic electrolyzed water. J Environ Manag 297:113414. https://doi.org/10.1016/j.jenvman.2021.113414
Gutiérrez MC, Siles JA, Diz J, Chica AF, Martín MA (2017) Modelling of composting process of different organic waste at pilot scale: biodegradability and odor emissions. Waste Manag 59:48–58. https://doi.org/10.1016/j.wasman.2016.09.045
Hawko C, Verriele M, Hucher N, Crunaire S, Leger C, Locoge N, Savary G (2021) A review of environmental odor quantification and qualification methods: the question of objectivity in sensory analysis. Sci Total Environ 795:148862. https://doi.org/10.1016/j.scitotenv.2021.148862
He M, Sun Y, Zou D, Yuan H, Zhu B, Li X, Pang Y (2012) Influence of temperature on hydrolysis acidification of food waste. Procedia Environ Sci 16:85–94. https://doi.org/10.1016/j.proenv.2012.10.012
Hu R, Liu G, Zhang H, Xue H, Wang X (2018) Levels, characteristics and health risk assessment of VOCs in different functional zones of Hefei. Ecotoxicol Environ Saf 160:301–307. https://doi.org/10.1016/j.ecoenv.2018.05.056
Kaza S, Yao L, Bhada-Tata P, Van Woerden F (2018) What a waste 2.0: a global snapshot of solid waste management to 2050. Urban Development Series. World Bank Publications, Washington, USA
Kim KH, Chun HH, Jo WK (2015) Spatial and long-term temporal assessment of organic hazardous air pollutants and their comparative health risks. Int J Environ Sci Technol 12(12):3929–3942. https://doi.org/10.1007/s13762-015-0822-1
Komilis DP, Ham RK, Park JK (2004) Emission of volatile organic compounds during composting of municipal solid wastes. Water Res 38(7):1707–1714. https://doi.org/10.1016/j.watres.2003.12.039
Kuang Y, Lin B (2021) Public participation and city sustainability: evidence from urban garbage classification in China. Sustain Cities Soc 67:102741. https://doi.org/10.1016/j.scs.2021.102741
Li X, Bi F, Han Z, Qin Y, Wang H, Wu W (2019) Garbage source classification performance, impact factor, and management strategy in rural areas of China: a case study in Hangzhou. Waste Manag 89:313–321. https://doi.org/10.1016/j.wasman.2019.04.020
Liu J, Zheng G (2020) Emission of volatile organic compounds from a small-scale municipal solid waste transfer station: ozone-formation potential and health risk assessment. Waste Manag 106:193–202. https://doi.org/10.1016/j.wasman.2020.03.031
Liu Y, Lu W, Dastyar W, Liu Y, Guo H, Fu X, Li H, Meng R, Zhao M, Wang H (2017) Fugitive halocarbon emissions from working face of municipal solid waste landfills in China. Waste Manag 70:149–157. https://doi.org/10.1016/j.wasman.2017.08.042
Liu Y, Lu W, Wang H, Huang Q, Gao X (2018) Odor impact assessment of trace sulfur compounds from working faces of landfills in Beijing, China. J Environ Manag 220:136–141. https://doi.org/10.1016/j.jenvman.2018.04.122
Liu Y, Yang H, Lu W (2020) VOCs released from municipal solid waste at the initial decomposition stage: emission characteristics and an odor impact assessment. J Environ Sci 98:143–150. https://doi.org/10.1016/j.jes.2020.05.009
Lou Z, Wang M, Zhao Y, Huang R (2015) The contribution of biowaste disposal to odor emission from landfills. J Air Waste Manag Assoc 65(4):479–484. https://doi.org/10.1080/10962247.2014.1002870
Ma J, Li L (2024) VOC emitted by biopharmaceutical industries: source profiles, health risks, and secondary pollution. J Environ Sci 135:570–584. https://doi.org/10.1016/j.jes.2022.10.022
Mustafa MF, Liu Y, Duan Z, Guo H, Xu S, Wang H, Lu W (2017) Volatile compounds emission and health risk assessment during composting of organic fraction of municipal solid waste. J Hazard Mater 327:35–43. https://doi.org/10.1016/j.jhazmat.2016.11.046
Nagata Y, Takeuchi N (2003) Measurement of odor threshold by triangle odor bag method. Odor Measur Rev 118:118–127
Ni Z, Liu J, Song M, Wang X, Ren L, Kong X (2015) Characterization of odorous charge and photochemical reactivity of VOC emissions from a full-scale food waste treatment plant in China. J Environ Sci 29:34–44. https://doi.org/10.1016/j.jes.2014.07.031
Nie E, Zheng G, Shao Z, Yang J, Chen T (2018) Emission characteristics and health risk assessment of volatile organic compounds produced during municipal solid waste composting. Waste Manag 79:188–195. https://doi.org/10.1016/j.wasman.2018.07.024
Rincón CA, De Guardia A, Couvert A, Le Roux S, Soutrel I, Daumoin M, Benoist JC (2019) Chemical and odor characterization of gas emissions released during composting of solid wastes and digestates. J Environ Manag 233:39–53. https://doi.org/10.1016/j.jenvman.2018.12.009
Scheutz C, Winther K, Kjeldsen P (2000) Removal of halogenated organic compounds in landfill gas by top covers containing zero-valent iron. Environ Sci Technol 34(12):2557–2563. https://doi.org/10.1021/es991301f
Shi X, Zheng G, Shao Z, Gao D (2020) Effect of source-classified and mixed collection from residential household waste bins on the emission characteristics of volatile organic compounds. Sci Total Environ 707:135478. https://doi.org/10.1016/j.scitotenv.2019.135478
Statheropoulos M, Agapiou A, Pallis G (2005) A study of volatile organic compounds evolved in urban waste disposal bins. Atmos Environ 39(26):4639–4645. https://doi.org/10.1016/j.atmosenv.2005.04.013
Sun C, Wang Z, Yang Y, Wang M, Jing X, Li G, Yan J, Zhao L, Nie L, Wang Y, Zhong Y, Liu Y (2023) Characteristics, secondary transformation and odor activity evaluation of VOCs emitted from municipal solid waste incineration power plant. J Environ Manag 326:116703. https://doi.org/10.1016/j.jenvman.2022.116703
Tan H, Zhao Y, Ling Y, Wang Y, Wang X (2017) Emission characteristics and variation of volatile odorous compounds in the initial decomposition stage of municipal solid waste. Waste Manag 68:677–687. https://doi.org/10.1016/j.wasman.2017.07.015
Tong R, Zhang L, Yang X, Liu J, Zhou P, Li J (2019) Emission characteristics and probabilistic health risk of volatile organic compounds from solvents in wooden furniture manufacturing. J Clean Prod 208:1096–1108. https://doi.org/10.1016/j.jclepro.2018.10.195
US EPA (1999) Determination of volatile organic compounds (VOCs) in air collected in specially-prepared canisters and analyzed by gas chromatography mass spectrometry (GC/MS). https://www.epa.gov/sites/default/files/2019-11/documents/to-15r.pdf. Accessed 01/1999
US EPA (2009) Risk assessment guidance for superfund volume i: human health evaluation manual (Part F, Supplemental Guidance for Inhalation Risk Assessment). https://nepis.epa.gov/Exe/ZyPDF.cgi/P1002UOM.PDF?Dockey=P1002UOM.PDF. Accessed 01/2009
Wang H, Xiang Z, Wang L, Jing S, Lou S, Tao S, Liu J, Yu M, Li L, Lin L, Chen Y, Wiedensohler A, Chen C (2018) Emissions of volatile organic compounds (VOCs) from cooking and their speciation: a case study for Shanghai with implications for China. Sci Total Environ 621:1300–1309. https://doi.org/10.1016/j.scitotenv.2017.10.098
Wenjing L, Zhenhan D, Dong L, Jimenez LMC, Yanjun L, Hanwen G, Hongtao W (2015) Characterization of odor emission on the working face of landfill and establishing of odorous compounds index. Waste Manag 42:74–81. https://doi.org/10.1016/j.wasman.2015.04.030
Wu T, Wang X, Li D, Yi Z (2010) Emission of volatile organic sulfur compounds (VOSCs) during aerobic decomposition of food wastes. Atmos Environ 44(39):5065–5071. https://doi.org/10.1016/j.atmosenv.2010.09.019
Xu L, Ling M, Lu Y, Shen M (2017) Understanding household waste separation behavior: testing the roles of moral, past experience, and perceived policy effectiveness within the theory of planned behavior. Sustainability 9(4):625. https://doi.org/10.3390/su9040625
Ying D, Chuanyu C, Bin H, Yueen X, Xuejuan Z, Yingxu C, Weixiang W (2012) Characterization and control of odorous gases at a landfill site: a case study in Hangzhou, China. Waste Manag 32(2):317–326. https://doi.org/10.1016/j.wasman.2011.07.016
Zhang Y, Yue D, Liu J, Lu P, Wang Y, Liu J, Nie Y (2012) Release of non-methane organic compounds during simulated landfilling of aerobically pretreated municipal solid waste. J Environ Manag 101:54–58. https://doi.org/10.1016/j.jenvman.2011.10.018
Zhang L, Wang B, Wang Z, Li K, Fang R, Su Y, Wu D, Xie B (2022) Spatiotemporal footprints of odor compounds in megacity’s food waste streams and policy implication. J Hazard Mater 437:129423. https://doi.org/10.1016/j.jhazmat.2022.129423
Zheng G, Liu J, Shao Z, Chen T (2020) Emission characteristics and health risk assessment of VOCs from a food waste anaerobic digestion plant: a case study of Suzhou, China. Environ Pollut 257:113546. https://doi.org/10.1016/j.envpol.2019.113546
Zhou J, You Y, Bai Z, Hu Y, Zhang J, Zhang N (2011) Health risk assessment of personal inhalation exposure to volatile organic compounds in Tianjin, China. Sci Total Environ 409(3):452–459. https://doi.org/10.1016/j.scitotenv.2010.10.022
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This work was supported by the Zhejiang Province Key Research and Development Technology Project (2021C03024).
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All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Ruiqian Zhang, Yong Qin, and Xiaosi Yin. The first draft of the manuscript was written by Ruiqian Zhang, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Zhang, R., Qin, Y., Yin, X. et al. Release characteristics of volatile organic compounds at residential garbage collection points: a case study of Hangzhou, China. Environ Sci Pollut Res 31, 18949–18961 (2024). https://doi.org/10.1007/s11356-024-32408-9
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DOI: https://doi.org/10.1007/s11356-024-32408-9