Skip to main content
Log in

Spatial and long-term temporal assessment of organic hazardous air pollutants and their comparative health risks

  • Original Paper
  • Published:
International Journal of Environmental Science and Technology Aims and scope Submit manuscript

Abstract

This study investigated the spatial and long-term temporal characteristics of 13 selected organic hazardous air pollutants and the health risks associated with inhalation exposure over a recent 6-year period. Regional types selected for this study included a residential–commercial complex, traffic junction, petrochemical industry, iron and metal industry, and background areas in Korea. Toluene was generally the most abundant pollutants in all areas. The petrochemical industrial area had the highest median concentrations of six pollutants (benzene, ethyl benzene, o-xylene, m,p-xylene, styrene, and chloroform), followed by the residential–commercial complex, traffic junction, iron and metal industry, and background area. The residential–commercial complex and traffic junction areas showed the highest and second highest toluene concentrations, respectively. Two pollutants (1,1-dichloroethane and 1,3-butadiene) were present in similar concentrations among the five areas. In addition, the temporal trends in the annual mean concentrations exhibited unpredictable behavior depending on both the area and the type of pollutants. At the residential–commercial complex and traffic junction areas, six aromatic compounds showed significant correlations among themselves. In most cases, three important meteorological parameters (relative humidity, temperature, and wind speed) were not significantly correlated with ambient pollutant concentrations. Benzene was the only pollutant that exceeded the cancer risk levels of 1 × 10−6, and this excess was only observed at certain areas.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  • Axelsson G, Barregard L, Holmberg E, Sallsten G (2010) Cancer incidence in a petrochemical industry area in Sweden. Sci Total Environ 408:4482–4487

    Article  CAS  Google Scholar 

  • Badol C, Locoge N, Léonardis T, Galloo J-C (2008) Using a source–receptor approach to characterize VOC behaviour in a French urban area influenced by industrial emissions Part I: study area description, data set acquisition and qualitative data analysis of the data set. Sci Total Environ 389:441–452

    Article  CAS  Google Scholar 

  • Barregard L, Holmberg E, Sallsten G (2009) Leukaemia incidence in people living close to an oil refinery. Environ Res 109:985–990

    Article  CAS  Google Scholar 

  • Blanchard CL, Hidy GM, Tanenbaum S, Rasmussen R, Watkins R, Edgerton E (2010) NMOC, ozone, and organic aerosols in the southeastern United States, 1999–2007: 1. Spatial and temporal variations of NMOC concentrations and composition in Atlanta, Georgia. Atmos Environ 44:4827–4839

    Article  CAS  Google Scholar 

  • Carter WPL, Seinfeld JH (2012) Winter ozone formation and VOC incremental reactivities in the Upper Green River Basin of Wyoming. Atmos Environ 50:255–266

    Article  CAS  Google Scholar 

  • Chu W, Gao N, Deng Y, Templeton MR, Yin D (2011) Impacts of drinking water pretreatments on the formation of nitrogenous disinfection by-products. Bioresour Technol 102:11161–11166

    Article  CAS  Google Scholar 

  • Delzell E, Macaluso M, Sathiakumar N, Matthews R (2001) Leukemia and exposure to 1,3-butadiene, styrene and dimethyldithiocarbamate among workers in the synthetic rubber industry. Chem Biol Interact 135–136:515–534

    Article  Google Scholar 

  • Deng Y, Peng P, Ren M, Song J, Huang W (2011) The winter effect on formation of PCDD/Fs in Guangzhou by vehicles: a tunnel study. Atmos Environ 45:2541–2548

    Article  CAS  Google Scholar 

  • Divine BJ, Hartman CM (2001) A cohort mortality study among workers at a 1,3 butadiene facility. Chem Biol Interact 135–136:535–553

    Article  Google Scholar 

  • Hoque RR, Khillare PS, Agarwal T, Shridhar V, Balachandran S (2008) Spatial and temporal variation of BTEX in the urban atmosphere of Delhi, India. Sci Total Environ 392:30–40

    Article  CAS  Google Scholar 

  • Karar K, Gupta AK (2006) Seasonal variations and chemical characterization of ambient PM10 at residential and industrial sites of an urban area of Kolkata (Calcutta), India. Atmos Res 81:36–53

    Article  CAS  Google Scholar 

  • Khoder MI (2007) Ambient levels of volatile organic compounds in the atmosphere of Greater Cairo. Atmos Environ 41:554–566

    Article  CAS  Google Scholar 

  • KME (Korean Ministry of Environment) (2008) Annual Report of Ambient Air Quality in Korea, KME

  • Lee JY, Kim YP, Kang C-H, Ghim YS (2006) Seasonal trend of particulate PAHs at Gosan, a background site in Korea between 2001 and 2002 and major factors affecting their levels. Atmos Res 82:680–687

    Article  CAS  Google Scholar 

  • Lee HW, Choi H-J, Lee S-H, Kim Y-K, Jung W-S (2008) The impact of topography and urban building parameterization on the photochemical ozone concentration of Seoul, Korea. Atmos Environ 42:4232–4246

    Article  CAS  Google Scholar 

  • Leuchner M, Rappenglück B (2010) VOC source-receptor relationships in Houston during TexAQS-II. Atmos Environ 44:4056–4067

    Article  CAS  Google Scholar 

  • McCarthy MC, O’Brien TE, Charrier JG, Hather HR (2009) Characterization of the chronic risks and hazard of hazardous air pollutants in the United States using ambient monitoring data. Environ Health Perspect 112:589–598

    Google Scholar 

  • Na K, Kim YP (2007) Chemical mass balance receptor model applied to ambient C2–C9 VOC concentration in Seoul, Korea: effect of chemical reaction losses. Atmos Environ 41:6715–6728

    Article  CAS  Google Scholar 

  • Na K, Moon K-C, Kim YP (2005) Source contribution to aromatic VOC concentration and ozone formation potential in the atmosphere of Seoul. Atmos Environ 39:5517–5524

    Article  CAS  Google Scholar 

  • Nguyen HT, Kim K-H, Kim M-Y (2009) Volatile organic compounds at an urban monitoring station in Korea. J Hazard Mater 161:163–174

    Article  CAS  Google Scholar 

  • Oskouie AK, Lordi DT, Granato TC, Kollias L (2008) Plant-specific correlations to predict the total VOC emissions from wastewater treatment plants. Atmos Environ 42:4530–4539

    Article  CAS  Google Scholar 

  • Parra MA, González L, Elustondo D, Garrigó J, Bermejo R, Santamaría JM (2006) Spatial and temporal trends of volatile organic compounds (VOC) in a rural area of northern Spain. Sci Total Environ 370:157–167

    Article  CAS  Google Scholar 

  • Pyatt D, Hays S (2010) A review of the potential association between childhood leukemia and benzene. Chem Biol Interact 184:151–164

    Article  CAS  Google Scholar 

  • Sangiorgi G, Ferrero L, Perrone MG, Bolzacchini E, Duane M, Larsen BR (2011) Vertical distribution of hydrocarbons in the low troposphere below and above the mixing height: tethered balloon measurements in Milan, Italy. Environ Pollut 159:3545–3552

    Article  CAS  Google Scholar 

  • Shin DC, Yang J (2010) Risk based approach for managing toxic VOCs in the air of Seoul. In: Proceeding of the 50th Meeting of Korean Society for Atmospheric Environment. Incheon, Korea, 13-May, pp 73

  • Snyder R (2002) Benzene and leukaemia. Crit Rev Toxicol 32:155–210

    Article  CAS  Google Scholar 

  • Stroud CA, Morneau G, Makar PA, Moran MD, Gong W, Pabla B, Zhang J, Bouchet VS, Fox D, Venkatesh S, Wang D, Dann T (2008) OH-reactivity of volatile organic compounds at urban and rural sites across Canada: evaluation of air quality model predictions using speciated VOC measurements. Atmos Environ 42:7746–7756

    Article  CAS  Google Scholar 

  • Su F-C, Mukherjee B, Batterman S (2013) Determinants of personal, indoor and outdoor VOC concentrations: an analysis of the RIOPA data. Environ Res 126:192–203

    Article  CAS  Google Scholar 

  • Tam BN, Neumann CM (2004) A human health assessment of hazardous air pollutants in Portland, OP. J Environ Manage 73:131–145

    Article  CAS  Google Scholar 

  • Tham YWF, Takeda K, Sakugawa H (2008) Polycyclic aromatic hydrocarbons (PAHs) associated with atmospheric particles in Higashi Hiroshima, Japan: influence of meteorological conditions and seasonal variations. Atmos Res 88:224–233

    Article  CAS  Google Scholar 

  • Touma JS, Cox WM, Tikvart JA (2006) Spatial and temporal variability of ambient air toxics data. J Air Waste Manage Assoc 56:1716–1725

    Article  CAS  Google Scholar 

  • USEPA (U.S. Environmental Protection Agency) (2010) Integrated Risk Information System. http://www.epa.gov/iris. Accessed 20 December 2010

  • Vu V-T, Lee B-K, Kim J-T, Lee C-H, Kim I-H (2011) Assessment of carcinogenic risk due to inhalation of polycyclic aromatic hydrocarbons in PM10 from an industrial city: a Korean case-study. J Hazard Mater 189:349–356

    Article  CAS  Google Scholar 

  • Yoo S-H, Kwak S-J, Lee J-S (2008) Using a choice experiment to measure the environmental costs of air pollution impacts in Seoul. J Environ Manage 86:308–318

    Article  CAS  Google Scholar 

  • Yuan Z, Zhong L, Lau AKH, Yu JZ, Louie PKK (2013) Volatile organic compounds in the Pearl River Delta: identification of source regions and recommendations for emission-oriented monitoring strategies. Atmos Environ 76:162–172

    Article  CAS  Google Scholar 

  • Yurdakul S, Civan M, Tuncel G (2013) Volatile organic compounds in suburban Ankara atmosphere, Turkey: sources and variability. Atmos Res 120–121:298–311

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (No. 2011-0027916) and GCRC-SOP (No. 2011-0030013). We also appreciate the reviewers for their thoughtful and valuable suggestions.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to W. K. Jo.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kim, K.H., Chun, HH. & Jo, W.K. Spatial and long-term temporal assessment of organic hazardous air pollutants and their comparative health risks. Int. J. Environ. Sci. Technol. 12, 3929–3942 (2015). https://doi.org/10.1007/s13762-015-0822-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13762-015-0822-1

Keywords

Navigation